萘烷

ResultsOne hundred and thirty-one kinds of chemical constituents in micro-milling of Poria Cocos were separated ; of which sixty-seven compounds representing 51.145% of the oil were characterized. Relative contents that were more than 2% were determined as Nonanal 2.058%,Camphor 2.401%,2,3-dimethyl Decalin 3.819%,trans-Nerolidol 2.266%,Farnesol 3.322%,α-Cedrol 7.936%.

结果茯苓超微粉中分离出131个成分，鉴定出67个化学成分，占挥发油总量的51.145%，其中相对百分含量大于2%的分别确定为壬醛Nonanal 2.058%；樟脑Camphor 2.401%；2，3-二甲基萘烷 2，3-dimethyl Decalin 3.819%；反橙花叔醇trans-Nerolidol 2.266%；金合欢醇 Farnesol 3.322%；α-柏木醇α-Cedrol 7.936%。

The present invention relates to compounds of formula wherein R is hydrogen, lower alkyl, lower alkoxy, halogen or lower alkyl substituted by halogen; R is hydrogen or halogen; or R and R are together with the carbon atom to which they are attached -CH=CH-CH=CH-; R is hydrogen, lower alkyl, phenyl optionally substituted by halogen, or is hetaryl, optionally substituted by lower alkyl; R is hydrogen, lower alkyl, phenyl, benzyl, lower alkenyl, lower alkoxy, phenyloxy, benzyloxy, S-lower alkyl, halogen, CN, lower alkyl substituted by halogen or O-lower alkyl substituted by halogen; R is hydrogen or lower alkyl, aryl is phenyl or naphthyl; n is 1, 2 or 3; m is 1 or 2; and pharmaceutically acceptable acid addition salts and tautomeric forms thereof.

本发明涉及式化合物及其可药用的酸加成盐和互变异构形式，其中R 1 是氢、低级烷基、低级烷氧基、卤素或被卤素取代的低级烷基；R是氢或卤素；或R 1 和R与它们连接的碳原子一起是-CH＝CH-CH＝CH-；R 2 是氢、低级烷基、任选被卤素取代的苯基或者是任选被低级烷基取代的杂芳基；R 3 是氢、低级烷基、苯基、苄基、低级链烯基、低级烷氧基、苯氧基、苄氧基、S-低级烷基、卤素、CN、被卤素取代的低级烷基或被卤素取代的O-低级烷基；R 4 是氢或低级烷基，芳基是苯基或萘基；n是1、2或3；m是1或2。

In this chapter, the MPV reactions catalyzed by alkoxy dysprosium is used to the reduction of prochiral ketones. The chiral alkoxy catalyst was prepared by chiral binaphthol and Dy 〓.

最后还将烷氧基镝催化下的MPV还原反应应用于潜手性酮的不对称还原，利用光学活性的联萘酚制备了手性烷氧基催化剂，结果表明该催化剂可有效地催化潜手性酮的不对称MPV还原。

In the fifth chapter, six compounds formed between nitrogen-containing ligands such as 2, 2'-bipyridyl, isonicotinamide and 1, 4, 8, 11-tetraazacyclotetradecane and the solution cadmium sulfonates such as 1, 5-naphthalenedisulfonate, 2, 6-naphthalenedisulfonate, 4, 4'-bipenyldisulfonate and 4, 4'-penyletherdisulfonate have been synthesized and structurally characterized. Besides, another compound has been synthesized with cadmium carbonate reacting with 1, 5-naphthalenedisulfonate acid.

第五章以2，2'-联吡啶、异烟酰胺和1，4，8，11-四氮杂环十四癸烷与含有Cd〓和1，5-萘二磺酸根离子、2，6-萘二磺酸根离子、4，4'-联苯二磺酸根离子和4，4'-苯醚二磺酸根离子的水溶液反应，合成了六个化合物，另外以1，5-萘二磺酸与碳酸镉反应合成出一个化合物。

After this research work, we know that: HMCM-22 is a better catalyst of selecting naphthalene alkylation; Surface modification of zeolite Y is effective, but the effect of zeolite 3 is not evident and surface modification doesn"t suits mordenite; Surface modification doesn"t affect the frameworks and inner environments of zeolites, but only reduces diameter of orifice and overlays surface acidities; t-butanol is not suitable for alkylating agent of the reaction using modified zeolites as catalyst; Solvents with smaller molecular size are advantageous for naphthalene alkylation reaction using modified zeolites as catalyst, such as cyclohexane is better than decalin.

