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Acting as an antenna molecule in the supramolecular system, Mg(superscript 2+)-HA remarkably enhances the photoinduced electron transfer efficiency between C60 and an electron donor, N, N-dimethylaniline.

作为超分子体系中的光捕获分子,Mg(上标 2+)-HA能显著地提高C60与N,N-二甲基苯胺的光诱导电子转移反应效率,生成的C60负离子自由基的电子自旋共振光谱信号强度比未加入Mg(上标 2+)-HA时增强了9倍左右。

Then the selenium-catalyzed oxidative carbonylation of aniline with thiols has been studied.

接着,考察了在催化量硒作用下苯胺和硫醇的氧化羰基化反应。

Place 5 ml in a test-tube immersed in iced water, add 0.4 ml of a 100 g/l solution of potassium chloride R, 0.1 ml of diphenylamine solution R and, dropwise with shaking, 5 ml of nitrogen-free sulphuric acid R.

硝酸盐:取本品5ml置试管中,于冰浴中冷却,加100g/l氯化钾溶液0.4ml与0.1%二苯胺溶液0.1ml,边摇边滴加无氮的硫酸5ml,摇匀,将试管于50℃水浴中放置15分钟,溶液产生的蓝色与标准硝酸盐溶液(2 ppm NO3)0.5ml,加无硝酸盐的水4.5ml,在同一时间用同一方法处理后的颜色比较,不得更深。

Objective To investigate the reproductive toxicity of 3,4-dichloroaniline (3,4-DCA), the effect of 3,4-dichloroanilines on sperms of Wistar rats was studied.

目的 研究3,4-二氯苯胺(3,4-DCA)对雄性大鼠精子的影响,以探讨3,4-DCA对雄性大鼠的生殖毒性作用。

It was shown that these two strains both can utilize benzoate as sole carbon source and the maximum tolerance of benzoate are 1.7% and 1.600, respectively; These two strains both can grow on benzene, toluene, xylene, phenol, benzyl alcohol of as sole carbon source. Pfluorescens PFO1 can degrade dianiline, 3,5-dinitrosalicylic acid, p- dimethylaminobenzaldehyde while P. aeruginosa ATCC27853 can utilize 3,5-dinitrosalicylic acid, p- dimethylarninobenzaldehyde.

结果表明,两种菌都能在以苯甲酸钠为唯一碳源的基础培养基上生长,并且,对苯甲酸钠的耐受性分别达到1.7%和1.6%;两种菌都能以适当浓度的苯,甲苯,二甲苯,苯酚,苯甲醇为唯一碳源生长;荧光假单胞菌能以二苯胺,对二甲氨基苯甲醛,3,5-二硝基水扬酸为唯一氮源生长;铜绿假单胞菌能以3,5-二硝基水扬酸,对二甲氨基苯甲醛为唯一氮源生长。

Aniline、phenol and other presented organic reductants are basic materials of organic chemical industry and easy to obtain, so the presented organic—reducing leaching processes have great prospects of practical use.

由于本文研究的苯胺、苯酚等有机还原剂是来源广泛的基本化工原料,因而有机还原浸出方法具有广阔的实际应用前景。

It has been proved that surface confined quinones can greatly impove the electrocatalytic activity for ORR.

本论文中研究的氨基蒽醌聚合物修饰电极,与其它方法得到的醌类修饰电极比较,具有性质稳定、制备过程简单、活性点位浓度高等优点,而且同时具有类似聚苯胺的长链结构和蒽醌官能团的特性,为制备具有高氧还原催化活性的蒽醌修饰电极的研究提供了新的思路。

Poly-aminoanthraquinone modified electrode is more stable, more easily prepared, and can provide higher surface concentration of reactive sites compared with other quinones modified electrode by adsorpsion or doping.

