薄膜

The static optical recording characteristics were studied by the home-made static characterizer, the high contrast pattern can be produced by 780 nm laser pulses and can be erased by heating.

利用自制的光学信息写入系统研究了m-NBMN/DAB有机薄膜的静态存储特性，发现在780 nm激光脉冲的作用下m-NBMN/DAB有机薄膜具有光学双稳态特性，并且在大气中加热薄膜可实现信息擦除。

AFM images revealed that as the sputtering time was prolonged, the film thickness increased, the film became compacter, and the specific area of the film also increased, thus, the release rate of silver ions increased, which led to improved antibacterial properties. EDX test results indicated that increase in film thickness led to increase in silver weight percentage per unit surface, causing improved antibacterial properties. Moreover, when the film thickness was 1 nm, the inhibition percentage of Staphylococcus aureus and Escherichia coli were 100%.

结果表明：随着薄膜厚度的增大，样品抗菌性能提高；溅射时间延长，薄膜厚度增大，膜层的致密性改善，单位面积上的银含量增加，膜层表面积增大，银离子释放几率增大，是提高抗菌性能的主要原因；当纳米结构银薄膜厚度为1 nm时，对大肠杆菌和金黄色葡萄球菌的抑菌率均达到100%。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

The conducting polymer Poly 3,4-Ethylene Dioxy Thiophene thin films was prepared by chemical polymerization. Fourier transform infrared and Scanning Electron Microscope were used to characterize its optical property and morphology. A gas sensor using PEDT thin film was fabricated with the assistance of interdigitated electrodes. The sensitivities of the prepared sensor to toxic NO2 and NH3 and its temperature property were studied.

采用化学聚合法制备了导电聚合物3，4-乙烯二氧噻吩膜，利用扫描电子显微镜和傅里叶变换红外光谱法对薄膜的光学成分及形貌进行了分析，采用叉指电极结构研制出了3，4-乙烯二氧噻吩薄膜气体传感器，研究了3，4-乙烯二氧噻吩薄膜气体传感器对有毒气体NO2和NH3的敏感特性以及其自身的温度特性。

When substrate temperature is below 650℃, the Ti〓N crystals are dispersively distributed in the amorphous TiN〓 film deposited by ion beam sputtering.

在离子束溅射制备的TiN〓薄膜中，当沉积温度在650℃以下时，Ti〓N晶体弥散分布在非晶的TiN〓薄膜中；而650℃以上沉积的薄膜中主晶相为TiN，沉积温度越高，TiN相的（111）织构越明显。

Appear principle teacher to make such explanatory normally to adding those who show film when film ply is incident light when the 1/4 that grows in filmy medium wave, going up filmily, the road path difference of the reflex below is equal to half wavelengh fitly, offset each other consequently.

对于增透膜的增透原理老师通常作这样的解释当薄膜的厚度是入射光在薄膜中波长的1/4时，在薄膜的上、下面的反射光的路程差恰好等于半个波长，因而相互抵消。

Thin film material and adhesive materials films label material similar or the same, but the pressure-sensitive materials and filmogen in business card printing and membership card making ?also the adaptability of the nature of differences.

薄膜不干胶材料的面材与薄膜标签材料相似或基本相同，但不干胶材料与薄膜材料在制卡和会员卡制作适应性方面有本质的区别。

Film material and adhesive materials films label material similar or the same, but the pressure-sensitive materials and filmogen in business card printing and membership card making ?also the adaptability of the nature of differences.

薄膜不干胶材料的面材与薄膜标签材料相似或基本相同，但不干胶材料与薄膜材料在制卡和会员卡制作适应性方面有本质的区别。

The results in this paper are concluded as follows:(1) Rolling contact fatigue has been used to examine the interfacial reaction products and study the mechanism of ion beam intermixing effect on the adhesion of Cr-N coating on steel by IBAD.

对多次冲击条件下薄膜的失效抗力及其与薄膜力学性能之间的关系进行了初步探讨，得到如下结果：（1）用滚动接触疲劳法检测离子轰击导致的界面反应产物和研究离子束共混对钢基体上IBAD沉积Cr-N薄膜结合强度的影响本质，结果表明，滚动接触疲劳能有效地分析界面最薄弱位置和评估界面反应产物，滚动接触疲劳引起的剥落可作为研究界面反应产物对结合强度影响的根据。

In the meanwhile, we summarized the inspective methods and principles of the DLC: N films such as Raman spectrum, X-ray photoelectron spectrum, infrared absorption spectrum, atomic force microscope, scanning electron microscope.

第三章介绍了射频磁控溅射方法制备薄膜的步骤及设备操作的步骤，并制备了DLC薄膜及DLC：N薄膜，对其成分和结构进行了对比。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新