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In this process, the electrolylic bath with cationic exchange membrance and leas electrode is used. The cathode liquor is oxalic acid, the anode liquor is diluted sulfuric acid. The process above has following advantages with high yield, top quality, lower cost, no "three wastes" pollution, and no oxalic aldehyde in the product. It is a cleaner and environment-friend technology, and is a development trend for production of glyoxalic acid. Complete analytical process for raw materials, intermediate and final products were established.

本论文通过对乙醛酸合成路线的研究,确定了草酸电解法制乙醛酸的工艺路线,此法采用装有阳离子交换隔膜和铅电极的电解槽,阴极电解液为草酸溶液,阳极电解液为稀硫酸,该工艺具有产品收率高、质量好、成本低、无三废污染、产品中无乙二醛等特点,是一条清洁、绿色工艺,是生产乙醛酸的主要发展方向。

The nanocrystalline film was composed of a three-diminsional network of interconnected particles.Reodx behavior and electrocatalytic activities of the Ti/nano-TiO2 electrode were investigated by cyclic voltammetry from oxalic acid and nitrobenzene to glyoxalic acid and p-aminionphenol. The Ti/Ti redox system,as a medium,shows highly electrocatalytic activities and stable characteristic to indirect electroreduction of organic compounds(e.g.:oxalic acid and nitrobenzene).

循环伏安法研究了纳米TiO2膜电极对草酸还原为乙醛酸、硝基苯还原为对氨基苯酚反应的电催化活性,结果发现纳米膜中的Ti/Ti氧化还原电对起一种中介作用,可使有机物如草酸和硝基苯间接电还原,且电极催化活性高,性能稳定。

The distribution coefficient of oxalic acid was larger than that of glyoxylic acid,and both of them decreased with the pH. The selectivity of oxalic acid to glyoxylic acid also decreased with pH.

在本实验的条件范围内,草酸的分配系数较乙醛酸大,且随溶液pH值的增大而下降,草酸对乙醛酸的分离系数随pH值的增大而减小。

The diluent solution of glyoxylic acid and oxalic acid was used as the separation object.TOA (in n-octanol) was used as the solvent. The extraction characteristics of single acid and two-acid solution were studied,and the influence of pH and the concentration of complexing agent on the distribution coefficients were measured. The suitable mathematic models were proposed to describe the relationship between TOA and carboxylic acid based on assumed extraction reaction in organic phase.

摘 要:以草酸和乙醛酸的稀溶液为分离对象,采用三辛胺为萃取反应剂、正辛醇为稀释剂,研究了单溶质、双溶质有机酸的萃取分离特性,测定了溶液pH值、萃取反应剂的浓度等因素对双溶质有机酸萃取的影响,提出了萃取的化学反应发生在有机相中的假定,建立了TOA萃取草酸的数学模型。

The diluent solution of glyoxylic acid and oxalic acid was used as the separation object. TOA (in n-octanol) was used as the solvent. The extraction characteristics of single acid and two-acid solution were studied, and the influence of pH arid the concentration of complexing agent on the distribution coefficients were measured. The suitable mathematic models were proposed to describe the relationship between TOA and carboxylic acid based on assumed extraction reaction in organic phase.

草酸和乙醛酸的稀溶液为分离对象,采用三辛胺为萃取反应剂、正辛醇为稀释剂,研究了单溶质、双溶质有机酸的萃取分离特性,测定了溶液pH值、萃取反应剂的浓度等因素对双溶质有机酸萃取的影响,提出了萃取的化学反应发生在有机相中的假定,建立了TOA萃取草酸的数学模型。

After 21 hours of reperfusion the size of cerebral infarction and the hydrous content of brain and MPO activity were determined.

异亚丙基莽草酸是从木兰科植物八角茴香中提取的有效成分莽草酸的合成衍生物。

This effect was observed clearly at final concentration between 1 and 10μ mol/L after treating for 24 hours. We concluded that the possible mechanisms of hydroquinone bleaching hyperpigmented skin were through its inhibition of tyrosinase activity at lower concentration and its cytotoxicity at higher one.

提示18α-甘草酸双胺盐、熊果苷的皮肤脱色作用机制与氢醌可能不同,后者低浓度时以抑制酪酸酶活性为主,高浓度时主要是细胞毒,且细胞早期的损伤部位可能发生在树状突。18α-甘草酸双胺盐能否成为一种无细胞毒酪氨酸酶抑制型皮肤脱色剂有待进一步临床加以验证。

Diisopentyl oxalate was synthesized with oxalic acid and isoamyl alcohol as raw materials and sodium bisulfate as catalyst.

草酸和异戊醇为原料,采用硫酸氢钠作催化剂合成草酸二异戊酯。

In this paper, di-isobutyl oxalate was prepared from oxalic acid and isobutyl alcohol using NaHSO_4 and p-toluenesulfonic acid as catalysts.

草酸和异丁醇为原料,在酸性催化剂作用下进行酯化反应合成出一种新型柴油十六烷值改进剂——草酸二异丁酯。

Objective: To establish an improvement of identification method of Monoammonium Glycyrrhizinate in Compound Ammonium Glycyrrhetate Injection.

目的:建立复方甘草酸单铵注射液中甘草酸单铵鉴别方法的改进方法。

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