苯酰胺

In this paper, acetanilide used as start material was chlorosulfonated, then reacted with alkylamines with different length of carbon chain to prepare 4 p-acetylaminophenylsulfonylalkylamine.

本文以乙酰苯胺为起始原料，经氯磺化后分别和不同碳链的正烷基胺反应制得4种不同碳链长度的对乙酰氨基苯磺酰烷基胺，将其水解后制得了对氨基苯磺酰正丁胺、对氨基苯磺酰正辛胺、对氨基苯磺酰正十二胺和对氨基苯磺酰正十八胺。

To explore new synthetic methods, we set out a careful investigation of the reaction of benzimidazolium salt with many nucleophilic agents, including the active aromatic compounds and heteratom nucleophilic agents, and found that the quaternary C=N is not so active; when benzimidazolium salt is reacted with big nitrogen nucleophilic agent? phthalimide, it does not give the expected addition product, instead, produces N-alkyl phthalimide through alkyl-transfermation from benzimidazolium salt to phthalimide.

为了开发新的合成方法，研究了苯并咪唑盐与各种亲核试剂（活泼芳环与杂原子亲核试剂）的反应，发现苯并咪唑盐不与活泼芳环及杂原子亲核试剂发生2位加成反应；在与体积较大的位阻型N亲核试剂邻苯二甲酚亚胺反应时，未得到亲核试剂与极化的C＝N的加成产物，而是得到N烷基化的邻苯二甲酰亚胺，进一步研究表明，苯并咪唑盐将1（3）位N上的烷基转移给了邻苯二甲酰亚胺，并讨论了其反应机理和取代基，溶剂效应。

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3，4-二溴马来酰亚胺进行N-甲基化反应合成3，4-二溴-N-甲基马来酰亚胺的同时，以碳酸二甲酯为甲基化试剂，对3，4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究；考察了1，4-二氮杂双环[2.2.2]辛烷，1，8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响，并应用碳酸二甲酯为甲基化试剂，合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

Huapai products:pchlorophenol,ochlorophenol,2,4dichlorophenol,2,6dichlorophenol,2,4,5trichlorophenol,2,4,6trichlorophenol,4chloro2benzyl phenol,pbromophenol,2,4,6tribromophenol,1chloro4(1,1dimethyl ethyl) benzene ether,3bromoanisole,mbromofluorobenzene,2tetra hydrofuran,αbromo4chloro acetophenone,αbromo4methoxy acetophenone,4chloro benzophenone,4chloro2methylaniline,n(2hydroxyethyl)ethane diamine; n(2aminoethyl)ethanolamine,2,3dibromopropionyl chloride,4bromo benzene sulphonyl chloride,terephthaloyl chloride,isophthaloyl chloride,nchlorosuccinimide,nbromosuccinimide,pchloranil;tetrachloro1,4benzoquinone,5chloroisatin.

华派公司产品：对氯苯酚，邻氯苯酚，2，4二氯苯酚，2，6二氯苯酚，2，4，5三氯苯酚，2，4，6三氯苯酚，4氯2苄基苯酚，对溴苯酚，2，4，6三溴苯酚，对氯苯基叔丁基醚，间溴苯甲醚，间溴氟苯，α溴甲基四氢呋喃，α溴代4氯苯乙酮，α溴4甲氧基苯乙酮，4氯二苯甲酮，4氯2甲基苯胺，N(2羟乙基)乙二胺， 2，3二溴丙酰氯，对溴苯磺酰氯，对苯二甲酰氯，间苯二甲酰氯，N氯代丁二酰亚胺，N溴代丁二酰亚胺，四氯苯醌，5氯靛红。

The test results of acute toxicity were examined with Pearson's degree of fitting. The results indicated that the silkworm was extremely sensitive to Chlorantraniliprole. The median lethal concentration (LC50) was 4.0905×10^(-3) mg/L and median lethal dose (LD50) was 1.1435×10^(-8) mg/larva for the 3rd instar newly exuviated larvae. No toxicity was observed when normal concentrations of Chlorantraniliprole were used to fumigate the silkworm rearing room. Both irrigation and leaf spraying with 1.25×10^(-4) mg/L Chlorantraniliprole solution showed strong systemic transmission properties in root, leaf and whole plant. The residual toxic period of this insecticide to silkworm was very long. Mulberry leaves sprayed with 1.25×10^(-4) mg/L Chlorantraniliprole solution could still cause 100% mortality of the 3 and 5 instar larvae after 60 d. Furthermore, toxic reaction was very quick. The poisoning symptoms emerged within 1~5 h after feeding on the poisonous leaves. The poisoned larvae experienced such symptoms as stopping ingestion, remaining still, vomiting slightly and body atrophy sequentially, and died ultimately.

