苯胺衍生物

In addition, ioding was found to be an efficient catalyst for the imino Diels-Alder reaction of N-arylimine and enol ethers and the reaction provided tertrahydroqinolines in good yields. One pot synthesis of tetrahydroqinolines from aldehyde, aniline and enol ethers was also achieved using iodine as the catalyst. The chemical yield of the"one pot"reaction was comparable with that obtained using preformed N-arylimine.

此外我们也发现碘能够有效地催化N-芳基亚胺与烯醇醚的Diels-Alder反应，以很高的化学收率得到了四氢喹啉衍生物，并且发现碘也能够直接催化芳香醛、苯胺、烯醇醚的三组分"一锅"反应，获得的化学产率与使用预制的N-芳基亚胺相当。

METHODS: Heparin with an aldehyde group as reducing end was prepared by nitrous acid degradation method.

将肝素钠用亚硝酸降解法降解，得到还原末端为醛基的肝素，分别溶解于二甲亚砜、含0.05 mL，0.5 mL冰醋酸的二甲亚砜溶液，再与对巯基苯胺发生还原胺化反应，用氰基硼氢化钠作还原剂，得到带巯基的肝素衍生物。

Methods Using 4-chloro-2-nitroaniline as a starting compound, followed by substitution, reductive cyclization, oxidation, and chlorination, to give the key intermediate 2,7-dichloroquinoxaline (7), which reacted with different phenolic compounds to afford quinoxaline derivatives.

方法以4氯2硝基苯胺为起始原料经取代、还原关环、氧化、和氯代合成了中间体2，7二氯喹喔啉(7)，再在喹喔啉的2位引入不同的取代酚结构单元，合成了一系列共9个新喹喔啉衍生物。

The adsorption orientations of benzene derivatives, thiophenol, 4-aminothiophenol and 1,4-dithiobenzene, were investigated on the surfaces of roughened Ag electrodes by using surface-enhanced Raman spectroscopy.

采用表面增强拉曼光谱技术研究了苯硫酚及其功能衍生物，对巯基苯胺和对苯硫酚在粗糙银电极上的吸附取向特征。

Research progress in the conductive high polymer of AXda010004 gathers the aniline in the metal antiseptically The conductive high polymer of survey gathers the aniline and research progress in the antiseptic respect of metal of derivative , have summarized the antiseptic mechanism put forward at present, and look into the distance to its application prospect .

综述了导电高分子聚苯胺及其衍生物在金属防腐方面的研究进展，总结了目前所提出的防腐机理，并对其应用前景作了展望。

According to the result, we believed that the reason resulted in the low sensitivity was that the marker residue compound MQCA structure has changed after conjugated with protein and the antibody induced by the conjugation could not recognize the free MQCA in the ci-ELISA. Therefore we designed some hapten which could reserve the marker residue structural speciality mostly. After synthesis route selection and optimum, the hapten 7-Hydroxymethyl-3-methyl-quinoxaline-2-carboxylic acid was synthesized, used 4-methyl-2-nitroaniline as the start material via six steps, such as oxidation cyclization, bromize reaction, hydrolysis, Beirut reaction, reduction, hydrolysis. This work established basis for producing the high affinity antibody and developing the sensitive ELISA residue detection method.

本论文认为导致ELISA检测灵敏度较低的原因，是残留标示物和蛋白偶联后的特征结构发生改变，诱导产生的抗体不能够对游离MQCA很好的识别，因此，本论文设计了能够最大化保留MQCA结构特征的系列半抗原结构，并对其合成路线进行了筛选和优化，最终以对甲基邻硝基苯胺为起始原料，经氧化环化、溴代、水解、Beirut缩合、还原、水解六步反应制备含羟甲基结构的MQCA衍生物7-羟基甲基-3-甲基-喹噁啉-2-羧酸，为制备对游离残留标示物高亲和力的抗体，高灵敏度的ELISA残留检测方法的建立奠定基础。

In addition, ioding was found to be an efficient catalyst for the imino Diels-Alder reaction of N-arylimine and enol ethers and the reaction provided tertrahydroqinolines in good yields. One pot synthesis of tetrahydroqinolines from aldehyde, aniline and enol ethers was also achieved using iodine as the catalyst. The chemical yield of the"one pot"reaction was comparable with that obtained using preformed N-arylimine.

此外我们也发现碘能够有效地催化N-芳基亚胺与烯醇醚的Diels-Alder反应，以很高的化学收率得到了四氢喹啉衍生物，并且发现碘也能够直接催化芳香醛、苯胺、烯醇醚的三组分&一锅&反应，获得的化学产率与使用预制的N-芳基亚胺相当。

The palladium-catalyzed heteroannulations of C_(60) with a variety ofο-iodoanilines afforded the first synthesis of C_(60)-fused indoline derivatives.

通过在Pd的催化下，富勒烯和邻碘苯胺类化合物的杂环化反应，首次合成了一系列富勒烯并吲哚啉环衍生物。

In this dissertation, electrophilic reactions of Nitrosonium with imines, aza-Diels-Alder reactions of N-arylimines with a variety of electron rich olefinic compounds induced by NO~+, and photoreactions of N-nitrosodiphenylamine with aromatic amines were studied.

本文研究了：(1)NO~+与亚胺双健发生的亲电反应；(2)NO~+引发的芳香亚胺和富电子碳碳双键作为亲二烯体的氮杂Diels-Alder反应，高选择性地得到了一系列四氢喹啉的衍生物；(3)N—亚硝基二苯胺与芳香胺发生光化学反应得到了一系列偶氮苯类化合物。

The better technology parameters of synthesis of triphenylamine, 4,4\'-dimethyltriphenylamine and 4,4\',4-trinitrotriphenylamine were obtained through the orthogonal test.

三苯胺及其衍生物是制备电荷传输材料，电致发光材料等的重要原材料，同时也可以作为有机染料和医药中间体。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。