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Many aromatic amine, such as aniline and N-methylaniline and diphenylamine, whose antidetonating quality are excellent, are not only often employed as concocting ingredient of antiknock but also suitable to research with electrochemical methods.

许多苯胺类化合物,如苯胺、N-甲基苯胺、二苯胺是性能良好的非金属抗爆制,也是抗爆剂常用的调合组分,且具有电子转移性质,适于电化学研究。

The decomposition of hydroxylamine hydrochloride under the reaction conditions was studied to understand its function during the amination process.

在此条件下,得到的苯胺收率为64 mol%,苯胺选择性为95.6%,转化数为48摩尔苯胺/摩尔V,此结果好于已有文献报道值。

Based on the mechanism of coupling reaction,the reaction of melt metallocene-based Poly(Ethylene-α-Octene) initiated by dicumyl peroxide was studied at elevated temperature in oscillatory shear flow field.

以苯胺、环氧丙烷为原料制备了N,N 二(2 羟丙基)苯胺,然后NHPPA与对硝基苯胺通过重氮偶合反应制备了一种具有推拉电子结构的偶氮化合物4 硝基 4′ N,N 二(2 羟丙基)氨基偶氮苯。

Seven Schiff bases of N-(4-hydroxyphenylmethylene)-1-naphthylamine, N-(4-hydroxyphenylmethylene)-p-methoxyaniline, N-(4-hydroxyphenylmethylene)-benzylamine, N-(4-hydroxy-3-methoxyphenylmethylene) furfurylamine, N-(4-hydroxy-3-methoxyphenyl methylene)-p-methylaniline, N-(4-hydroxy-3-methoxyphenylmethylene)-p-methoxyaniline and N-salicylidene-4-aminoantipyrine were first synthesized by the one step solid phase reactions between aromatic aldehydes with phenolic hydroxyl and amines at room temperature without solvent.

分别以带酚羟基的芳醛与胺类反应,首次通过室温固相反应一步合成了N-(4-羟基苯基亚甲基)-1-萘胺、N-(4-羟基苯基亚甲基)-对甲氧基苯胺、N-(4-羟基苯基亚甲基)-苄胺、N-(4-羟基-3-甲氧基苯基亚甲基)糠胺、N-(4-羟基-3-甲氧基苯基亚甲基)-对甲苯胺、N-(4-羟基-3-甲氧基苯基亚甲基)-对甲氧基苯胺和N-亚水杨基-4-氨基安替比林7种Schiff碱,反应15min完成,产率均超过90%。

Electrochemical corrosion measurements results indicated that the polyaniline nanofibers synthesized by direct mixed reaction have more excellent corrosion protection than conventional aggregated polyaniline for mild steel. In general, the emeraldine salt shows better anticorrosion performance than emeraldine base in 3.5% NaCl aqueous solution.

电化学测试技术研究表明,直接混合反应法合成的聚苯胺纳米纤维具有比常规聚苯胺更好的防腐蚀性能;在3.5%NaCl溶液中,掺杂态聚苯胺产物的防腐蚀性能优于解掺杂态聚苯胺产物。

A mode of the directionally growth of PAn on the surface of NaFe〓P〓rod-like particle was suggested. Some of aniline molecules in the reactants are fixed on the surface of skutterudite particles before the beginning of the polymerization. Other aniline molecules link with the aniline molecules fixed on the surface of skutterudite and form liner chains when the initiater is added into the reactants.

提出了聚苯胺在棒状方钴矿NaFe〓P〓材料表面定向生长的物理化学模型:在表面配位键的作用下方钴矿晶须表面首先附着了一层苯胺单体,在引发剂的作用下溶液中的苯胺分子在这层单体上定向聚合,形成了定向聚苯胺线性分子。

Methoxytriphenylamine and 4,4′-di methoxy -triphenylamine with good solubility in common organic solvents were synthesized by Ullmann reaction.

通过Ullmann反应合成了4-甲氧基三苯胺和4,4′-二甲氧基三苯胺两种具有良好溶解性的甲氧基取代三苯胺,通过FTIR、1H NMR和元素分析等手段对其进行了表征,并采用循环伏安结合UV-Vis吸收光谱测试了其能级结构。

The environmental black direct dye stuff without carcinogensis was prepared by 4,4'-diamino-dibenzidine-2-sulfonicacid,1-hydroxy-7-aminonaphthalene-3,6-dusuifonicacid,m-benzoic-diamine and aniline.

以4,4'-二氨基-二苯胺-2-磺酸代替苯胺,与1-羟基-7-氨基-3,6-二萘磺酸、间苯二胺、苯胺等合成无致癌作用的环保型黑色直接染料。

The environmental black direct dyestuff without carcinogensis was prepared by 4,4'- diamino - dibenzidine - 2 - sulfonicacid, 1 - hydroxy - 7 - aminonaphthalene - 3,6 - dusuifonicacid, m - benzoic - diamine and aniline.

以4,4'-二氨基-二苯胺-2-磺酸代替苯胺,与1-羟基-7-氨基-3,6-二萘磺酸、间苯二胺、苯胺等合成无致癌作用的环保型黑色直接染料。

A process for preparing superthin film of polyaniline, which can be used for chemical sensors, electrochromic device, luminous device, chemical modifying electrode and polymer FETs, uses intrinsic polyaniline solution and polymer acid as raw materials, which take part in doping reaction to prepare said film.

本发明公开了一种掺杂诱导沉积聚苯胺自组装超薄膜的制备方法,属超薄膜制备技术领域。它采用本征聚苯胺溶液及聚合物酸为原料,基于本征聚苯胺与聚合物酸的掺杂反应制备聚苯胺超薄膜。

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