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It indicates that the PANI particles constituted films are ball like or ellipsoid like; the film takes on tertiary structure; HClO4 servers as both an acid medium and a dopant; the crystallizability of the film seems poor; the relationship between film thickness and acid concentration is not in linearity; the conductivity of the film is on a level with semiconductor, whose value depend more on film appearance than acidity of acid medium; the film starts dedoping at 67.3℃ and end at 277.2℃.

结果表明,构成薄膜的聚苯胺粒子呈球型或椭球型;薄膜具有三级结构特征;高氯酸不仅作为介质酸,同时作为掺杂剂;薄膜的结晶性能不佳;薄膜厚度与介质酸的浓度并非线性关系;薄膜的电导率处于半导体水平;电导率大小与无机介质酸的酸性强弱有一定关系,与表面形貌关系更为紧密;高氯酸掺杂聚苯胺薄膜在67.3℃时开始脱掺杂,在277.2℃脱除完全。

The photochemical and thermal decomposition of various diphenylamine diazonium salts in ethanol were studied. It was found that, the major products in photochemical decomposition are their corresponding substituted diphenylamino-4-ethyl ethers while their corresponding diphenylamines were obtained as only one product in the case of thermal decomposition.

并研究了二苯胺型重氮盐的光、热分解,结果表明:在醇中,二苯胺型重氮盐的光解主要生成重氮基被乙氧基取代的产物;热解几乎生成唯一的重氮基被氢取代的产物。

The influence of aniline concentration, feeding temperature and residence time on aniline diazotization in a spiral reactor was analyzed with orthogonal test and, in particular, the influence of feeding temperature was tested.

用正交试验方法分析了苯胺浓度、进料温度和停留时间等对螺旋管式苯胺重氮化反应工艺的影响,并着重试验了进料温度因素对反应的影响。

The reaction of aniline over catalyst DH-1 to synthesize diphenylamine has been studied .

苯胺在DH 1催化剂上合成二苯胺的反应规律进行了研究。

The synthesis of diphenylamine from aniline-phenol by liquid phase condensation in the presence of Pd/C catalyst was studied.

研究了在Pd/C催化剂存在下,通过液/固催化缩合反应由苯胺和苯酚合成二苯胺的方法。

A liquid amine ashless antioxidant HAO without phosphorus and zinc was prepared by alkylation of diphenylamine and 12 carbon iso olefin mixture, which can be applied at high temperature.

以二苯胺和含C12 的混合异构烯烃为原料,通过烷基化工艺,研制出了适于高温条件下应用的不含磷、锌元素的液态胺型无灰抗氧剂双十二烷基二苯胺

Diphenylamine method) and 1240mgkg-1NO3- for corn.

确定了两种作物采用两种方法进行氮素营养诊断的临界值,冬小麦为2.00(NO3-N色阶,二苯胺法)、1500mgkg-1(NO3-,反射仪法);夏玉米为2.40(NO3--N色阶,二苯胺法)和1240mgkg-1(NO3-,反射仪法)。

Monodispersive Au nanoparticles were synthesized via the redox reaction between diphenylamine sulfonate and HAuCU-The effect of the amount of sodium diphenylamine sulfonate and polyon the morphology and size of Au nanoparticls were examined.

利用四氯合金酸和二苯胺磺酸钠反应,制备了大小均匀的金纳米粒子。考察了还原剂二苯胺磺酸钠和保护剂聚乙烯吡咯烷酮的用量的变化对金纳米粒子形貌和大小的影响。

Methods Starting from 2-chloro-4-nitrophenol and 2- pyridine hydrochlorid, 3-chloro-4-(pyridin-2-ylmethoxy) aniline was obtained via etherization and reduction. The obtained aniline coupled with N-(4-chloro-3-cyano-7-ethoxyquinolin-6-yl) acetamide to give 4-[3-chloro-4-(2-pyridylmethoxy) phenylamino]-3-cyano-7-ethoxy-6-N-acetylaminoquinoline. And then it was deacetylated, followed by reacting with4- but-2-enoyl chloride to yield the target compound neratinib.

以2-氯-4-硝基苯酚和2-氯甲基吡啶为起始原料,经醚化、硝基还原得到3-氯-4-(吡啶-2-甲氧基)苯胺,3-氯-4-(吡啶-2-甲氧基)苯胺与3-氰基-6-乙酰氨基-7-乙氧基-4-氯喹啉反应得到3-氰基-6-乙酰氨基-4-[3-氯-4-(吡啶-2-甲氧基)苯氨基]-7-乙氧基喹啉,3-氰基-6-乙酰氨基-4-[3-氯-4-(吡啶-2-甲氧基)苯氨基]-7-乙氧基喹啉去乙酰保护基后,与-4-二甲氨基-2-丁烯酰氯经酰化反应得到ner-atinib。

The results of X-ray diffraction showed that the nickel nanoparticles had face centered cubic structures and the structures of polyandinc have not been affected under high temperatures.

采用先合成导电聚苯胺,然后用多元醇原位液相还原的方法,合成了聚苯胺/镍纳米复合材料,纳米镍的含量约为19.22%。

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