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The main products are: HH-01 fungicides HH-02 organic dispersant HH-03 cationic starch Wood HH-04 cationic starch Department HH-05 modified starch warp sizing agents also sell German Baker Chemical Co., Ltd. Main Products Defoamer series product: E640, T50 Surface Sizing Agent: A281, A288, K532, pesticides / medicine / veterinary medicine a variety of intermediate products (p-Bromo-p-Bromotoluene bromoform 1 - bromo-heptane triethyl citrate 1,2, 3 - Three Bromopropane 3 - chloro -4 - fluoro bromobenzene Bromotoluene ethylbenzene 4 - bromo -2 - bromo-ethyl-Chloroaniline 2 - bromo--5 - chloro-toluene 3 - bromo-methyl 1,6 C - Dibromo Hexane 1 - bromo -4 - nitrobenzene o-methoxy benzaldehyde acid propyl bromide p-fluorotoluene bromo dodecane toluene four of iodine bromide bromoethane three citric acid tert-butane n-butyl 2 - bromo-p-bromo-butane Hydroxybenzaldehyde between 2 - bromo-propionic acid bromide veratryl aldehyde inter-bromo-trifluoro-n-hexane of toluene on Bromoxynil Bromotoluene toluene ethylbenzene o-bromophenol bromide bromide Cyclohexane Cyclopentane bran acid dibutyl maleate Ethyl Lactate Propylene between bromine bromine bromine between aniline o-anisidine o-fluorophenol difluorobenzonitrile to aminobenzaldehyde Bromotoluene aniline on Bromobenzaldehyde Bromotoluene acid) and other relevant units have been in substantial promotion, and client set up a good relationship of cooperation has been the user's praise.

现主要产品:HH—01杀菌剂 HH—02有机分散剂HH—03阳离子淀粉 HH—04木署阳离子淀粉 HH—05 经纱上浆变性淀粉同时还代理销售德国贝克化学公司系列产品主要产品消泡剂:E640 、T50 表面施胶剂:A281、A288 、K532,农药/医药/兽药中间体多种产品(对溴苯酚对溴甲苯溴仿 1-溴庚烷柠檬酸三乙酯 1,2,3-三溴丙烷 3-氯-4-氟溴苯对溴乙苯 4-溴-2-氯苯胺溴乙酸乙酯 2-溴-5-氯甲苯 3-溴丙酸甲酯 1,6-二溴己烷 1-溴-4-硝基苯邻甲氧基苯甲醛溴乙酸丙酯对氟甲苯溴代十二烷对碘甲苯四溴乙烷溴代叔丁烷柠檬酸三丁酯 2-溴氯苯间羟基苯甲醛溴丁烷 2-溴丙酸黎芦醛溴已烷间溴三氟甲苯对溴苯腈对溴乙苯邻溴甲苯溴代环已烷溴代环戊烷糠溴酸马来酸二丁酯溴丙烯乳酸乙酯间溴苯胺间溴苯甲醚邻氟苯酚邻氟苯腈对氨基苯甲醛对溴苯胺对溴苯甲醛对溴苯甲酸)等在相关单位得到了大量推广,与客户建立了良好的合作关系,得到了用户的赞誉。

The result indicated that deoxidizing emeraldine destroyed of quinone diamide conjugate structure, both of the conductivity and solubility were reduced. The charge was delocalized along the molecular chains after protonic acid doped, which was beneficial to the electric conductivity.

结果表明,还原本征态聚苯胺破坏了聚苯胺链中的醌二亚胺的共轭结构,电导率和溶解性能均下降;质子酸掺杂本征态聚苯胺后分子链上的电荷离域程度增加,有利于电子流动,从而提高其电导率。

The results revealed that the conversion was 92.4% when aniline concentration was 1 mol/L, feeding temperature was 25℃ and residence time was 11 s. With feeding temperature being the main factor, the effect of residence time decreases successively. The diazotization anomalies could be caused at aniline concentration above 1.5 mol/L. The proper feeding temperature which can lead to the highest conversion was 20~30℃.

试验结果表明,在苯胺浓度为1 mol/L,进料温度为25℃,停留时间为11 s时反应转化率达92.4%;苯胺浓度、进料温度、停留时间对反应影响程度各不相同,其中进料温度的影响最大,停留时间次之,苯胺浓度高于1.5mol/L后,对反应影响加剧,导致反应异常;从进料温度对反应的影响试验分析可得,反应转化率最高的进料温度在20~30℃之间。

The PANI-C composite electrodes had better cycling stability than PANI electrodes and the specific capacitance of the composite electrodes was 587F/g, which was much higher than that of the pristine activated carbon (140F/g), owing to the faradic reaction of PANI with the electrolyte.

