蒽二醌

A series of novel dendrons with 1,3,5-triazine structure were synthesized by convergent strategy using cyanuric chloride, p-hydroxyazobenzene,β-naphthol, 1-hydroxyanthraquinone, 3,5-dihydroxybenzyl. They were the first generation p-phenyl-azo-phenyloxy-terminated dendron G1.0, the first generation naphthyloxy-terminated dendron G1.0, the first generation naphthyloxy-terminated and 1-anthraquinonoxy-cored dendron G, and the second generation naphthyloxy-terminated dendron G2.0.

以对羟基偶氮苯、β-萘酚为端基，三聚氯氰、3，5-二羟基苄醇为支化单体，1-羟基蒽醌为核心，用收敛法合成了一系列新型结构的含均三嗪环的树枝块：第一代端基为偶氮苯的树枝块G1.0、端基为萘氧基的树枝块G1.0、端基为萘氧基、中心为蒽醌的树枝块G、第二代端基为萘氧基的树枝块G2.0。

The electrolytic oxidation of Cr 3+ to Cr 2O 2- 7 with lead dioxide anode is studied.

应用整体电解法，以二氧化铅为阳极，铜为阴极，对重铬酸钾间接电化学氧化蒽制蒽醌中影响Cr3 +电化学氧化过程电流效率的因素进行了探讨。

The existence of hydrogen bond within or between the molecules of pigment can enhance the perdurability, light fastness and weather resistance.

有机颜料发色母体最主要的是偶氮和酞菁两大类(分别为50%和25%)，其余25%的颜料属于杂环的发色体：喹吖啶酮、异吲哚啉与异吲哚啉酮、苝、喹酞酮、二噁嗪、吡咯并吡咯二酮、金属络合颜料、靛族和稠环酮颜料(如：蒽醌、黄蒽酮、皮蒽酮等)。

To further study the chemical constitutes of lipophilic active parts, we prepared Alc95% and Alc50% according to original literature. 20 compounds were isolated by using macroporous resin, silica gel, polyamide, Sephadex LH-20, Rp-18, preparative TLC and preparative HPLC chromato-graphy. The structures of them were elucidated by means of physical and chemical properties, modern spectroscopic analysis techniques—UV、IR、 EI/MS、ESI/MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC. They are nine anthraquinones: chrysophanol (95-1), physcion (95-2), emodin (95-5), aloemodin (95-7), rhein (50-1), sennoside A or B (50-6),ω-hydroxylemodin (95-10), chrysophanol-8-0-β-D-glucoside (95-12), aloemodin-ω-0-β-D-glucoside (95-13); three phenanthaquinones: tanshinone ⅡA (95-3), cryptotanshinone (95-6), tanshinone Ⅰ(95-4); one isoflavone: 7, 3'-dihydroxyl-5' methoxyisoflavone (95-14) and protocaechuic aldehyde (95-9), protocaechuic acid (95-11), astragaloside Ⅳ(50-4), amygdalin (50-5), 2, 3, 5, 4'-tetrahydroxylstilbene-2-0-β-D-glucoside (50-3),-catechin (50-2), cinnamic acid (95-8). Among them, 3'-dihydroxyl-5' methoxyisoflavone (95-14) is a new compound.

经过溶剂萃取、大孔吸附树脂富集、Sephadex LH-20精制、制备TLC及Semi-pre HPLC等手段从中分离了20个化合物，利用理化性质和波谱技术(UV、IR、EI／MS、ESI／MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC)相结合鉴定了它们的结构，分别为9种蒽醌类化合物：大黄酚，大黄素甲醚，大黄素，芦荟大黄素，大黄酸，番泻苷A或B，ω-羟基大黄素(ω-hydroxylemodin)，大黄酚-8-0-β-D-葡萄糖苷(chrysophanol-8-0-β-D-glucoside)，芦荟大黄素-ω-0-β-D-葡萄糖苷(aloemodin-ω-0-β-D-glucoside)；3种菲醌类化合物：丹参酮ⅡA(tanshinoneⅡA)，隐丹参酮，丹参酮Ⅰ(tanshinone Ⅰ)；1种异黄酮：7，3'-二羟基-5'-甲氧基异黄酮（7，3'-dihydroxy-5' methoxyisofla-vone）以及原儿茶醛，原儿茶酸，黄芪甲苷(astragaloside Ⅳ)，苦杏仁苷，2，3，5，4'-四羟基二苯乙烯-2-0-β-D-葡萄糖苷（2，3，5，4'-tetrahydroxylstilbene-2-O-β-D-g1ucoside），Z—儿茶素，桂皮酸。

In the presence of acetic acid and polyethylene glycol, anthracene reacted with ammonium ceric nitrate and sodium bromate to form anthraquinone.

