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Electron-withdrawing groups (F, CF 3 ) decreased the efficiency of the transformation, which has as byproducts benzonitrile and phenethyl N -acetamide.

电子集团撤回(六,比照3)转换效率降低,而作为副产品和苯氮苯甲-乙酰胺。

In this thesis, a series of benzamides and thioureas derivatives have been designed and prepared. By reasonable photoreaction conditions, a series of benzophenone and quinazoline compounds have been synthesized and structurally determined by NMR, MS and X-ray crystallography, respectively.

本文设计并合成了一系列苯甲酰胺和硫脲衍生物,通过选择合理的光反应条件,合成了一系列二苯甲酮和喹唑啉类化合物,应用核磁、质谱以及X-射线衍射技术对这些化合物的结构进行表征。

The results indicate that the carbon and the oxygen in the —COOH group,and the nitron in —2—NH group come into formation of different large π bonds with the benzene rings,and there is a dihedral angle of 63.2° because of place blocking and conjugate effect.

结果显示,该分子羧基的碳氧原子、磺酰胺基的氮原子与苯环形成不同的离域大π键,空间位阻效应和共轭效应使两个苯环不在同一平面,二面角为63.2°。

Soluble PANt (=0. 49dl/g) in NMP was used tocopolymerize with -COCI terminated low molecular weight poly- to - phenylene terephathalamide. Through elemental analysis the molecular wd...

我们还用聚苯胺([η]=0.49dl/g)与-COCI封端的果对苯二甲酰对苯二胺进行嵌段共聚,经过产物的元素分析与计算结果比较,确定出特性黏数为0.49dl/g的聚苯胺平均分子量。

It includes the following steps: polymerizing 2, 4-dihydroxyl metaphenylene diamine hydrochloride, diamine monomer and dipic acid anhydride to gain the polyimide that contains hydroxy on the molecule chain, making the hydroxyl take esterification reacting with acyl chloride and acrylic acid to gain polyimide photosensitive material that has negative photonasty.

该聚酰亚胺光敏材料以2,4-二羟基间苯二胺盐酸盐,二胺单体和二酸酐为原料进行聚合,得到分子链上含羟基的聚酰亚胺,然后使羟基与丙烯酸及其衍生物的酰氯发生酯化反应,得到具有负性感光性能的聚酰亚胺光敏材料。

Some research and analysis on the reaction of 2,4-difluoronitrobenzene and nucleophilic reagent alcohol sodium (methyl alcohol ,ethyl alcohol, propyl alcohol, n-butyl alcohol, t-butyl alcohol, et hl) and the reaction choice of opposite -F in different solvent and conditions have done in this paper.

论文以2,4-二氟硝基苯为主要原料,研究了其与亲核试剂醇钠(甲醇、乙醇、丙醇、正丁醇、叔丁醇等)在不同溶剂中的反应情况,讨论了在几种代表性的溶剂——醇、四氢呋喃、苯、N,N-二甲基甲酰胺中亲核取代反应的情况,研究了温度、反应时间、亲核试剂、溶剂等条件对亲核取代反应的影响。

N-(1-Naphthyl)ethylenediamine dihydrochloride solution was injected into the mixed flow of the water sample and sulfanilamide solution. Red dye formed by the reactions was spectrophotometrically detected at lλmax 540 nm.

将N-(1-萘基)乙二胺二盐酸盐溶液注入到水样和对氨基苯磺酰胺溶液的混合流,在lλmax 540nm处对反应形成的红色染料进行分光光度检测。

N-1-Naphthylethylenediamine dihydrochloride solution was injected into the mixed flow of the water sample and sulfanilamide solution. Red dye formed by the reactions was spectrophotometrically detected at lλmax 540 nm.

将N-1-萘基乙二胺二盐酸盐溶液注入到水样和对氨基苯磺酰胺溶液的混合流,在lλmax 540nm处对反应形成的红色染料进行分光光度检测。

Four new chiral sulfonamide alcohol s were synthesized from camphor and L-phenylalanine and their application to the enantioselective addition of diethylzinc to benzaldehyde was described.

由天然樟脑和-苯丙氨酸合成了4个新的手性磺酰胺醇,并对其在二乙基锌对苯甲醛的不对称加成中的催化性能进行了研究。

Four new chiral sulfonamide alcohols were synthesized from camphor and L-phenylalanine and their application to the enantioselective addition of diethylzinc to benzaldehyde was described.

由天然樟脑和-苯丙氨酸合成了4个新的手性磺酰胺醇,并对其在二乙基锌对苯甲醛的不对称加成中的催化性能进行了研究。

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