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螯合

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Urushiol can be used as the basic raw material to develop economic and practical coating with good resistance to high temperature alkaline solution. Thus the polymer precursor was prepared using the polymerization of urushiol and formaldehyde. Then the urushiol-titanium chelate polymer (urushiol-Ti resin) was synthesized by way of the reaction of tetrabutyl titanate with the polymer precursor. The prospective target product was analyzed by means of high-performance liquid chromatography and Fourier transformation infrared spectroscopy.

为开发经济实用的耐高温碱水漆酚钛清漆,以漆酚为基本原料,先通过漆酚与甲醛缩聚,再将钛酸丁酯与前期合成产物反应,从而合成出了漆酚-钛螯合高聚物,并通过高效液相色谱和傅立叶红外技术检测了预期产物的合成情况。

It was shown that all of the four β-diketones tested, acetylacetone, trifluoroacetylacetone, benzoylacetone and 1-phenyl-3-methyl-4-benzoylpyrazolone-5, improved the sensitivity of Al to some extent.

结果表明,四种螯合物对Al的分析性能均有一定程度的改善。

The DSC and FTIR techniques were utilized to analyze the thermal evolution process of the PZT gelation powder with and without acetylacetone agents and the physicochemistry changes of the PZT powders from amorphous to crystal phases.

用DSC和FTIR技术分析了有无乙酰丙酮螯合的两种PZT凝胶粉末的热演化过程;分析了PZT由无定型相向结晶相转化过程中发生的物理化学变化。

It demonstrated that the hydroxy organic acids substituted with-OH,-SH at α—C such as lactic acid, Hydroxy-acetic acid, mercapto-acetic acid, glyconic acid have good selectivity for separation of hematite and aegirine pka values of organic acids fall down because of the-I inductive effect of-OH or-SH, and lie at the pH range between two minerals point-zero-charge. As a result, the depression ability of them was enhanced, and a cyclo-pentyl chelate was formed when this organic acids acted with Fe〓 on the minerals surface.

发现在α位具有-OH、-SH等取代基的短链一元羧酸(乳酸、羟基乙酸、巯基乙酸,葡萄糖酸)对赤铁矿与钠辉石的浮选分离具有优良的选择性抑制作用,-OH、-SH的-I诱导效应导致有机酸的pKa值下降并落在两种矿物零电点之间,使其抑制性能增强,并与矿物表面的Fe〓形成稳定的五元螯合环。

The precursor solutions of titanium alkoxide with different amount of AcAc were characterized by DTA to study the chelating process of titanium alkoxide with AcAc.

对含有不同量乙酰丙酮的前驱体溶液做了热重分析,研究了钛酸丁酯与乙酰丙酮的螯合过程。

From the point of ion exchange and chelating ,the high adsorption selectivity was investigated by the peculary structure of amidoxime fiber(combined with crosslinking structure and the maximal conversion of cyano) and Au ion.

从离子交换和螯合吸附的角度,根据偕胺肟基纤维本身的交联结构和最大氰基转化特点以及金离子本身的结构特点对其高选择吸附性能进行了解析。

Chelate fiber with amidoxime group,which is obtained from chemical modification of PAN fiber,is treated with mercury nitrate to prepare anion-exchange fiber.The optimum conditions of the anion-exchange fiber absorption of the thiocyanate ion,such as ion concentration,time,the pH value were studied.

以聚丙烯腈纤维进行NH2OH化学改性制得的含有偕胺肟基的螯合纤维为原料,经Hg(NO3)2化学处理,制得阴离子交换纤维;并以硫氰酸根离子为研究对象,系统地探讨和研究了阴离子交换纤维吸附硫氰酸根离子的最佳条件参数:离子浓度、时间、pH值等。

Polyvinyl alcohol amidoxime chelate fiber was synthesised by pre irradiation graft copolymerization and amidoximation.

利用60Co-γ射线预辐照接枝和胺肟化反应合成了含羧基的聚乙烯醇胺肟螯合纤维。

The organic compounds like cyanine, macrocyclic azotic compound, azo-metal complex, metal chelate, benzoheterocycle dye, have been applied to recordable optical discs as the recording materials.

菁类、大环氮杂、偶氮、金属螯合物、苯并杂环等类的化合物已被作为光记录材料进行研究。

The ultraviolet-visible absorption spectra, optical constants (complex refractive index N=n+ik) of the thin films and thermal characterizations of three kinds of novel nickel-azo dyes based on 4-methylthiazole, benzothiazole and 6-methylbenzothiazole were investigated.

分别对三种以 4 甲基噻唑、苯并噻唑和 6 甲基苯并噻唑作为重氮组份,以 3 二乙氨基苯酚作为偶合组份的偶氮染料的镍螯合物的光谱、热学性质和薄膜的光学常数(复折射率N =n+ik)及光存储性能进行了研究。

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