苯胺的

The influence of each condition on the reaction speed and yield was studied, and the optimal conditions were: the ratio of the amount of substance of aromatic amine and heptafluoro-isopropyl iodine was 1:1.1~1.5, the amount of substance of sodium dithionite, sodium bicarbonate, aniline compounds were respectively 1.1~1.3, the amount of substance of phase transfer catalyst TBAB and aniline compounds was 0.05~0.1, the concentration of aniline compound was 0.5~1.0 mol/L, reaction temperature was 10~20 ℃, and the solvent was aether.

最佳结果为：芳胺与七氟异丙基碘的物质的量比1：1.1~1.5，连二亚硫酸钠、碳酸氢钠与苯胺的物质的量分别为1.1~1.3，相转移催化剂四丁基溴化铵与苯胺的物质的量比在0.05~0.1，溶剂总用量使苯胺浓度在0.5~1.0 mol/L；反应温度10~20℃；溶剂采用乙醚。取代基供电子性越强，反应时间越短，产率越高；氨基的对位优先反应，氨基的邻位较难发生反应；且七氟异丙基总是优先取代在芳环电子云密度较高的位置上。

In this dissertation, two derivatives of aniline containing polyoxyethylene substituent m-phenylene diamino formyl alkylenediamine poly acetate and poly-3-aminobenzoate were designed and synthesized. And then, comb-shaped polyaniline grafted by PEO were prepared by chemical oxidation copolymerization. The structure of copolymers were characterized by FTIR, ultraviolet-visible spectrum, elemental analysis and TEM etc..

本文在设计并合成两种含聚氧乙烯取代基的苯胺衍生物——间苯二氨基甲酰己二氨基甲酸聚氧乙烯乙酸酯和3-聚氧化乙烯单甲醚基苯胺的基础上，采用化学氧化法将它们与苯胺进行共聚，制备出了聚氧乙烯接枝聚苯胺的梳型共聚物。

The results show that the compound conductive fiber has typical structure of sheath-core consists of black greened polyaniline electric conductive deposition as the skin and the white polypropylene matrix fiber as the core, which makes the compound fiber preferable physical mechanical property. The intensity and the elongation ratio of the electric conductive fiber are decreased but the thermal stability is enhanced after modified. The compound fiber has the good acid resistance but poor base resistance. The thermal stability of the compound fiber prepared by 4-methyl-benzene sulfonic acid is better than that prepared by hydrochloride acid. Moreover, the compound fiber can be re-doped by other organic or inorganic acid after freed from the adsorbed acid. Furthermore, the electric conductivity of the compound fiber decreases with the temperature increasing but hardly changed with the humidity. The adsorptive ability and therefore the content of the polyaniline, the constant of electric conduction, and the durability of the compound fiber can be enhanced by thinning the diameter, section heteromorphosis, section heteromorphosis and plasma treatment of the surface or blending with COPET of the fiber.

结果表明：复合纤维是聚丙烯与聚苯胺的共混体系，具有典型的皮芯型结构，皮层为墨绿色的聚苯胺沉积层，形成连续的导电通道，芯层为白色的聚丙烯基质纤维，提供物理机械性能；导电改性后纤维的强度、强力和伸长率均有下降，但热稳定性得到提高；复合纤维的耐酸性比耐碱性好，以对甲苯磺酸做掺杂酸比盐酸掺杂聚苯胺热稳定性好，脱掺杂后的复合纤维，可用其它无机酸或有机酸进行再掺杂；复合导电纤维的电导率随温度升高降低幅度较大，但几乎不受湿度影响；基质纤维细旦化、截面异形化、表面等离子体处理或共混COPET等改性处理均能提高纤维的吸附性，进而提高复合纤维表面聚苯胺含量、电导率和耐久性。

According to the contrasts between the structure of PANI and that of POT, the conclusion could be made that steric hinderance effect of methyl groups in the poly-O-methylaniline is more prominent than induction effect and hyperconjugation.

比较聚苯胺和聚邻甲苯胺的结构可知，甲基取代苯环中的一个氢原子后，甲基对聚邻甲苯胺的空间位阻效应明显大于诱导效应和超共轭效应。

Humic acids, oxidizable fraction and lipids were the main fractions affecting the sorption capacity. The humic acids had the maximum adsorption capacity for nitrobenzene and aniline, the lipids naturally present in the soil strongly compete for hydrophobic sorption sites within the soil organic matter, and the adsorption capacity of mineral surface for nitrobenzene and aniline were only 2.31mg·kg-1 and 3.63mg·kg-1, respectively.

硝基苯和苯胺在湿地土壤中的吸附主要受腐殖酸、易氧化有机质组分和脂类化合物的影响，其中腐殖酸对硝基苯和苯胺具有最大的吸附容量；脂类化合物表现为与硝基苯、苯胺竞争土壤有机质结构中的吸附位点，去除脂类化合物后残余物的吸附量增大；矿物组分对硝基苯和苯胺的吸附是次要的，吸附容量仅为2.31mg·kg-1和3.63mg·kg-1。

The emulsion polymerization of aniline in three phase system of non polar solvent and surfactant and water was studied.

采用非极性溶剂－表面活性剂－水三相体系进行苯胺的乳液聚合，比较了所得聚苯胺与溶液法合成聚苯胺在性能上的差异；通过X射线衍射分析，电镜分析等测试手段研究比较了两种聚苯胺的结构。

We have not found any reports that o-toluidine and N,N-dimethylaniline can be used as antiknock. The electrochemical properties of aromatic amine are in line with its' antidetonating quality and actual application.

而实际上采用胺类化合物作抗爆剂时，一般使用N-甲基苯胺、苯胺、邻甲苯胺及间甲苯胺，尚未见到使用对甲苯胺和N，N-二甲基苯胺的报道。

The Seebeck coefficient of ultrasonic PAn is greater than that of conventional PAn, both of them increase with the increase of temperature.

在聚苯胺分解温度以下，两种聚苯胺的Seebeck系数均随温度的升高而增大，直至聚苯胺的分解。

YAA at amino acid level.

从实验室保存的一株能高效降解苯胺的不动杆菌中克隆到完整的苯胺双加氧酶基因簇，序列分析表明该基因簇包含6个完整的ORF，全序列与已报道的不动杆菌YAA的苯胺双加氧酶基因簇在氨基酸水平上有较高的同源性。

Optimum reaction conditions were outlined for the in-situ polymerization of aniline onto the surface of rayon fiber and alkalized PET fiber.

讨论了聚苯胺的导电机理以及碱减量处理条件、聚合反应条件对聚苯胺／粘胶和聚苯胺／涤纶导电复合纤维导电性的影响。

What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢？

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我，一个心中布满虚荣的女孩子真实的想法。