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The CFD method was applied to calculate and simulate the form and action process of the cavitation at the representative character of the cavitation erosion on the surface of the hydraulic turbines.Some argumentation was presented that micro jet impacted the wall with a certain degree when bubble collapsed with the result that the maximal strain of the wall annularly distributed the local of the boundary touching the micro jet.Cavitation was gradual to develop regionally at the mode of chain reaction and di...

针对水轮机叶片表面气蚀的典型特征,利用CFD方法进行仿真计算,模拟气蚀形成和作用过程;根据模拟计算结果提出了新观点:空泡溃灭发生微射流以一定的倾角冲击壁面,壁面材料产生的最大应变在流束边界局部区域,呈环状分布;空泡气蚀在局部区域是渐进的,以"连锁反应"形式扩展,具有一定过流环境的分布特征;典型的冲蚀缺陷形貌是空泡气蚀在不同阶段的产物。

Combined a large number of on -site investigate and survey data of loess area in the north of Shaanxi Province, the paper analyzed the influence factors and interrelationship of slope erosion, then put forward the main influence factors , the peculiarity of outwash destructions the main style and protective measures about slope erosion of highway in loess area. The first: the emphasis about protective measures of cut-slope are the selection of rate of grade, the place of plain stage of slope, the slope protection; the second: the emphases about drainage of cut-slope is the rational installation and mating of drainage establishment; And following this principle: the effective holding up , the rapid obviating, the smooth articulation, the seepage prevention and prevent erosion.

根据陕北黄土地区公路的大量现场调查和实测资料,分析了公路边坡冲蚀的影响因素及其相互关系,提出了黄土地区公路边坡冲蚀的主要影响因素、冲蚀破坏特点、主要类型与防护对策,得出:1、路堑边坡坡面冲蚀防护重点是坡率选择、边坡平台设置、边坡防护;2、路堑边坡排水重点是排水设施的合理设置与配套;并遵循有效拦截、迅速排除、衔接顺畅、防渗防冲等原则。

First, combined with the corrosion mechanism of carbon steel in chlorhydric acid, the relation between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles are developed in terms of Hansch Relation.

最后,运用灰色理论,通过建立苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构关系的灰色缓蚀模型,研究了苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构的关系。

At last, the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles are studied by constructing the grey inhibition model of the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles.

通过对2—苯基丁腈缓蚀性能的理论预测和试验验证,认为利用某一类苯腈类化合物的缓蚀性能与分子结构关系,从理论上预测同类型苯腈类化合物的缓蚀性能是可能和合理的。灰色理论研究结果表明,苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构参数的关系,可用GM(0,3)模型描述。

ABSTRACT Inhibition mechanism and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles whose inhibition is caused by chemical adsorption and quaternary ammonium salts whose inhibition is caused by physical adsorption are mainly studied from microscope through quantum chemistry calculation, and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles are studied by making use of model-constructing thought of grey theory in this paper.

本文主要通过量子化学计算,从微观角度研究了化学吸附型缓蚀剂苯腈类化合物和物理吸附型缓蚀剂季铵盐在盐酸溶液中对碳钢缓蚀的缓蚀机理和缓蚀性能与分子结构的关系;并运用灰色理论建模思想,研究了苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构的关系。其中,通过量子化学计算,从微观角度研究物理吸附型缓蚀剂在盐酸溶液中对碳钢缓蚀的缓蚀机理和缓蚀性能与分子结构的关系,是在尝试着进行;而运用灰色理论建模思想,研究缓蚀剂缓蚀性能与分子结构的关系,是一项具有尝试性和开拓性的工作。

Then, inhibition mechanism and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles and quaternary ammonium salts are studied from microscope through quantum chemistry calculation, and according to the results, theory predicting and proof testing of a benzene nitrile (2-benzo butyl nitrile) are made.

利用Hansch关系的研究结果表明,苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀效率,可用苯腈类化合物氰基氮原子的净电荷密度和分子最高占据轨道能量或分子最低空轨道能量构成的表达式表达。量子化学计算研究结果表明:1、苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀机理可能是:苯腈类化合物分子以其氰基氮原子上的电子提供给铁的3d空轨道,形成配位键;同时铁的3d轨道上的电子提供给苯腈类化合物分子的能量最低空轨道,形成&反馈键&。

Pit corrosion is a main kind of localized corrosion. The process of forming pit corrosion includes three stages-formation of pit source, development of pit cave and forming occluded corrosion cell. Molybdate series inhibitors can be inhibitive, for it can control three stages of pit development. First, there is apparent synergistic effect between molybdate and phosphate, which can suppress formation of pit source. Second, there is apparent passivation of molybdate inhibitor according to electrochemistry analysis, which let oxidation film in unoccluded cave repassivate.

首先,钼酸盐与磷酸盐或硅酸盐复配的缓蚀剂具有较理想的缓蚀性能,并且有明显的协同作用,从而能抑制部分点蚀核的产生;其次,钼酸盐复配缓蚀剂的使用,从电化学的角度分析,具有明显的钝化性能,且钝化区间较宽、维钝电流密度较小,从而能使未封闭的蚀孔或点蚀核附近的氧化膜再钝化,得到有效的修复;最后,对于还有部分蚀孔发展成为闭塞腐蚀电池的情况,钼酸盐、磷酸盐能进入蚀孔内部并且在酸性条件下生成铁钼磷酸盐,从而有效地减缓了点蚀的恶化,抑制了腐蚀的发展。

The relations between inhibition efficiency of carb on steel in hydrochloric acid and molecular structure of compounds of benzene ni t riles were studied by constructing the grey inhibition model of inhibition syste m.

通过运用灰色理论建模思想,建立缓蚀体系的灰色缓蚀模型,研究了盐酸溶液中苯腈类化合物对碳钢缓蚀的缓蚀性能与分子结构的关系。

Although forest canopy layer could prevent splash erosion effectively, clay was taken away by overland flow and run off easily, the erosion amount became less after removing the forest canopy and surface soil, while the splash erosion still produced in the surface layer; the splash function weakened after having water current, the starting particles were less than bareland, so removing the surface disturbed soil made the erosion amount and clay less, silty sand more than bareland, but unsteady, the wear and tear energy used by raindrop splash and current function for overcoming sediments separating and starting were comparatively large, sediments were very difficult to be started and transported, it explained that forest root systems could increase anti-erosion capability of forest vegetation, make rainfall-current system splash and export finer particles than bareland.

虽然林冠层能有效防止溅蚀的发生,但坡面流还是能带走粘粒部分,粘粒还是容易流失。去除林冠和表层土后,侵蚀量变得更少,但表层还是会被溅蚀,有水流后,溅蚀作用减弱,颗粒起动的比裸地的少,所以,去除表层扰动土后,侵蚀量更少,粉沙多,粘粒比裸地更少一些,但不稳定,雨滴击溅和水流作用用于克服泥沙分离起动损耗的能量较大,很难被起动输移,这说明森林植被根系的作用增加了林地植被的抗蚀力,使降雨一水流系统仅能溅起输出比裸地坡面更细小的泥沙颗粒。

Singapore Science Center science teacher said that in general solar eclipse 15 days after the lunar eclipse will occur, but only "on the entire loss" of the moon will show the dark red, the Lantern Festival in 2009 only "on partial eclipse."

新加坡科学馆科学教员说,一般日蚀后第15天就会出现月蚀,但因为只有&月全蚀&的月亮会呈现暗红色,2009年元宵节只是&月偏蚀&。

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