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The palladium-catalyzed heteroannulations of C_(60) with a variety ofο-iodoanilines afforded the first synthesis of C_(60)-fused indoline derivatives.

通过在Pd的催化下,富勒烯和邻碘苯胺类化合物的杂环化反应,首次合成了一系列富勒烯并吲哚啉环衍生物。

The catalytic property of polyvinylidene chloride polyethylene polyamine palladium complex (PVDC-DETA-Pd,PVDC-TETA-Pd,PVDC-TEPA-Pd)for Suzuki reaction of sodium tetraphenylborate with iodobenzene were examined under microwave heating.

本论文研究了聚偏二氯乙烯多乙烯多胺负载钯催化剂和PVDC二苯胺钯催化剂的制备、表征及其在微波条件下对Suzuki反应的催化性能。1。

The central part was composed of hypertrophic chondrocytes, for which the number increased with time. The cartilaginous tissue at the time of 2 weeks' cultivation appeared strongly positive staining of collagen type Ⅱ immunohistochemistry and safranine "O", as well as strongly metachromatic to toluidine blue.

其中心为肥大软骨细胞,且随培养时间的延长而增多。2周时,软骨组织甲苯胺蓝染色呈强的红色异染反应,Ⅱ型胶原免疫组织化学染色呈强阳性,番红&O&染色呈强阳性。

Then the bFGF was replaced by transforming growth factor-β1 (TGF-β1 10 μg·L-1) for next three weeks. Results Some spindle MSCs turned into round or elliptic shape and secreted metachromatic matrix with Toluidine blue.

结果:细胞形态由纺锤形变为圆形或椭圆形,细胞分泌了大量的甲苯胺蓝异染的基质,形成了类软骨陷窝。

The Mannich-type addition of O , O'-dialky phosphite to 2-fluorobenzaldehyde and 4-trifluoro- methylaniline was carried out in one pot by means of adopting three kinds of green synthetic methods, microwave irradiation, ionic liquid and free solvent-catalyst condition. According to the results, the synthetic method was optimized without catalyst and solvent at 100 ℃ and 15 min, and it was economic, convenient, high yields, timesaving and environment friendly.

采用微波辐射﹑离子液体和无溶剂无催化剂三种绿色合成方法,分别进行了以亚磷酸酯、邻氟苯甲醛和对三氟甲基苯胺为原料的类Mannich一锅法合成反应研究,经合成筛选,优选出控制反应温度100 ℃、无溶剂和无催化剂加热反应15 min的合成方法,实验结果表明该方法经济、简便、产率高、反应时间短及对环境友好。

Nitrogen species in FCC diesel oil include basic species (such as aniline, quinoline, and their derivatives) and nonbasic species (such as indole, carbazole, and their derivatives), and only 0.1% of the nitrogen compounds are quinoline and about 64% of them are carbazole and their derivatives.

氮化物主要为碱性氮化物和非碱性氮化物两大类型,其中碱性氮化物主要是苯胺及其衍生物,喹啉含量很低,约占总氮质量分数的0.1%,非碱性氮化物主要包括吲哚及其衍生物和咔唑及其衍生物,而咔唑类氮化物一般约占总氮质量分数的64%。

Methods Tarry stools from 38 cases definited upper gastrointestinal bleeding and 16 stomach strains confirmed including red blood cells by test under microscope respectively tested by colloidal gold indicator paper, orthotolidine method and tetramethyl benzidine indicator paper.

将38例临床确诊为上消化道出血患者的&柏油&样粪便和16份经镜检证实含红细胞的胃引流物标本分别用胶体金试纸、邻联甲苯胺和四甲基联苯胺尿隐血试纸测试其是否含有隐血。

MAIN OUTCOME MEASURES: The morphology of BMSCs was observed by the inverted phase contrast microscope. Expression of BMSC surface antigens was detected by flow cytometer. Osteogenous potential was assessed by alkaline phosphatase staining. Adipogenic potential was evaluated by Oil red O staining. Chondrogenic potential was assessed by toluidine blue staining.

主要观察指标:倒置相差显微镜下观察骨髓间充质干细胞的生长状态,流式细胞仪检测细胞表面标志物的表达,采用碱性磷酸酶染色鉴定成骨能力,以油红O染色鉴定成脂能力,以甲苯胺蓝染色鉴定成软骨能力。

Absorption spectra indicate that there is little or no interaction between chromphores in the ground state. However, the fluorescence emission of oxadiazole and triphenylamine moieties are almost quenched, which shows that in the excited ground state there exists very effective intramolecular singlet-singlet energy transfer .

研究发现,这些多发色团化合物在基态发色团之间没有作用或作用很小,而其中噁二唑和三苯基胺单元的荧光被严重的猝灭,这说明在激发态下,萘酰亚胺发色团与噁二唑、三苯胺功能团之间发生了分子内单线态—单线态能量转移。

Absorption spectra indicate that there is little or no interaction between chromphores in the ground state. However, the fluorescence emission of oxadiazole and triphenylamine moieties are almost quenched, which shows that in the excited ground state there exists very effective intermolecular singlet-singlet energy transfer.

研究发现,这些多发色团化合物在基态发色团之间没有作用或作用很小,而其中恶二唑和三苯基胺单元的荧光被严重的猝灭,这说明在激发态下,萘酰亚胺发色团与恶二唑、三苯胺功能团之间发生了分子内单线态-单线态能量转移。

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