蒽醌基

The pigments synthesized from 2, 7-diaminoflurenone consistently show better photosensitivity than that containing anthraquinone. A plot of the E1/2 values against the Hammett constant σ was obtained for the pigments which have different substituents in the anilide ring. The plot reveals that neither a strong electron-releasing group, such as methoxy, nor a electron-withdrawing group, such as nitro-group, enhances the sensitivity of the photoreceptor in which these pigments are used as CGL materiel.

芴酮类偶氮染料的光敏性优于蒽醌类偶氮染料，其偶合基酰胺芳环取代基为强的给电子基团或强的吸电子基团时都不利于其光敏性的提高，只有当取代基基团为氯时其表现出最好的光敏性，这一结果与Law等人的研究结果相同。

To further study the chemical constitutes of lipophilic active parts, we prepared Alc95% and Alc50% according to original literature. 20 compounds were isolated by using macroporous resin, silica gel, polyamide, Sephadex LH-20, Rp-18, preparative TLC and preparative HPLC chromato-graphy. The structures of them were elucidated by means of physical and chemical properties, modern spectroscopic analysis techniques—UV、IR、 EI/MS、ESI/MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC. They are nine anthraquinones: chrysophanol (95-1), physcion (95-2), emodin (95-5), aloemodin (95-7), rhein (50-1), sennoside A or B (50-6),ω-hydroxylemodin (95-10), chrysophanol-8-0-β-D-glucoside (95-12), aloemodin-ω-0-β-D-glucoside (95-13); three phenanthaquinones: tanshinone ⅡA (95-3), cryptotanshinone (95-6), tanshinone Ⅰ(95-4); one isoflavone: 7, 3'-dihydroxyl-5' methoxyisoflavone (95-14) and protocaechuic aldehyde (95-9), protocaechuic acid (95-11), astragaloside Ⅳ(50-4), amygdalin (50-5), 2, 3, 5, 4'-tetrahydroxylstilbene-2-0-β-D-glucoside (50-3),-catechin (50-2), cinnamic acid (95-8). Among them, 3'-dihydroxyl-5' methoxyisoflavone (95-14) is a new compound.

经过溶剂萃取、大孔吸附树脂富集、Sephadex LH-20精制、制备TLC及Semi-pre HPLC等手段从中分离了20个化合物，利用理化性质和波谱技术(UV、IR、EI／MS、ESI／MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC)相结合鉴定了它们的结构，分别为9种蒽醌类化合物：大黄酚，大黄素甲醚，大黄素，芦荟大黄素，大黄酸，番泻苷A或B，ω-羟基大黄素(ω-hydroxylemodin)，大黄酚-8-0-β-D-葡萄糖苷(chrysophanol-8-0-β-D-glucoside)，芦荟大黄素-ω-0-β-D-葡萄糖苷(aloemodin-ω-0-β-D-glucoside)；3种菲醌类化合物：丹参酮ⅡA(tanshinoneⅡA)，隐丹参酮，丹参酮Ⅰ(tanshinone Ⅰ)；1种异黄酮：7，3'-二羟基-5'-甲氧基异黄酮（7，3'-dihydroxy-5' methoxyisofla-vone）以及原儿茶醛，原儿茶酸，黄芪甲苷(astragaloside Ⅳ)，苦杏仁苷，2，3，5，4'-四羟基二苯乙烯-2-0-β-D-葡萄糖苷（2，3，5，4'-tetrahydroxylstilbene-2-O-β-D-g1ucoside），Z—儿茶素，桂皮酸。

Jiangsu Rixin Enterprise Group Co.,Ltd is a leading manufacturer of dyestuff intermediate. Its products includes 1-amino anthraquinone、 Pyrazone anthrone 、Desperse red 92#、1-Nitroanthraquinone etc.

江苏日欣集团是国内主要的染料中间体的生产厂家之一，其主要产品在国内占有重要的地位，产品有：1-氨基蒽醌、吡唑蒽酮、分散92#红、1-硝基蒽醌等。

Yangzhou Rixing Biochemical Products Co.,Ltd is a leading manufacturer of dyestuff intermediate. Its products includes 1-amino anthraquinone、 Pyrazone anthrone 、Desperse red 92#、1-Nitroanthraquinone etc.

扬州日兴生物化工制品有限公司是国内主要的染料中间体的生产厂家之一，其主要产品在国内占有重要的地位，产品有：1-氨基蒽醌、吡唑蒽酮、分散92#红、1-硝基蒽醌等。

When anthrone react with aryl aldehyde in the presence of pyridine by using xylene as the solvent,besides 10 arylmethylene anthrone derivatives we found other oxygenated anthrone which have not been reported.

发现其生成物中除含有目标化合物 1 0 -芳香基甲叉基蒽酮外，还含有部分文献中没有报道的蒽酮氧化物，经物理方法确定其为蒽醌。

Based on this result, a new technology is suggested, that is by regulating the effective sulphonating contents of 1-amino-anthraquinone, adjusting the concentration of sulfuric acid to hydrolyze 1-amino-anthraquinone disulfonic acid conversing to 1-amino-anthraquinone -2-sulfonic acid, and briminating the hydrolyzed product in 100% sulfuric acid, 87% yield of Bromamino-acid was achieved, 10% higher than the conventional method prepared by "oleum method".

此新工艺，溴氨酸在产物中含量可达87％，比常规的发烟硫酸法生产溴氨酸提高了10％，质量和收率都接近或达到溶剂法生产的水平。 1，5-二硝基蒽醌和1，8-二硝基蒽醌是生产分散蓝56、分散蓝73等一系列分散染料重要中间体。

Ib was synthesized by condensation of phthalic anhydride with 2-methylresorcinol in fused AlCl〓/NaCl (5∶1), followed by selective acetylation, methylation, NBS bromination and condensation with sodium ethoxide.

邻苯二甲酸酐在熔融的三氯化铝-氯化钠(5：1)中和-2，6-二羟基甲苯环合得1，3-二羟基-2-甲基蒽醌〓后经选择性乙酰化、甲基化、NBS溴化、乙醇钠缩合得1-甲氧基-2-乙氧甲基-3-羟基蒽醌。

The main metabolites in each reactor were detected by UV/VIS, infrared and high performance liquid chromatography and mass spectrometry. Probably, the mother dye molecule facultatively hydrolyzed to produce 1-NH2-2-hydroxy anthraquinon, OH-substituted anthraquinon and 3,4-dihydroxy-benzonic acid.

对各反应器中主要的代谢产物分别进行紫外-可见、红外和高效液相色-质联谱仪检测分析后发现，母体染料经兼氧水解首先生成1-氨基-2-羟基蒽醌以及还原态的—OH基取代蒽醌隐色体，进一步水解生成3，4-二羟基苯甲酸。

The type and position of substituents affected OWF〓 greatly for naphthoquinone and anthraquinone derivatives.

4取代基类型和取代基位置对OWF〓有较大的影响，如萘醌类发色母体、蒽醌类发色母体等。

Dianthracene was synthesized by reducing the addition product of β-naphthyl- lithium with anthraquinone.

采用还原β-萘基锂与蒽醌的加成物制备了有机电致蓝光材料9，10-二蒽。

And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47：5 法老对约瑟说，你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法，同时，采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。