萘基

The results also show the sensitivity is enhanced for the pigments with a larger anilide ring. It is important to note that the photosensitivity is greatly increased when the coupler component changed ftom a 2-hydroxy-3-naphthanilide to a 2-hydroxy-11H-benzocarbazole-3-naphthanilide coupler. Clearly, conjugation effects favours to enhance the photosensitivity.

偶合基部分共轭环的扩大使蒽醌偶氮染料的光敏性增加，特别是偶合基萘环上扩大了一个咔唑环后，其吸收光谱大幅红移，光敏性提高了几十倍，这一结果对红外偶氮光导染料的设计合成具有重要参考价值。

The results of UV absorption show that λ max is not sensitive to the electronic effects exerted by the substituent in the coupler moiety. The λ max has a small red-shift when the anilide aromatic ring in the coupler moiety is larger. This indicates that the conjugation effect of the anilide ring with chorosorb is not very significant. It is important to note that a red-shift of 60-130 nm was observed when the coupler component changed from a 2-hydroxy-3-naphthanilide to a 2hydroxy-11H-benzocarbazole-3-naphthanilide coupler. The red-shift may be due to the conjugation resulting from the carbazole ring.

对上述三个系列偶氮染料吸收光谱的研究结果表明，偶合基酰胺芳环共轭环的扩大对偶氮染料在可见光区最大吸收红移作用不是很显著；当偶合基萘环上共轭环扩大了一个咔唑环后，其偶氮染料在可见光区的最大吸收大幅红移，跨入近红外染料行列，这一结果对红外偶氮染料的设计合成具有重要的参照价值。

A series of reactions may occur when the nitrous acid and naphthalene inside the atmospheric aqueous phases is exposed to sunlight. This article devotes to investigating from a microscopic angle the reaction mechanism and kinetics of this system using laser flash photolysis technique with an excitation wavelength of 355nm. The main research results are listed as below:(1) The OH quantum yield FOH for the photolysis of HNO2 in the aqueous phase was determined to be 0.234 and the absorption spectrum of OH radical was recorded as well.

本文以激光闪光光解为主要研究手段，考察了大气液滴中的HNO2及HNO2+萘体系经355nm紫外光照射后发生的微观反应及其机理，结果表明：(1)液滴中的HNO2经355nm光照产生OH自由基的量子产额为FOH=0.234；以瞬态技术记录了水相中的OH自由基的吸收光谱。

A series of 3-naphthyl-2--1,3-thiazolidin-4-ones were synthesized by the three-component one-pot cyclocondensation of naphthylamine, aromatic aldehyde and 2-mercaptoacetic acid using a microwave-assisted method in the presence of DMAP/DCC.

利用微波促进的多组分一锅法，在封管条件下，以萘胺、芳醛和巯基乙酸为原料，4-二甲氨基吡啶/N，N'-二环已基碳二亚胺为催化剂，合成了系列新的噻唑烷酮衍生物，该反应具有时间短、操作简便等优点。

amino-1,4-naphthoquinones failed to be obtained through the classical routes due to the strongly electron-withdrawing nitro group, which deactivating the nucleophilic ability of the nitro anilines.

2-硝基苯胺-1，4-萘醌类衍生物由于硝基的强吸电性使硝基苯胺的亲核性减弱，不能通过经典的加成-氧化或加成-取代的方法合成得到。

The auxiliary can be recovered in high yield (81%) only by filtering and recrystallization. Besides, some other aldehydes have been chosen to test the enantioselectivity of N,N\'-dibenzyl tartamide, in comparison with two other allylaborates reagents developed previously by Roush and Brown, respectively. The results show that %e.e. of homoallylic alcohol is superior to that of the former, and approaches the Brown reagent.

产物经S_N2反应得瑞格列萘中间体-甲基烯丙基-2-氯苯基-叠氮甲烷(17)；同时，将筛选出的新型手性配体N-苄基酒石酸二酰胺用于其他几种醛(正丁醛，异戊醛和环己醛)的不对称烯丙基化反应，并与广泛应用的Roush配体(22)和Brown配体(27)相比较，发现其立体选择性优于Roush配体，并接近Brown配体，但明显具有可回收利用的优势。

A series of novel chiral aminophosphine ligands with binaphthyl backbone and partially reduced binaphthyl backbone were synthesized from optically pure NOBIN and H〓-NOBIN respectively. The effects of binaphthyl backbone and substitutes at the phosphorous atom on Pd (0)-catalyzed allylation of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate were systematically investigated.

