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The results indicated that following the increase of acetanilide loading, PVC crystalline was raised first and then decreased, when acetanilide content was 3%, PVC crystalline reached the maximum and the tensile strength was the strongest; the micro morphology was changed from an even cloud-like structure to an fiber like network, and the perfection of the network was raised first and then lowered, as made the elongation at rupture rise first and then decline.

结果表明:随着乙酰苯胺质量分数的增加,PVC结晶度先增后降,当乙酰苯胺质量分数为3%时,PVC结晶度最大,拉伸强度也最大;微观结构逐渐由均匀的云片状结构变成网络结构,且网络的完善性先增后降,使得材料的韧性先增后降。

It indicates that the PANI particles constituted films are ball like or ellipsoid like; the film takes on tertiary structure; HClO4 servers as both an acid medium and a dopant; the crystallizability of the film seems poor; the relationship between film thickness and acid concentration is not in linearity; the conductivity of the film is on a level with semiconductor, whose value depend more on film appearance than acidity of acid medium; the film starts dedoping at 67.3℃ and end at 277.2℃.

结果表明,构成薄膜的聚苯胺粒子呈球型或椭球型;薄膜具有三级结构特征;高氯酸不仅作为介质酸,同时作为掺杂剂;薄膜的结晶性能不佳;薄膜厚度与介质酸的浓度并非线性关系;薄膜的电导率处于半导体水平;电导率大小与无机介质酸的酸性强弱有一定关系,与表面形貌关系更为紧密;高氯酸掺杂聚苯胺薄膜在67.3℃时开始脱掺杂,在277.2℃脱除完全。

The SDS micellar-templated polymerization of aniline is strongly pH-dependent in this case. A wider range at low pH (1.0~4.0) was required to produce the conducting PANI, optimal pH was 3.0 and the transition from emeraldine salt to emeraldine base form of PANI occurred at about pH 10.4 in this anionic micellar system.

结果表明该反应具有明显的pH值依赖性, pH (1.0~4.0)是合成导电聚苯胺所必需的,其最适pH值为3.0,聚苯胺由导电的翠绿亚胺盐转变为本征态发生在pH 10.4。

Several aminated Fullerene derivatives were synthesized by the reaction of C〓 with phenylamine, diphenylamine and triethylamine etc., the phenomena of fragmentation and aggregation of the aminated Fullerene derivatives in UV laser desorption ionization mass spectrometer was observed, a few nitrogenous poly-Fullerene ions, such as C〓NH, C〓N〓H〓, C〓N〓H〓, C〓N〓H〓, C〓N〓H〓 etc.

对C〓富勒烯与苯胺、二苯胺、三乙胺等形成的加合物在紫外激光解吸电离作用下可以发生不同寻常的裂解和聚合现象进行了研究,认为其形成机理为:上述加合物在紫外激光解吸电离作用下,发生裂解产生C〓NH、C〓N及C〓等离子,然后它们之间发生聚合,形成如:C〓NH、C〓N〓H〓、C〓N〓H〓、C〓N〓H〓、C〓N〓H〓等含氮原子的聚富勒烯离子。

A new concept about organic-inorganic thermoelectric material was proposed. New composite material possessed the thermoelectric properties, which the organic and inorganic thermoelectric materials own. Synthesis and properties of polyaniline/skutterudite composites were investigated.

为进一步扩展热电材料领域及探索新型热电材料,本文首先提出了有机-无机复合材料的概念,并对NaFe〓P〓粉末材料与聚苯胺复合形成的聚苯胺/方钴矿复合热电材料的合成和性质进行了初步研究。

In order to improve the hole mobility, a novel conjugated polymer DOTPAV-PT with triphenylamine unit in the side chain was synthesized and characterized in details, and the photophysical and electrical properties were investigated .

为提高聚噻吩衍生物的空穴迁移率,将空穴传输基元三苯胺引入到聚合物结构中,合成一种侧基为三苯胺乙烯基的聚噻吩衍生物DOTPAV-PT,并对其进行详细的表征和光物理性质及电性能研究。

All of the tripodal schiff base ligands and their complexes were characterized.

以三乙醇胺、巯基苯胺、巯基乙胺为初始原料,设计合成了六个三脚架结构的化合物,其合成路线如下:三乙醇胺与氯化亚砜反应得到三(2-氯乙基)胺(1),然后与巯基苯胺或巯基乙胺在碱性条件下反应生成三脚架结构的三{[2-(2-氨基苯基)硫代]乙基}胺(2)或三{[2-(2-氨基乙基)硫代]乙基}胺(3),然后再与水杨醛、2-甲酰基-8-羟基喹啉(8)、2-甲酰基-8-苄氧基喹啉(7)反应得到六种新型的含硫西佛碱化合

Through these we find the characterization of ammonium sulfate and aniline ratio, hydrochloride and perchlorate (HCLO4) concentration, polyvinylpyrrolidone and polyvinyl alcohol of Concentration on the morphology and conductivity polyaniline films have great impact.

通过这些表征我们发现过硫酸铵与苯胺摩尔比、盐酸和高氯酸(HCLO4)的浓度、聚乙烯吡咯烷酮和聚乙烯醇的浓度对聚苯胺薄膜形貌和电导率有很大的影响。

We synthesize a series of star-burst compounds using triphenylene as the core, alkyl chain as the linker to connect the core with the triphenylamine / carbazole derivatives. The electrochemical properties of those star-burst compounds were studied by cyclic voltammetry. Then we fabricate OLED device by employing those electropolymeric film as the hole-transport layer, and all the devices show well-performance.

因此我们合成出以三伸苯为核心,以碳链当作连接基团,接上数个不同的三苯胺基团或咔唑基团之星状化合物,佐以循环伏安法观察此一系列化合物之电化学行为,探讨不同三苯胺基团或咔唑基团对於此类分子之电聚效果的影响,并将其运用在有机电激发光材料上,皆有不错的效果。

The empirical Freundlich equation was successfully employed to describe the adsorption process. Due to hydrogen-bonding interaction between the tertiary amino groups on the resin and the amino groups of p-methylaniline, the adsorption capacity towards p-methylaniline of NDA-8 is higher than that of NKA when the equilibrium concentration is 5 mmol/L.

结果表明:2种树脂吸附对甲苯胺均符合Freundlich等温吸附方程,NDA-8树脂表面叔氨基与对甲苯胺之间的氢键作用可有效强化吸附能力,在平衡浓度均为5mmol/L的情况下,其吸附容量达到NKA的1.5~1.6倍。

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