聚苯胺/活性炭复合电极比活性炭电极具有更高的容量,同时比聚苯胺电极具有更好的循环稳定性。聚苯胺/活性炭复合电极的比电容为587F/g,而活性炭电极仅为140F/g。

In order to improve its solubility and conductivity, the chemical oxidation method was used to prepare emeraldine salt type conductive polyaniline co-doped with nitric acid (HNO3) and dodecylbenzene sulfonic acid.

本研究使用化学氧化聚合法,以硝酸与十二烷基苯磺酸共掺杂制备导电性聚苯胺,采用共掺杂的方法不但可改善聚苯胺难溶的特性,更可兼顾聚苯胺之导电性。

A wavelet packet transform based generalized regression neural networkwas developed to process overlapping ultraviolet absorption spectra of p- nitroaniline ,o- nitroaniline and m- nitroaniline .

开发了一种小波包变换广义回归神经网络法,用于处理对硝基苯胺、邻硝基苯胺和间硝基苯胺重叠的紫外吸收光谱,达到不经预先化学分离进行同时测定的目的。

Compared with non-nanopolyaniline synthesized by conventional emulsion polymerization, nanopolyaniline has the narrow and uniform distribution of particle dimension and the diameter of particle is about 4-5nm,and the conductivity reaches 3.2S·cm-1, which is more than 100 times higher than that of nanopolyaniline;Moreover, it has higher solubility in conventional solvent and the solubility reaches 95% in N-methyl pyrrolidone;what's more ,it has higher crystallinity and more uniform crystal proved by XRD, apparent blue shift indicated by UV, which makes it possible to prepare transparent conductive composite films.

结果表明,微乳液法合成的纳米聚苯胺与常规乳液法合成的非纳米聚苯胺相比,具有明显的优越性:粒径分布窄,95%的在10nm 以下,最大的不超过30nm;电导率较高,达到了3.2S/cm,提高了2 个数量级以上;在有机溶剂中的溶解度较高,其中在N-甲基吡咯烷酮中的溶解率达到了95%;X 射线衍射仪分析表明,纳米聚苯胺结晶度高,晶型更为规整;紫外可见光谱研究发现,纳米聚苯胺在可见光区有明显的蓝移,为制备透明的导电复合膜提供了可能。

Triphenylamine and their derivatives are excellent optical materials,and TPA is chosen as the basic framework for the design and synthesis of a series of TPA-based dyes.

三苯胺(Triphenylamine,TPA)及其衍生物是一类性能优良的光电材料,本论文即是选用三苯胺为基本骨架,通过简单的有机反应,设计和合成一系列三苯胺类有机敏化剂。

We have synthesized 4,4'-dinitro-3 4''-dimethyl triphenylamine,(1), in 84% yield in an one-step condensation process between 3,4-dimethyl aniline and 4-fluoro-nitrobenzene. After the auto-oxidation of (1) and the subsequent hydrogenation of the nitro-groups, an AB2 type triphenylamine polyimide intermediate bearing two amine groups and one acid-anhydride group each on individual phenyl ring,{AB2 PI Intermediate}, was prepared successfully. The yields of the autoxidation and the hydrogenation steps are 81% and 90% respectively.

中文摘要本研究以3,4-二甲苯胺及4-氟硝基苯为原料,经一步骤缩合反应得到产率为84 %之4,4'-二硝基-3&,4&-二甲基三苯胺(1),由(1)经自氧化法后再以氢化法还原硝基,成功地制备出带有二胺基与一羧基的三官能基之AB2型三苯胺中间体(AB2型PI中间体),自氧化反应与氢化法的产率各为81%及90%。

The humidity resistance and the sensitivity to chemical warfare agents simulants of the tuned films were also investigated.Self-assembled LBL polyaniline films were prepared from aniline monomers by in situ polymerization and the mechanism of film formation was discussed. It was proposed that the self-assembly of polyaniline occurred through the quick absorption of aniline monomer cations or aniline monomer cation radicals on the glass surfaces by electrostatic attractions to form homogeneous polymerization centers, then increased gradually by the way of upright to the glass supports for extensity, leading to the polyaniline chain growth. The polyaniline was doped under acidic condition to absorb anionic polyelectrolyte, such as sodium polystyrene sulfonate based on the electrostatic force, or to adsorb polymer based on hydrogen-bonding interactions, for example Polyvinyl Alcohol, and then recycled to fabricate_n or_n self-assembled multilayer films.

跟踪了原位聚合的具有纳米结构的聚苯胺多层自组装膜的成膜过程,提出了该自组装膜的成膜机理:聚合反应初始阶段的苯胺阳离子或苯胺阳离子自由基通过静电作用快速吸附到带负电荷的基片表面,形成均匀的聚合中心,然后以垂直于基片的方式进行链增长生成PANI;PANI在酸性条件下经现场掺杂后带正电荷,再通过静电作用吸附带负电荷的聚电解质如聚苯乙烯磺酸钠,或通过氢键作用吸附聚合物如聚乙烯醇,这样循环LBL-SA即得到_n或_n等原位聚合聚苯胺自组装膜。

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