从NOBIN出发合成了一系列膦上含有不同取代基的氮膦配体MAPs以及含有被部分还原的联萘骨架的氮膦配体H〓-MAPs，将此两类配体运用于钯催化的乙酸1，3-二苯基烯丙基酯与丙二酸二甲酯的反应中，考查了膦上取代基和配体骨架对反应的影响。

A series of sulfonated poly(arylene thioether/ether phosphine oxide)s was prepared by direct polycondensation of sBFPPO and BFPPO with the diphenol-type or dimercapto-type monomers such as hydroquinone, bisphenol-A, 4,4'-biphenol, 4,4'-diphenol (6F), 1,5-dihydroxynaphthalene, 4,4'-dihydroxybiphenyl, and 4,4'-thiobisbenzenethiol, respectively.

将BFPPO与sBFPPO分别与多种二羟基或二巯基单体，如对苯二酚、双酚A、4，4'-二苯酚、双酚F、1，5'-二羟基萘、4， 4'-二羟基二苯硫醚和4，4'-二巯基二苯硫醚，直接共聚制备了一系列磺化聚芳醚三苯基氧膦，侧重考察了二羟基和二巯基单体结构单元对产物的耐氧化性能的影响。

Moreover, seven ruthenium phenanthroline derivatives were also synthesized. The synthesis of Ru3Cl2 and Ru2AqphenCl2 have not yet been reported, and a new and effective method for the synthesis of Ru32 was also investigated.

本文第二章主要内容是以邻菲咯啉为原料，合成四种刚性结构强的邻菲咯啉衍生物：二吡啶基吩嗪，四吡啶基吩嗪， 10.11-1.4-萘酮－2，3；2'，3'－二吡啶基吩嗪，对羟基苯基并[4，5]-邻菲咯啉。

The results of its fluorescence probe showed that when the guanidine hydrochloride concentration in denaturation solution was about 1.0 mol/L,there existed some stable hydrophobic regions,which could interact with a hydrophobic reagent 8-anilino-1-naphthalene sulfonic acid,in the partially folded intermediate of Bacillus amyloliquefaciensα-amylase;with the denaturation concentration increasing,the stable hydrophobic regions disappered.the results of fluorescence quenching using acrylamide and potassium iodide as quenchers showed that using acrylamide as quenchers,with the protein denaturation extent increasing,the number of Trp that can be quenched increased untill all the Trp residues were quenched;Using potassium iodide as quenchers,with the maximum number(8) of tryptophan residues in a partially folded intermediate Bacillus amyloliquefaciensα-amylase molecule could be quenched by potassium iodide;with the denaturation concentration increasing,the number of Trp that can be quenched decreased to 5.the results of their protein electrophoreses and SEC showed that no aggregate or aggregate precipitation of Bacillus amyloliquefaciensα-amylase formed during the whole unfolding/refolding procedure of Bacillus amyloliquefaciensα-amylase induced by guanidine hydrochloride or urea.

ANS外源荧光探针结果表明：盐酸胍诱导的芽孢杆菌α-淀粉酶分子去折叠过程中存在着能够与探针分子1-苯胺基-8-萘磺酸结合的稳定的疏水区域；而随着芽孢杆菌α-淀粉酶分子在盐酸胍溶液中变性程度的加深，这一疏水区域逐步被瓦解。丙烯酰胺和碘化钾猝灭结果表明：在盐酸胍溶液中，随着芽孢杆菌α-淀粉酶分子变性程度的进一步加深，其分子内能够被丙烯酰胺接近的色氨酸残基逐渐增多，直至全部被猝灭。但位于芽孢杆菌α-淀粉酶分子表面的能够被碘化钾猝灭的色氨酸残基，在中间态芽孢杆菌α-淀粉酶分子中数目达到最大的8个，而随着其分子变性程度的进一步加深，反而减少至5个。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了