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萘酚

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A series of novel dendrons with 1,3,5-triazine structure were synthesized by convergent strategy using cyanuric chloride, p-hydroxyazobenzene,β-naphthol, 1-hydroxyanthraquinone, 3,5-dihydroxybenzyl. They were the first generation p-phenyl-azo-phenyloxy-terminated dendron G1.0, the first generation naphthyloxy-terminated dendron G1.0, the first generation naphthyloxy-terminated and 1-anthraquinonoxy-cored dendron G, and the second generation naphthyloxy-terminated dendron G2.0.

以对羟基偶氮苯、β-萘酚为端基,三聚氯氰、3,5-二羟基苄醇为支化单体,1-羟基蒽醌为核心,用收敛法合成了一系列新型结构的含均三嗪环的树枝块:第一代端基为偶氮苯的树枝块G1.0、端基为萘氧基的树枝块G1.0、端基为萘氧基、中心为蒽醌的树枝块G、第二代端基为萘氧基的树枝块G2.0。

Two different catalysts for oxidative coupling of 2-naphthol to give racemic 1,1′-binaphthene-2,2'-diol were introduced and the yields in different conditions were studied.

介绍了两种在水相中利用2-萘酚氧化偶合制备外消旋1,1'-联-2,2'-二萘酚的催化剂,并对不同反应条件下的产率进行了研究。

Methods: Solubility and water oil distribution coefficient of the complex were studied, and compared with kaempferol-3-O-rutinoside.

制备山萘酚-3-O-芸香糖苷的磷脂复合物,测定其与山萘酚-3-O-芸香糖苷的溶解度,并对两者的水油分配系数进行分析。

It was proved that host CP44 can recognize the isomers, a-naphthol and β-naphthol by fluorescence probe.

荧光探针表明:主体CP44能对α-萘酚、β-萘酚同分异构体进行分子识别。

An isomeric form of naphthol,C10H7OH,occurring as white crystals and used in making antioxidants,pigments,and dyes .

萘酚萘酚的一种异构体,C10H7OH,以白色结晶体存在并用于制造抗氧化剂、色素和染料

The host CP66 is found to recognize the isomer of naphthol by using a fluorescence probe.

荧光探针测试表明,主体CP66能对α-萘酚、β-萘酚同分异构体进行分子识别。

Based on theoretical calculation of electronegativity of groups offlotation-reagent and method of infra-red adsorption spectroscopy, the collection andadsorption of α-nitroso-β-naphthol in hematite flotation have been studied. The chemicaladsorption seems to be predominant owing to formation of pentacyclic nitrosyl chelate com-pound by atoms of nitrosyl bond in α-nitroso-β-naphthol together with Fe~(3+) on hematitesurface.

研究了α-亚硝基β-萘酚对赤铁矿的捕收性能及吸附规律,导出了吸附方程和吸附速率方程用药剂基团电负性理论计算以及红外吸收光谱法论述了其作用机理α-亚硝基β—萘酚主要是以N O键合原子与赤铁矿表面的Fe形成N O五元环螯合物而化学吸附。

The function mechanism among the minerals and floatation drugs had been studied with the way of IR and academic calculation, which pointed out that absorption of G-4 on the surface of phosphorite belonged to physical and chemical types, but the chemical one was in the highest flight. Absorption of amine collector named GE-609 on the surface of quartz belonged to electrostatic and physical type. Distilled water could hardly wash the GE-609 down from the surface of quartz. Leading component of S-721 was the concentrated compound of naphthol sulfonic acid and formaldehyde. The compound had a stronger affinity to the Mg~(2+) on surface of dolomite than the Ca2+ on surface of phosphorite, which is the essential reason in the separation of phosphorite and dolomite. The leading components of soluble glass in function were HSiO3 hydronium and F^SiC^ colloid granule.

通过红外光谱测定以及理论计算的方法研究了选矿药剂与矿物间的作用机理,研究表明:脂肪酸捕收剂G-4对胶磷矿的捕收作用是以化学吸附为主、化学吸附与物理吸附共同作用的结果;胺类阳离子捕收剂GE-609在石英表面的吸附属于静电物理吸附,但很难用水洗的方法使GE-609从石英表面脱附;S-721主要成分为萘酚磺酸与甲醛的缩合物,萘酚磺酸与甲醛的缩合物对白云石表面Mg~(2+)的吸附明显强于对胶磷矿表面Ca~(2+)的吸附,这是胶磷矿与白云石分离的根本原因;水玻璃溶液中对石英起抑制作用的主要组分是HSiO_3~-和H_2SiO_3胶粒,水玻璃除对石英起抑制作用外,对矿浆还具有一定的分散作用。

After the diazotization ,2-aminophenol-4-(2-'carboxy)sulfanil phenylamine was coupled with acetoacetanilide,2-naphthol,1-phenyl-3-methyl-5-pyrazolone,1-naphthol-4-sulfonic acid,separately to get the different diazotized compounds,then complexed with potassium chromium sulfate or cobaltous chloride to obtain the yellow,orange,red,purple,blue and other colour dyestuffs.

2-氨基苯酚-4-(2'-羧基)磺酰苯胺重氮化,分别与乙酰乙酰苯胺、2—萘酚、1-苯基-3-甲基-5-吡唑啉酮、尼文酸、1-乙酰氨基-7-萘酚等偶合,得到不同的偶氮化合物,然后分别与硫酸铬或氯化钴进行络合反应,得到黄、橙、红、紫、蓝多种颜色染料,并进行了毛织品的染色实验。

Under the selected chromatographic operation conditions, the 2,2'-Dihydroxy-1,1'-binaphthyl, 2-Naphthol and other impurities could be separated efficiently.

在选定的色谱条件下,1,1'-联-2-萘酚和2-萘酚等杂质之间具有较好的分离效果。

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