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The varying tendencies of partition coefficients of some compounds in aqueous or nonaqueous solvent systems by calculating the phase equilibria with universal quasichemical functional group activity coefficient model are predicted. These compounds included saturated and unsaturated fatty acids ethyl esters,N2,4dinitrophenylamino alcohols, pnitrophenyl glucosides and so on, with simple structures and much differences in polarity.

以饱和及不饱和脂肪酸乙酯、2,4二硝基苯胺基脂肪醇和对硝基苯基葡萄糖甙等结构较为简单、极性差别较大的溶质系列为研究对象,应用修正的通用基团活度系数模型,通过相平衡计算,预测了它们在含水或不含水的溶剂体系中分配系数的变化趋势,并与前人的工作进行了对比。

The ratio of snails left water in the complex group was decreased 71.9% than that of nicotinanilide group.

由此表明,3个厂家生产的氯硝柳胺与湖北三利公司生产的烟酰苯胺复配形成的3组氯烟复合物,在浸杀和喷洒灭螺的效果上是一致的。

The results showed that the optimum conditions for pretreatment of coking wastewater were 6 g activated carbon per liter, 30 ℃, pH=9 and reaction for 20 min, under which the removal efficiency of organic pollutants are more than 70%. Among the 56 kinds of organic compounds, 45 kinds such as dolichoalkanes, polynucleation aromatic series, azacyclo compounds could be removed, and the removal ratios of amidobenzene, hydroxybenzene, indoleacetic, acid-2-methyl-phenyl-ester are 63.5%, 42.6%, 88.1%, 28.1% respectively, while cresol and xylenol are more than 70% and 85%.

结果表明,在最佳反应条件即活性炭投加量6 g·L-1,温度30 ℃,pH=9,反应时间20 min的情况下处理废水有机物去除率大于70%,原水中检测出的56种有机物中的45种被去除,如长链烷烃、多环芳香族及氮杂环化合物等的浓度降至检测限以下,剩余的11种有机物中苯胺、苯酚、吲哚、乙酸-2-甲基苯酯的去除率分别达到63.5%、42.6%、88.1%、28.1%,甲苯酚和二甲苯酚(5种)去除率在70%和85%以上。

First, the precursor polymer with azobenzene groups on main-chain was obtained by condensation polymerization between 4,4'-dihydroxyazobenzene and N,N-(2-bromoethyl)aniline through Williamson reaction. Then the azo polymer containing azobenzene groups both on main-chain and side-chain was prepared through an azo-coupling reaction between the precursor polymer and the diazonium salt of 4-nitroaniline.

设计并合成了一种新型的主侧链均含偶氮生色团的聚合物,首先通过4,4'-二羟基偶氮苯与N,N-二溴乙基苯胺之间的Williamson反应缩聚得到主链含偶氮苯基团的先驱聚合物,再通过重氮偶合反应得到目标产物,并利用核磁共振、红外光谱、紫外可见光谱、热分析等手段确认了所制备聚合物的结构。

In addition, ioding was found to be an efficient catalyst for the imino Diels-Alder reaction of N-arylimine and enol ethers and the reaction provided tertrahydroqinolines in good yields. One pot synthesis of tetrahydroqinolines from aldehyde, aniline and enol ethers was also achieved using iodine as the catalyst. The chemical yield of the"one pot"reaction was comparable with that obtained using preformed N-arylimine.

此外我们也发现碘能够有效地催化N-芳基亚胺与烯醇醚的Diels-Alder反应,以很高的化学收率得到了四氢喹啉衍生物,并且发现碘也能够直接催化芳香醛、苯胺、烯醇醚的三组分"一锅"反应,获得的化学产率与使用预制的N-芳基亚胺相当。

The low-current STM image showed that polyaniline molecular wires on Au(111) clearly exhibited a hexagonal-lattice ordered arrays, and the nearest neighbor distance in all molecular direction was 〓 The easy and feasible route (supramolecular self-assembly with CD-electropolymerization) promises to prepare an insulated polyaniline molecular wire.

低电流STM图像表明在Au(111)表面的聚苯胺分子线为六角的二维有序,分子与分子之间的最相邻距离为〓这种先进行CD超分子自组装后电聚合的方法可能会成为一类制备导电聚合物绝缘分子导线的新方法。

The structure, component, morphology and magnetic property of the composites were characterized by X-ray diffractometry, Fourier transform infrared spectroscopy, transmission electron microscopy and vibrating sample magnetometry, respectively. The tangent value of magnetic loss angle and dielectric loss angle of the composites were measured by an impedance/material analyser with the frequecy in the range of 1 MHz~1 GHz.

利用X射线衍射仪、红外光谱仪、扫描电子显微镜和振动样品磁强计分别表征了样品的结构、形貌和磁性能,用阻抗/材料分析仪测定了复合物在1 MHz~1 GHz的频率范围内的磁损耗和介电损耗,并研究了聚苯胺和引发剂的相对含量对复合物的磁损耗和介电损耗的影响。

It was found that the samples PVP-PdCl2-CdCl2 and PVP-PdCl2-HgCl2, compared with PVP-PdCl2, exhibited much higher catalytic activity and dechlorination selectivity, and the yields of the coupling by-products were obviously decreased. For example, when p-chloroaniline was used as substrate, the reaction time was shortened to 1/8, and the yield of dechlorination product was about 25 times as much as the original one, and when p-chlorotoluene was used as substrate, the yield of coupling by-product catalyzed by bimetallic catalyst was 1/390 of that catalyzed by monometallic catalyst.

与负载型单金属催化剂PVP-PdCl2相比, PVP-PdCl2-CdCl2和PVP-PdCl2-HgCl2对氯代芳烃脱氯有高得多的催化活性和脱氯选择性,且偶联副产物显著减少;以对氯苯胺为底物时,双金属催化下的反应时间缩短为单金属催化下的1/8,而脱氯产物收率提高25倍;底物为对氯甲苯时,双金属催化下的偶联副产物仅为单金属催化下的1/390。

The method of using formaldehyde buffer solution a b sorption-hydrochloric pararosaniline spectrophotometry to determine sulfur diox ide in air has higher sensitivity and good selectivity,and prevents from adoptin g mercurial absorbent.But the conditions in lab are not well controlled,the v alue of reagent blank and standard curvilinear slope can't accord with the one s tipulated in"Methods for Air and Waste Gas Monitoring and Analysis".Some opra tional techniques for SO2 determination in lab are introduced for reference.

文摘:以甲醛缓冲溶液吸收-盐酸副玫瑰苯胺分光光度法测定空气中的二氧化硫,方法灵敏度高,选择性好,避免了使用含汞的吸收液,但如果实验条件控制不好,试剂空白值及标准曲线的斜率就会不符合《空气和废气监测分析方法》中规定的值,本文着重从操作技巧方面对二气化硫测定的实验室质量控制进行分析,仅供参考。

In the present work, benzene and aqueous ammonia are used as starting materials, hydrogen peroxide is used as the oxidant to synthesis aniline.

苯胺是重要的化学化工原料,传统的生产方法存在操作条件苛刻、方法复杂、污染环境和腐蚀设备等严重不足,不符合当今的绿色化学和可持续发展的要求。

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