螯合作用

A new collector with chelate-ability,diphenyl α-(3-phenylthioureido) alkanephosphonate,is synthesized,and the collecting performance for cerussite ,calcite and quartz,and the relationship between property and structure are investigated, and the depressor function of pyrogallic acid are also studied.

合成具有螯合性能的新型捕收剂———-α(3-苯基硫脲基)烃基膦酸二苯酯，研究该系列化合物对白铅矿、方解石和石英的捕收能力以及结构和性能的关系，并考查焦性末食子酸的抑制作用。

Objective: To study the protective effect of collagen peptide-chromium chelate on liver injury in alloxan-treated mice.

目的：研究胶原蛋白多肽铬螯合物对小鼠四氧嘧啶致肝损伤在形态结构方面的保护作用。

The effects of reaction factors of oxidation, grafting copolymerization and chelation on the corrosion and scale inhibition performance of modified product were studied.

实验研究了影响氧化反应、丙烯酸接枝共聚反应和螯合反应的各因素对木素磺酸钠改性产物缓蚀阻垢性能的作用规律。

In this paper, firstly, a detail analysis、 study and discussion of the existing disposing-chlorine method were made, on this condition, a new method based on the way of oxidation and deoxidization was discussed, phosphoramidic acid chelate resin and DOOl cation exchange resin were chosen as framework materials, two kinds of new disposing-chlorine materials could be obtained by loading Fe~(2+) on the skeleton of the materials, the surplus residual chlorine was disposed by taking advantage of chlorine oxidizing Fe~(2+).

本文在对已有的余氯去除方法进行分析、研究、探讨的基础上，提出一种基于氧化还原方式的吸附除氯方法，实验以氨基磷酸螯合树脂和D001强酸性阳离子交换树脂为骨架材料，并对这两种材料载Fe~(2+)改性得到两种新型除氯剂，通过固载的Fe~(2+)与水中余氯(Cl_2、ClO~-、HClO)的氧化还原作用将水中的余氯除去。

Generally the larger La~(3+) ion prefers the monazite type due to its higher oxygen coordination number of 9 as compared to 8 of the zircon type.

而EDTA作为模板剂除了螯合和诱导晶体生长外，还起到抑制镧离子形成9配位结构的作用，从而避免了单斜独居石结构晶相的产生。

The Molar conductivity indicates that all the complexes are nonelectrolyte. IR spectra show the ligand is bonded with RE ion through its oxygen atom in hydroxyl group of phenol; NO3 is coordinated as a symmetrical chelating bidentate group; the coordinated atoms of DMF and DMSO are the oxygen atoms in carbonyl and sulfoxyl groups. Fluorescence spectrum suggests that the Tb3+complexes have characteristic luminescence and its fluorescence intensity is enhanced after doping with La3+, Gd3+, Y3+, influence of doping ions and neutral ligands have also been discussed.

摩尔电导率表明，所有配合物均为非电解质；红外光谱及核磁共振氢谱表明，对叔丁基杯[8]芳烃通过酚羟基的氧原子与稀土离子配位；硝酸根为双齿螯合配位；DMF和DMSO则分别通过羰基氧和亚砜基氧与稀土离子配位；配合物的荧光光谱表明，所有Tb的配合物具有较强的特征荧光，掺杂La~(3+)、Gd~(3+)、Y~(3+)离子对Tb~(3+)的荧光有较强的增强作用。

It demonstrated that the hydroxy organic acids substituted with-OH,-SH at α—C such as lactic acid, Hydroxy-acetic acid, mercapto-acetic acid, glyconic acid have good selectivity for separation of hematite and aegirine pka values of organic acids fall down because of the-I inductive effect of-OH or-SH, and lie at the pH range between two minerals point-zero-charge. As a result, the depression ability of them was enhanced, and a cyclo-pentyl chelate was formed when this organic acids acted with Fe〓 on the minerals surface.

发现在α位具有-OH、-SH等取代基的短链一元羧酸（乳酸、羟基乙酸、巯基乙酸，葡萄糖酸）对赤铁矿与钠辉石的浮选分离具有优良的选择性抑制作用，-OH、-SH的-I诱导效应导致有机酸的pKa值下降并落在两种矿物零电点之间，使其抑制性能增强，并与矿物表面的Fe〓形成稳定的五元螯合环。

Both crystallographically unique Zn atoms exit as an octahedral geometry. The four equatorial positions of Zn1 atom are occupied by the carboxylate-oxygen atoms of the two tartrates, and the two oxygens of the left four carboxylate-oxygen atoms coordinate to two different Zn2 atoms, respectively, forming infinite coordination polymer chains. The left two of the trans equatorial positions of Zn2 atom are completed with two oxygen atoms of two water molecules. The axial positions of both Zn atoms are occupied by the nitrogen atoms from different 4,4'-bipyridine molecules to give a 2D rectangular-grid layers with a cavity dimension of 0.51165(3)nm×1.13896(5) nm. A three dimensional network is formed by the crystallization water chains joined by the carboxylate-oxygen atoms through hydrogen-bonding interactions.

两个晶体学独立的Zn原子均为八面体构型，其中Zn1原子赤道配位点被2个酒石酸根中的4个羧酸根氧螯合配位， 2个酒石酸根中剩下的4个羧酸根氧中的2个分别与2个Zn2原子连接形成无限一维链， Zn2原子的另外2个反式赤道配位点被2个水分子氧占据，同时这两种Zn原子的轴向配位点均被4，4'-联吡啶的氮原子占据，形成具有矩形格子[0.51165(3) nm×1.13896(5) nm]的二维层状结构，游离的2个水分子通过氢键作用形成二聚体，并与酒石酸根中未与Zn配位的羧酸氧连接，把二维层状结构连接成三维网状的超分子结构。

Therefore can pass to use the cupric sulfate sulfuric acid potassium for the catalyst take sulfuric acid as to carry the body to digest it, make the amino acids chelate match the conversion for dissolve sex easily of ammonium sulfate and white vitriol, then absorb a fixed amount to try the kind to join 40% sodium hydroside combine under the steam heat function make ammonia the spirit swims to leave out, through cool off to respond the born boric acid with boric acid, be got the total nitrogen content by the standard aqua titration of hydrochloric acid immediately after;But the white vitriol can immediately join the hydrochloric acid hydroxylate , fluoride to turn the in order to cover up, carry on the titration but get the content of its zinc with the EDTA mark liquid..

因此可以通过用硫酸铜硫酸钾为催化剂以硫酸为载体将其消化，使氨基酸螯合锌转化为易溶性的硫酸铵和硫酸锌，然后吸取一定量的试样加入40 %的氢氧化钠并在水蒸气高温作用下使氨气游离出来，经冷却与硼酸反应生成硼酸铵，接着由盐酸标准溶液滴定得到总氮含量；而硫酸锌即可加入盐酸羟铵、氟化氢铵为掩蔽剂，用EDTA标液进行滴定而得到其锌的含量。

Become the pharmacodynamical functional group to realize the direct connection on body's endo-sugar with amino acid, and then to make the function of discharging lead after sugar taking amino acid into cell to complex with lead.

本论文选择葡萄糖和阿拉伯糖作为药动团，L-半胱氨酸等其它侧链氨基酸作为药效团，实现人体内源性糖和氨基酸的直接相连，从而发挥糖携带氨基酸进入细胞螯合排铅的作用。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。