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3-Nitrodiphenylamine is generally synthesized by the Ullmann condensation of N-(3-nitrophenyl) acetamide with bromobenzene.

摘 要:间-乙酰氨基硝基苯与溴苯发生Ullmann缩合反应是制备3-硝基二苯胺最常用的方法。

The catalysis of single and mixed micelles and functional molecules for alkaline hydrosis of acetanilide has been studied at 40℃ in aqueous acetonitrile solution with UV spectrophotometry.

在40℃下乙腈水溶液中,用紫外分光光度法研究了单一和混合胶束及功能分子对乙酰苯胺碱性水解反应的催化作用。

Methods Protein in blood and urine was precipitated directly by acetonitrile with acetanilide was used as the internal standard using Agilent Zorbax SB-Aq column (250 mm×4.6 mm, 5 μm). The mixed solvents of water (triethylamine 0.12%, acetic acid 0.12%) and acetonitrile were used as the mobile phase to separate cephalosporins using gradient elution method at 1 mL/min and 254 nm.

以乙酰苯胺为内标,血液和尿液用乙腈直接沉淀蛋白,采用Agilent Zorbax SB-Aq(250 mm×4.6 mm, 5 μm)色谱柱,流动相选用水(含0.12%三乙胺和0.12%乙酸)和乙腈的混合溶剂梯度洗脱,流速1 mL/min,检测波长254 nm。

N -alkylation of aniline by diethyl ether on Al 2O 3 was studied.

研究了在氧化铝催化剂上,苯胺与乙醚气相N -乙基化反应的动力学,得到了幂函数型动力学模型。

So it is the major tendency of preparing amine.

本次实验的目的产物是邻甲苯胺。

Pararosaniline was the most accurate and sensitive method of determining SO2 residue, and it was fit for the samples of any SO2 content. Improvement pararosaniline method was only fit for the samples of high SO2 residue. Iodometry was not fit for the deep color samples and low SO2 residue samples. The fast determination method could be used the quality and semi-quantitative determination of SO2 residue in edible fungus.

副玫瑰苯胺比色法是检测SO2残留最准确、最灵敏的方法,适合于各种SO2浓度的样品;改良的副玫瑰苯胺比色法只适合于高SO2残留的样品;碘量法不适宜检测深颜色的食用菌,而且在检测低SO2残留样品时准确度不高;快速测定法可用于食用菌产品中SO2残留的定性检测和半定量分析。

Saturated Ag/AgCl. Furthermore, in situ UV-Vis spectra showed that the electrocopolymerization between m-toluidine and p-phenylenediamine was performed. The p-phenylenediamine might react with m-toluidine to yield more active intermediates, which not only promote polymerization but also accelerate polymerization. In addition, through that p-phenylenediamine could be incorporated into copolymer to make the copolymer have a phenazine or phenazine like cyclic structure, which was proved by the FTIR of polymers.

在恒电位电解的条件下,相应的原位紫外-可见光谱和聚合物的傅立叶变换红外光谱表明间甲基苯胺和对苯二胺能发生电化学共聚反应,由于对苯二胺可能与间甲基苯胺形成了具有较强反应活性的中间体,使得对苯二胺的加入不但促进和加速了聚合反应,而且还结合进聚合物中形成了phenazine或类似于phenazine的环结构。

The investigation also showed that, the antioxidants with same action mechanism, for example, as both radical scavengers, phenol and amine antioxidants are synergistic; but the synergistic effects between two antioxidants with different action mechanism, such as radical scavenging phenol and amine antioxidants, and hydroperoxide decomposing ashless dithiocarbamate, are much stronger, and the heterosynergism between dithiocarbamate and alkylated diphenylamine is outstanding, which can serve as high temperature ashless high performance antioxidant combination; the heterosynergism among three antioxidants with three different action mechanisms, for example, the tri-component combination of alkylated diphenylamine, zinc dithiocarbamate and organic molybdate ester, can achieve excellent antioxidation performance.

研究还表明,具有相同抗氧机理的不同抗氧剂,如酚类和胺类抗氧剂,具有协同作用;不同作用机理的两抗氧剂之间,如自由基清除剂和氢过氧化物分解剂,具有更好的抗氧化协同效果,其中,无灰氨基甲酸酯与烷基化二苯胺抗氧剂具有最佳的抗氧协同效能,可成为高温无灰抗氧剂应用的一个很好选择;不同抗氧机理的三种抗氧剂复合,如烷基化二苯胺,氨基甲酸锌和有机钼酸酯组成的三元复合抗氧剂,具有更为优秀的抗氧化性能。

Quantum chemical CNDO/2 method has been performed to study 20 chloranlines on the electronic structure in order to analyze their toxicities to Photobacterium Phosphoreum. The correlation analysis and the step regression analysis are put in use in this paper.

研究氯苯胺类化合物的电子结构与发光菌毒性的关系,应用CNDO/2量子化学方法计算了20个氯苯胺类化合物的电子结构,探讨了发光菌在5、15、30 min时间内的半抑制浓度的负对数P(5-EC50)、P(15-EC50)、P(30-EC50)与化合物的电子结构的关系。

The calculated results validate the rationality of molecular structure design for TPA-based organic dyes.5.Effects on DSCs performance by dye bath solvents were investigated,and dichloromethane is chosen for sensitizers' comparison.6.The Incident Photon-to-Ccurrent Conversion Efficiencyand Current-Voltage curves of the DSCs based on the as-prepared dyes were measured.The relationship between dye structures and photovoltaic performance of the DSCs were studied.

计算结果证明了三苯胺基染料分子结构设计的合理性。5、研究了TiO_2膜的染料敏化时所用溶剂对电池性能产生的影响,结果表明,二氯甲烷溶液敏化的膜电极,用于DSCs的测试,均表现出较好的光电性能。6、通过入射单色光光电转换效率以及电流-电压曲线的测试,系统表征了三苯胺基染料敏化的DSCs的光电转换性能,揭示了影响电池性能参数差异的因素。

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