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苯胺染料

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The charges on the substituents affected OWF〓 greatly for some azobenzene derivatives, pyridone derivatives, nitrodiphenylamine derivatives, some reactive dyes and 1, 4-diamino anthraquinone derivatives, in this instance, OWF〓 changed linearly with the change of the charges.

2给电子取代基或吸电子取代基的电荷对OWF〓有较大的影响,OWF〓随电荷的变化而线性变化,如某些偶氮苯衍生物、吡啶酮类染料母体、硝基二苯胺类化合物、偶合组分和重氮组分之间夹角α变化不大的活性染料、1,4—二氨基蒽醌衍生物等。

The invention belongs to the technical field of solar batteries, which more particularly relates to a preparation of a novel triphenylamine group organic dye and the application thereof as a photosensitizer in a dye-sensitized solar cell.

本发明属于太阳能电池技术领域,具体为一种新型三苯胺基有机染料的制备及其在染料敏化太阳能电池中作为光敏化剂的应用。

The invention belongs to solar energy battery technology, which in detail relates to a novle triphenylamine organic dye and preparation and its application as photosensitizer in dye sensitization solar energy battery.

本发明属于太阳能电池技术邻域,具体为一类新型三苯胺基有机染料和制备及其在染料敏化太阳能电池中作为光敏化剂的应用。

It was found that the introduction of t-butyl or methoxy group in the triphenylamine subunit could lead to more efficient photoinduced intramolecular charge transfer, thus improving the overall photoelectric conversion efficiency of the resultant DSSC.

研究结果表明叔丁基或甲氧基取代三苯胺基团能够促进分子内电子转移,进而提高染料分子的敏化效率。

In the same reactor, telon fast green 5G was synthesized through condensation and sulfonation processes with 1,4,5,8-hydroxyanthraquinone and p-toluidine as main raw materials.

由1,4,5,8—四羟基蒽醌和对甲苯胺为主要原料,在一个反应器内同时完成了缩合和磺化两步单元反应,合成酸性蒽醌绿染料,并对其反应条件对产物收率的影响进行了研究,确定了最佳合成工艺条件(反应时间16 h、反应温度120℃、原料的配比1:2.2)。

The experimental results indicated that saturated —N=N— bonds of dyes can be easily deoxidized by scrap iron, and the intermediate product aniline was produced.

实验结果表明,染料的偶氮键易被铁屑内电解还原,反应过程中有中间产物苯胺生成。

In this article,a non-carcinogenic dye intermediate 4-aminodianiline-2-sulfonic acid is synthesized from 4-nitro-1-chlorobenzen through sulfonation,condensation and reduction.

针对联苯胺作为合成染料的重要中间体已被确认为致癌物的情况,以对硝基氯苯为原料,经磺化、缩合、还原,合成了一种无致癌性并取代联苯胺的双胺化合物染料中间体4-氨基二苯胺-2-磺酸,利用红外光谱、差热和氢谱核磁对其性质进行了表征。

A trademark used for dextroamphetamine.

一种晶状酸,由苯胺制取,用作染料。

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