本论文中研究的氨基蒽醌聚合物修饰电极,与其它方法得到的醌类修饰电极比较,具有性质稳定、制备过程简单、活性点位浓度高等优点,而且同时具有类似聚苯胺的长链结构和蒽醌官能团的特性,为制备具有高氧还原催化活性的蒽醌修饰电极的研究提供了新的思路。

The results of its intrinsic fluorescence spectroscopy and fluorescence phase diagram showed that when the guanidine hydrochloride concentration in denaturation solution was about 1.0 mol/L, there existed a partially folded intermediate of Bacillus amyloliquefaciens a-amylase during its unfolding procedure, which followed a three-state model; the result of its fluorescence probe showed that when the guanidine hydrochloride concentration in denaturation solution was about 1.0 mol/L, there existed some stable hydrophobic regions, which could interact with a hydrophobic reagent 8-anilino-1-naphthalene sulfonic acid, in the partially folded intermediate of Bacillus amyloliquefaciens a-amylase; and the results of fluorescence quenching using acrylamide and potassium iodide as quenchers showed the distribution of Trp residues in Bacillus amyloliquefaciens a-amylase in different denaturation solution, with the maximum number (8) of tryptophan residues in a partially folded intermediate Bacillus amyloliquefaciens a-amylase molecule could be quenched by potassium iodide; and the results of their protein electrophoresis and SEC showed that no aggregate or aggregate precipitation of Bacillus amyloliquefaciens a-amylase formed during the whole unfolding procedure of Bacillus amyloliquefaciens a-amylase induced by guanidine hydrochloride.

内源荧光光谱和荧光相图结果表明,当变性液中盐酸胍浓度约为1.0 mol/L时,芽孢杆菌a-淀粉酶的去折叠过程中出现一个部分折叠中间体,其去折叠过程符合&三态模型&;荧光探针结果表明,在溶液中盐酸胍浓度约为1.0 mol/L时,中间态芽孢杆菌a-淀粉酶分子中存在着能够与探针分子1-苯胺基-8-萘磺酸结合的稳定的疏水区域;荧光猝灭研究给出了不同程度变性的淀粉液化芽孢杆菌a-淀粉酶中的Trp的分布情况,结果表明中间态芽孢杆菌a-淀粉酶分子中能够被碘化钾猝灭的位于分子表面的色氨酸残基数目达到最大的8个;蛋白电泳和体积排阻色谱结果表明,在盐酸胍诱导的芽孢杆菌a-淀粉酶分子的整个去折叠过程中,不会以共价键或非共价键形式形成芽孢杆菌a-淀粉酶分子之间的集聚体或集聚体沉淀。

The results of its fluorescence probe showed that when the guanidine hydrochloride concentration in denaturation solution was about 1.0 mol/L,there existed some stable hydrophobic regions,which could interact with a hydrophobic reagent 8-anilino-1-naphthalene sulfonic acid,in the partially folded intermediate of Bacillus amyloliquefaciensα-amylase;with the denaturation concentration increasing,the stable hydrophobic regions disappered.the results of fluorescence quenching using acrylamide and potassium iodide as quenchers showed that using acrylamide as quenchers,with the protein denaturation extent increasing,the number of Trp that can be quenched increased untill all the Trp residues were quenched;Using potassium iodide as quenchers,with the maximum number(8) of tryptophan residues in a partially folded intermediate Bacillus amyloliquefaciensα-amylase molecule could be quenched by potassium iodide;with the denaturation concentration increasing,the number of Trp that can be quenched decreased to 5.the results of their protein electrophoreses and SEC showed that no aggregate or aggregate precipitation of Bacillus amyloliquefaciensα-amylase formed during the whole unfolding/refolding procedure of Bacillus amyloliquefaciensα-amylase induced by guanidine hydrochloride or urea.

ANS外源荧光探针结果表明:盐酸胍诱导的芽孢杆菌α-淀粉酶分子去折叠过程中存在着能够与探针分子1-苯胺基-8-萘磺酸结合的稳定的疏水区域;而随着芽孢杆菌α-淀粉酶分子在盐酸胍溶液中变性程度的加深,这一疏水区域逐步被瓦解。丙烯酰胺和碘化钾猝灭结果表明:在盐酸胍溶液中,随着芽孢杆菌α-淀粉酶分子变性程度的进一步加深,其分子内能够被丙烯酰胺接近的色氨酸残基逐渐增多,直至全部被猝灭。但位于芽孢杆菌α-淀粉酶分子表面的能够被碘化钾猝灭的色氨酸残基,在中间态芽孢杆菌α-淀粉酶分子中数目达到最大的8个,而随着其分子变性程度的进一步加深,反而减少至5个。

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What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢?

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我,一个心中布满虚荣的女孩子真实的想法。

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