在醋酸、聚乙二醇存在下，蒽与硝酸铈铵和溴酸钠反应生成蒽醌，聚乙二醇作为相转移催化剂可以提高反应的选择性。

In the prepared process, 1,8- dihydric anthraquinone and 2,3,5,4-tetrahydroxystilbene-2- O-3 -D-glucoside were chosen as detected targets, the quality of 4 prepared method, high pressure steamed method, prepared method with beans, prepared method with ginger, prepared method with yellow wine, was compared.

以1，8-二羟基蒽醌和二苯乙烯甙作为检测指标，对黑豆炮制法、姜制法、酒制法和高压清蒸法四种方法进行比较，发现高压清蒸法得到的产品中游离态蒽醌和二苯乙烯甙含量最高，分别是其它三种炮制品的1.78～1.84倍和1.06～1.61倍。

Based on this result, a new technology is suggested, that is by regulating the effective sulphonating contents of 1-amino-anthraquinone, adjusting the concentration of sulfuric acid to hydrolyze 1-amino-anthraquinone disulfonic acid conversing to 1-amino-anthraquinone -2-sulfonic acid, and briminating the hydrolyzed product in 100% sulfuric acid, 87% yield of Bromamino-acid was achieved, 10% higher than the conventional method prepared by "oleum method".

此新工艺，溴氨酸在产物中含量可达87％，比常规的发烟硫酸法生产溴氨酸提高了10％，质量和收率都接近或达到溶剂法生产的水平。 1，5-二硝基蒽醌和1，8-二硝基蒽醌是生产分散蓝56、分散蓝73等一系列分散染料重要中间体。

Ib was synthesized by condensation of phthalic anhydride with 2-methylresorcinol in fused AlCl〓/NaCl (5∶1), followed by selective acetylation, methylation, NBS bromination and condensation with sodium ethoxide.

邻苯二甲酸酐在熔融的三氯化铝-氯化钠(5：1)中和-2，6-二羟基甲苯环合得1，3-二羟基-2-甲基蒽醌〓后经选择性乙酰化、甲基化、NBS溴化、乙醇钠缩合得1-甲氧基-2-乙氧甲基-3-羟基蒽醌。

The main metabolites in each reactor were detected by UV/VIS, infrared and high performance liquid chromatography and mass spectrometry. Probably, the mother dye molecule facultatively hydrolyzed to produce 1-NH2-2-hydroxy anthraquinon, OH-substituted anthraquinon and 3,4-dihydroxy-benzonic acid.

对各反应器中主要的代谢产物分别进行紫外-可见、红外和高效液相色-质联谱仪检测分析后发现，母体染料经兼氧水解首先生成1-氨基-2-羟基蒽醌以及还原态的—OH基取代蒽醌隐色体，进一步水解生成3，4-二羟基苯甲酸。

The blue crosslinking polymeric dyes were synthesized with use of leucoquinizarin and polyvinylamine prepared from the Hofmann degradation of polyacrylamide. The maximum wave length was 597nm. The effects of temperature, the concentration of amino group, the pH value and the mole ratio of leucoquinizarin to amino group on the yield of red crosslinking polymeric dye were discussed.

以具有不同聚合度和不同胺化度的聚乙烯胺为骨架，以1，4—二羟基蒽醌隐色体为原料合成了蓝色可交联高分子染料，该染料的最大吸收波长为597nm，研究了反应温度、氨基浓度、pH值以及1，4—二羟基蒽醌隐色体与聚乙烯胺中氨基的摩尔比对反应的影响。

And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47：5 法老对约瑟说，你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法，同时，采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。