通过本论文的研究，我们知道：HMCM-22是萘择形烷基化反应较好的沸石之一；Y沸石的外表面改性效果较好，β沸石则效果不明显，而丝光沸石则不适于外表面改性；外表面改性不改变沸石的骨架结构和孔道内部环境，仅减小孔口直径和覆盖外表面酸性位；叔丁醇不适于作外表面改性沸石催化的反应的烷基化试剂，其反应活性很低，且选择性无明显提升；分子较小的溶剂更适于外表面改性沸石催化的反应，环己烷就明显好于十氢萘。

The strain TV9704 does not use dodecane,hexadecane,liquid paraffin,diesel and naphthalene as carbon source and energy for its growth,therefore the oil consumption value was not obviously decreased;comparatively,thiophene or dibenzothiophenewas the only carbon source,sulfur source and en...

这一菌株不能以正十二烷、正十六烷、液体石蜡、萘和柴油为碳源和能源生长，因此不会明显地损失石油的燃烧值；但它能利用噻吩或二苯并噻吩作为唯一硫源来生长。

The present doctoral dissertation was carried out to study the chemical constituents isolated from stems of two medicinal schisandraceous plants.34 compounds were isolated from the ethanol extracts of the stems S.henryi collected in the Jiangxi province by various column chromatographies.27 of them were identified on the basis of spectral analysis.There are 18 lignans,(including 5 dibenzocyclooctadienes,6 aryltetralins,2 tetrahydrofurans,3 diarylbutanes,2 other lignans),3 flavanols,2 glyceroesters,1 naphthoquinone,1 xanthine and 2 steroids,of which 6 compounds were new compounds,and 7 compounds were isolated from this family for the first time.

采用多种色谱技术进行分离纯化，从翼梗五味子藤茎的乙醇提取物中分离到34个化合物，综合运用现代波谱学技术鉴定了27个化合物，包括木脂素类化合物18个(其中联苯环辛烯类木脂素5个，芳基四氢萘类木脂素6个，四氢呋喃类木脂素2个，二芳基丁烷类3个，其他类型木脂素2个)，黄烷醇类化合物3个，甘油酯类化合物2个，萘醌类化合物1个，黄嘌呤类化合物1个，甾体类化合物2个，其中，5个为新化合物，7个为本科首次报道。

The solid-liquid reaction method was used for the preparation of HPLC aryl-bonded silica gel stationary phases, including 3, 5-dinitrobenzyl, quinolinyl ether and 1, 1'-di(2-naphthol) ether bonded silica gel stationary phases by using N-(β-aminoethy1)-γ-aminopropylmethyldimethoxy silane and 3-glyci-doxypropyl trimethoxylsilane as coupling reagents, respectively.

采用固液相连续反应，以N-－γ-氨丙基甲基二甲氧基硅烷和γ-丙基三甲氧基硅烷为偶联剂，分别制备了二硝基苯甲酰胺基、喹啉醚基和联萘酚醚基三种芳基键合硅胶固定相。

Liquid-phase thermal desorption studies of five systems of n-paraffins adsorbed in MS-5A were conducted by tetralin as a thermal carrier.

本文分别通过对含正己烷、正庚烷、正辛烷、正庚烷+正辛烷以及含正己烷+正庚烷+异辛烷的5A分子筛在吸附惰性液体四氢萘中的热脱附实验，取得了这方面的实验数据。

Third, volatilizable parts from Hainan Rauvolfia were obtained through water vapor distillation. They were analyzed by GC/MS. The resuts showed that about 10 compounds in the root essential oil were extracted and 9 of them were identified. Fatty acids and phenol ramification are the main types of the compounds.

用水蒸气蒸馏法获得了萝芙木中的易挥发组分，对其进行了GC/MS分析，分析结果表明，萝芙木根挥发油分离出10个峰，鉴定出9种化合物，其主要成分为9-十八烷酸、十六酸，棕榈酸、9，12-十八烷二酸、1H－萘酚[2，1-b]吡喃-1-酮，分别占挥发油总量的25.66%、19.34%、18.12%、17.23%，四者占其总量的80.35%。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。