食下毒力试验结果经Pearson拟合度检验表明，氯虫苯甲酰胺对3龄起蚕的食下致死中浓度(LC50)为4.0905×10^(-3)mg/L，致死中量(LD50)为1.1435×10^(-8)mg/头；药剂在常规浓度下对家蚕无熏蒸毒性；1.25×10^(-4)mg/L稀释药液对桑树根灌和喷叶处理，表现极强的根部、叶部和全株性内吸传导特性；药液对家蚕的残毒期很长，1.25×10^(-4)mg/L稀释药液田间喷雾桑叶，间隔60 d后采叶饲喂3龄和5龄蚕的死亡率均为100%，且中毒反应极快，添食毒叶后1~5 h出现中毒症状，经停止食桑、静伏、少量吐液、蚕体萎缩等过程后陆续死亡。

The application status of high performance engplastics such as PA,PC,PTFE,MPPO,PSU and FRP in ammunition part s including sabots,shell,gas check ring,ammunition case,shell body at home and abroad are presented in detail.

详细介绍了国内外高性能工程塑料如聚酰胺、聚碳酸酯、聚四氟乙烯、改性聚苯醚、聚砜、纤维增强塑料等在弹托、弹带、闭气环、药筒、弹体等多种弹药部件上的应用情况，分析了未来应用发展的趋势，提出了发展其应用的几点建议。

These include the Asiatic Lion , the Bengal Tiger , and the Indian white-rumped vulture , which suffered a near-extinction from ingesting the carrion of diclofenac -treated cattle.

这些物种包括由于摄取二氯苯二磺酰胺 diclofenac 处理过的牛肉而濒临灭绝的印度白尾秃鹰，亚洲狮和孟加拉虎。

We select the polyamide resins, the polyurethane resin mixed with isopropyl alcohol and ethyl acetate component solvent, form the plastic printing ink of non-benzene solvent, use the IGT printability meter, the transmission density meter, the magnetic force mixer and many kinds of measuring instrument, measure the sample printing ink printed on the commonly used package printing film. The performance, the printability and the color characteristic of non-benzene solvent ink for plastic film printing were researched with the development printing ink sample.

结合与之相适应的树脂、颜料和助剂，开发研制了以聚酰胺树脂、聚氨酯树脂与醇、酯混合溶剂形成油墨连结料的无苯型塑料凹印油墨，并结合塑料凹印工艺要求，采用IGT印刷适性仪、透射密度仪、磁力搅拌器等多种测试仪器，通过对各种包装常用承印材料及样品油墨的测试，探讨了研制油墨样品的性能、印刷适性和颜色特性。

The results show that during the development of the oriental tobacco leaves, the activity of acid invertase was decreased; the changes of GS reached its peak in the 20dans in Samsun, but in the 30dans in Basma and Canik ;the activity of PAL was decreased in the 30dans; The content of total nitrogen was decreased with the mature leaves, but nicotine、total carbon and soluble total sugar were increased. Different varieties, carbon and nitrogen metabolism key enzyme activity and the content of metabolites were different.

结果表明，在香料烟叶片发育过程中，酸性转化酶的活性均呈下降趋势；谷氨酰胺合成酶的活性Samsun品种在20d叶龄时最高，而Basma和Canik在30d叶龄时最高；苯丙氨酸解氨酶的活性均表现为30d时最低；随着叶片成熟总氮含量降低，烟碱含量升高，总碳、可溶性总糖随着叶片成熟其含量呈升高趋势；品种不同，碳氮代谢关键酶的活性及代谢产物的含量变化均有很大差异。

With the promotion of Lewis acid,these aziridines were readily hydrolyzed to generateα-chloro-phenyl-acetamide.

在Lewis酸的存在下，产物很容易进行水解反应，生成氯代的苯乙酰胺。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。