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By adopting the technology of coinstantaneously synthesizing the two products, the optimal reaction conditions are molar ratio of 1∶1 for MN to BA, in the presence of 10 7 % of catalyst at 80 ℃ for 5 h.

本文采用气-质联用技术作为烷基化工艺的评价手段[4 ] ,研究了三氯化铝催化甲基萘的长链烷基化,考察了催化剂用量、芳烷摩尔比

A series of 3-naphthyl-2--1,3-thiazolidin-4-ones were synthesized by the three-component one-pot cyclocondensation of naphthylamine, aromatic aldehyde and 2-mercaptoacetic acid using a microwave-assisted method in the presence of DMAP/DCC.

利用微波促进的多组分一锅法,在封管条件下,以萘胺、芳醛和巯基乙酸为原料,4-二甲氨基吡啶/N,N'-二环已基碳二亚胺为催化剂,合成了系列新的噻唑烷酮衍生物,该反应具有时间短、操作简便等优点。

2 Mm were compared using the Lipophilic Hydrophilic Ratio concept which was defined on the basis of the Washburn equation, and their surface free energy component s were also estimated using the Washburn equation and van Oss-Chaudhurry-Good theory with n-hexane,α-bromonaphthalene, formamide and water as probe liquids.

2mm无烟煤、锰砂和石英砂滤料的润湿性;同时以正己烷、1-溴萘、甲酰胺和去离子水为探针液,用Washburn方程和vanOss-Chaudhurry-Good理论对滤料表面自由能成分进行了估算。

The photocycloaddition of 1-naphthonitrile (1-NpCN) and 2,3-dimethyl-2-butene in cyclohexane or benzene gave cyclobutane 3 primarily,but that of 2-NpCN gave azetine 6 asthe major and cyclobutane 5 as the minor product in low conversion photolysis.

在低转化光解情况下,1-萘甲腈(1-NpCN)和2,3-二甲基丁烯-2在环已烷或苯中的光环加成反应主要得到环丁烷3,但2-NpCN主要得到氮杂环丁烯6和少量的环丁烷5,三氟醋酸量增加抑制1-NpCN和DMB的光环加成反应,表明TFA与基态及单激发态1-NpCN生成非光反应的复合物,它也淬灭(1-NpCN-DMB)激基复合物。

The photocycloaddn. of 1-naphthonitrile (1-NpCN) and 2,3-dimethyl-2-butene in cyclohexane or benzene gave cyclobutane I primarily, but that of 2-NpCN gave azetine II as the major and cyclobutane III as the minor product in low conversion photolysis. The photocycloaddn. of 1-NpCN with DMB is retarded by increasing amts. of trifluoroacetic acid which is shown to form non-photoreactive complexes with ground state as well as with singlet excited state 1-NpCN. It also quenches the *(1-NpCN-DMB) exciplex.

在低转光解情况下,1-萘甲腈(1-NpCN)和2,3-二甲基丁烯-2在环已烷或苯中的光环加成反应主要得到环丁烷3,但2-NpCN主要得到氨杂环丁烯6和少量的环丁烷5,三氟醋酸量增加抑制1-NpCN和DMB的光环加成反应,表明TFA与基态及单激发态1-NpCN生成非光反应的复合物,它也淬灭^*(1-NpCN-DMB)激基复合物。

The gas phase oxidative cracking processes of decalin and cyclohexane were investigated by using the quartz tube reactor at atmospheric pressure.

采用石英管反应器,在常压下研究了十氢萘和环己烷的气相氧化裂解过程。

With benzoic acid, terephthalic acid, 2. 6naphthalene dicarboxylic acid, dimethyl-2, 6-naphthalene dicarboxylate as solutes, water, acetic acid, N, N-dimethylformamide, N, N-dimethylacemide, dimethyl sulphoxide, N-methl2-ketopyrolidine, and the mixture of water and acetic acid as solvents respectively, the solubilities of 15 binary systems and 4 ternary systems were determined.

实验以苯甲酸、对苯二甲酸、2,6-NDCA、2,6-萘二甲酸二甲酯为溶质,以水、醋酸、N,N-二甲基甲酰胺、N,N-二甲基乙酰胺、二甲基亚砜、N-甲基-2-吡咯烷酮以及水和醋酸的混合溶液为溶剂,测定了十五个二元物系和四个三元物系的溶解度数据。

Computation was made to investigate the solidification points of three isomers of hexadecane and the mixtures of hexadecane with two different alkyl naphthalenes by molecular dynamics.

利用分子动力学模拟手段对十六烷的3种异构体及添加烷基萘的混合物的凝点进行计算。

Computation was made to investigate the solidification point s of three isomers of hexadecane and the mixtures of hexadecane with two different alkyl naphthalenes by molecular dynamics.

利用分子动力学模拟手段对十六烷的3种异构体及添加烷基萘的混合物的凝点进行计算。

Their physic-chemical properties were determined by XRD, BET, H2-TPR and XPS, and their catalytic performance were evaluated through the hydrotreating reaction with thiophene or tetralin as feedstock.

采用XRD、BET、H2-TPR和XPS等表征方法对氮化物的理化性质进行研究;并以噻吩和四氢萘的环己烷溶液为原料,考察氮化物作为加氢催化剂的加氢精制性能。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

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