薄膜层

Meanwhile, the accurate mask alignment between the active layer on the bottom glass and the black matrix on the top glass and the choice of low-reflectivity black matrix material in conventional technology are also omitted.

并利用淀积欧姆接触层n〓a-Si：H和金属薄膜时沉积在SiN〓保护层上的n〓a-Si：H和金属薄膜作遮光黑层，省去了传统方法中上玻璃基板的黑矩阵与下玻璃基板TFT有源层沟道之间苛刻的对版工艺，并避免了传统黑矩阵制作工艺中对低反射率黑层材料的需求。

The micro movement of deposited cluster and the microstructure evolution of thin film have been studied in dimension of atom-cluster in this paper. There are some important applications to do deeply research on the migration, coacervation and nucleation of atom cluster, to optimize the deposition process, to enhance the characteristics of thin film.

在原子尺度上揭示膜层形成初期粒子的微观变化过程及膜层微观结构的演化规律，对深入了解表面粒子的迁移、吸附和成核，对改进和优化薄膜生长工艺、提高薄膜质量、改善薄膜性质具有重要意义。

In this thesis, the heterojunction with intrinsic hydrogenated amorphous silicon thin layer ( heterojunction with intrinsic thin layer: HIT) solar cells are investigated. The solar cell structure of p/i/n are fabricated. The substrate is a typical 4-inch n-type wafer with (100) crystal orientation, 1~10 ohm-cm and about 525 μm thickness. The p and i a-Si:H layers are deposited by a 13.56 MHz plasma enhanced chemical vapor deposition. The i a-Si:H layers are especially deposited by pulse-wave modulation plasma technique with fixed plasma turn-off time toff = 10 ms and changed plasma turn-on time ton= 10 to 40 ms to selectively control the different silicon to hydrogen bonding configurations. The effect of various Si:H bonds on the performance of HIT solar cells are explored.

中文摘要本论文针对异质接面薄本质层(heterojunction with intrinsic thin layer： HIT)太阳电池进行研究，采用一般典型四英吋晶向为(100，厚度约为525 μm，电阻率约为 1~10 ohm-cmn型矽晶圆为基板，制作p/i/n太阳电池，p及i层薄膜以13.56 MHz电浆加强化学气相沈积，i层并采用脉波调变电浆技术，在固定电浆关闭时间toff = 10 ms及改变电浆开启时间由ton = 10 ms 至40 ms条件下制作具有不同矽氢键结微结构的氢化非晶矽薄膜以探讨不同矽氢键结对太阳电池性能的影响。

At the temperature as low as that at which the monomer cannot diffuse in large scale,adatom nucleation and island formation depends on the increase of adatom density.With the increase of temperature,the film growth mode depends on the competition between in-plane diffusion and inter-layer diffusion of monomers.

当薄膜生长温度低于单原子的扩散温度时，表面原子的成核和表面岛的生长主要是由沉积原子的空间随机性和表面原子密度增加而决定的，随着薄膜生长温度的提高，薄膜的生长模式则取决于单原子的层内扩散和层间扩散的竞争。

AFM images revealed that as the sputtering time was prolonged, the film thickness increased, the film became compacter, and the specific area of the film also increased, thus, the release rate of silver ions increased, which led to improved antibacterial properties. EDX test results indicated that increase in film thickness led to increase in silver weight percentage per unit surface, causing improved antibacterial properties. Moreover, when the film thickness was 1 nm, the inhibition percentage of Staphylococcus aureus and Escherichia coli were 100%.

结果表明：随着薄膜厚度的增大，样品抗菌性能提高；溅射时间延长，薄膜厚度增大，膜层的致密性改善，单位面积上的银含量增加，膜层表面积增大，银离子释放几率增大，是提高抗菌性能的主要原因；当纳米结构银薄膜厚度为1 nm时，对大肠杆菌和金黄色葡萄球菌的抑菌率均达到100%。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

This study proposes to coat these CIGS thin film bases under the non-vacuum. In this process, synthesis nano-sized alloy powder is turned into trihydric compound paste of CIS by using Sol-Gel in the first step. An array of CIGS thin film absorbing layer was produced on Soda Lime glass through screen-printing.

中文摘要本文提出以非真空制程的涂布方法制备CIGS薄膜吸收层，将具备奈米等级的多元合金粉末利用溶胶-凝胶制备三元化合物的CIS前驱层浆料，以网版印刷式於钠玻璃基板上制作CIGS薄膜吸收层。

This embodiment will illustrate that the present invention of the (poly trimethylene terephthalate) PTT laminated film performs better than its PET counterpart in terms of vapor impermeability, flexibility and warpage; its vapor impermeability is about equal to a TPT back sheet, while flexibility and warpage are better than TPT back sheet.

本实施例说明本发明聚对苯二甲酸丙二醇酯薄膜复合成的叠层膜的抗水汽渗透性、挠性和翘曲度优于多层聚对苯二甲酸乙二醇酯薄膜复合形成的叠层膜，抗水汽渗透性与TPT背板基本相当，挠性和翘曲度优于TPT背板。

The present invention relates to a halogen-free, multilayered, uniaxially oriented heat shrink film comprising a core layer comprising a blend of polyolefins; a first skin layer on the upper surface of the core layer, and a second skin layer on the lower surface of the core layer, wherein the first and second skin layers independently comprise a polyolefin blend and wherein the shrinkage of the film is at least about 40% in the machine direction at 270 DEG F.

本发明涉及一种不含卤素、多层、单轴取向的热收缩薄膜，包含含聚烯烃共混物的芯层；在芯层上表面上的第一皮层，和在芯层下表面上的第二皮层，其中，第一和第二皮层独立地包含聚烯烃共混物，并且其中，在270°F，在纵向薄膜的收缩率至少约为40％。

It indicated that the multiple-layered films were mainly composed by C-F, C=C and Si-O bonging, a little Si-C and Si-F bonding were also existed because of history effect. The bondgap were calculated as 2.7eV. The dielectric constant of the multiple-layered films was close relative to the thickness of the covering layer-SiOx, so the thickness had better be reduce. The bonding configurations of multiple-layered films had no evident changes after 400癈 annealing, the thickness raise very little and the dielectric constant increase 8%. Compared with one-layered a-C:F films prepared in the same conditions, the SiOx/a-C:F/SiOx multiple-layered films had a better thermal stability.

结果表明，多层膜主要由C-F，C=C，Si-O键构成，由于器壁的历史效应，薄膜中还存在少量Si-C和Si-F键；多层膜的光学带隙经计算约为2.7eV；多层膜的介电常数与包层SiO_x厚度有很大关系，应尽可能减小SiO_x厚度；在经历200-400℃的N_2氛围中退火后，多层膜的红外结构没有发生太大的变化：膜厚度稍微增大，介电常数只增加了8％，与同样制备条件下沉积的单层a-C：F薄膜相比具有较好的热稳定性。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。