苯胺

In the results of the optical properties, these molecular monomers have different HOMO and LUMO energy gap such that there are dual-emission and energy transfer mechanism in solution fluorescence spectrum. In the study of the electrochemical properties, various of triphenylamine derivaties have different oxygen binding site and they make elecropolymerization happen or not. In the applications of the hole-transport materials, the performance of compound 21 is better than other compounds. The electropolymerized-film may have residual cation molecules so they can increase the concentration of hole-transport. Due to this reason , compound 21 is suitable to become hole-transport materials.

在光学研究方面，由於目标化合物内单体的HOMO及LUMO能阶差异，使得在溶液萤光放射上有双发射及能量转移的情形发生；在电化学研究方面，不同的三苯胺衍生物由於氧基的位置不同，使得取代基在间位的化合物有不错的电聚合效果；而元件的应用上，具有咔唑基团的化合物21由於在形成电聚薄膜后，可能有残余的阳离子态化合物，使得电聚薄膜内的电洞数浓度较高，因此与其他元件相比之下，有较低的启动电压和不错的元件效率。

The novel triphenylamine group organic dye provided by the invention is novel in structure, is easy to be composed, is low in cost, and has excellent photoelectric properties, can be modified by molecule designing and shows a potential application prospect to replace a heavy metal organic photosensitizer.

本发明提供的新型三苯胺基有机染料结构新颖，易于合成，成本低廉，光电性能突出，可通过分子设计进行改性，显示出潜在的替代贵金属有机光敏化剂的应用前景。

Results of UV spectrum and cyclic voltammography showed that the introduction of triphenylamine into polymer main chain did not affect its optical and electrochemical properties so much, indicating that the polymer is a promising hole-transport material.

实验结果表明，这一聚合物具有良好的溶解性，高的玻璃化转变温度，而且4-叔丁基三苯胺在引入聚合物主链后仍然保持了其光学及电化学活性，作为空穴传输材料具有潜在应用价值。

A new 2,5-dithienylsilole with triphenylamine substituents at the 3,4-positions was synthesized.The TST was utilized to construct conjugated silole-containing poly(3,6-carbazole)s PCz-TST with TST contents of 1%～20%.

合成了一种3，4-位为三苯胺的新型silole单体及其与 N-己基-3，6-咔唑组成的共聚物PCz-TST，其中TST的含量变化为1%～20%。

It was found that the introduction of t-butyl or methoxy group in the triphenylamine subunit could lead to more efficient photoinduced intramolecular charge transfer, thus improving the overall photoelectric conversion efficiency of the resultant DSSC.

研究结果表明叔丁基或甲氧基取代三苯胺基团能够促进分子内电子转移，进而提高染料分子的敏化效率。

Next, another novel diamine, 5-5-(4-phenyl-1,3,4-oxadiazol-2-ylbenzene-1,3-diamine, was prepared and polymerization was carried out in the same way to obtain polyimides containig triphenylamine units and 1,3,4-oxadiazole moieties in the side chain .

接下来，合成另一个新型双胺5-5-(4-phenyl-1，3，4-oxadiazol-2-ylbenzene-1，3-diamine后，以相同方法进聚缩合反应，可制得另一系列三苯胺和1，3，4-恶二唑为侧链的聚醯亚胺。

First, N'-(4-aminophenyl)-N'-4-(5-phenyl-1,3,4-oxadiazol-2-ylphenylbenzene-1,4-diamine was prepared and polymerization was carried out by direct polycondensation with a series of dianhydrides to obtain polyimides containig triphenylamine units in the main chain and 1,3,4-oxadiazole moieties as pendent group.

首先合成新型双胺N'-(4-aminophenyl)-N'-4-(5-phenyl-1，3，4-oxadiazol-2-ylphenylbenzene-1，4-diamine后，与一系的芳香族二酐进聚缩合反应，可制得一系列三苯胺为主链且1，3，4-恶二唑为侧链的聚醯亚胺。

Experimental results showed that the hydrogenation degree can be enhanced significantly by the addition of triphenylphosphine. When the molar ratio of TPP, TPPTS and Ru is 2:5:1, 89% hydrogenation degree can be achieved after 12 h under reaction conditions of 5.0 MPa and 150~C.

考察了溶剂种类、水溶液的pH值、添加助剂三乙胺、水／有机两相体积、底物浓度等对对-氯硝基苯转化率和生成对-氯苯胺选择性的影响，并在90℃、4.0MPa、反应时间为6h的条件下，进行了催化剂的循环实验。

Sections from frontal lobe, occipital lobe, striatum and hippocampus of normal subjects and sections from hippocampus of AD patients were used in hematoxylin eosin, Lox Fast blue, toluidine blue stains and ulex europaeus agglutinin immunostaining.

应用荆豆凝集素(ulex europaeus agglutinin， UEA)免疫组织化学及甲苯胺蓝等染色观察正常增龄病例额叶、枕叶、壳核、海马及AD患者海马的神经元、毛细血管形态改变，应用图像分析技术测算各部位神经元与毛细血管密度比值并分析其与年龄之间的相关性。

Versicolor suited to grow and produce laccases at pH value 3.5-5.7, and unbuffered media were able to get good laccase productivity though buffered media could get higher laccase activity. Metal ions Cu(superscript 2+) and Mn(superscript 2+) in the culture could remarkably increase the activity of laccases. The optimal concentration of Cu(superscript 2+) was 0.008-0.08mmol/L, and the optimal concentration of Mn(superscript 2+) was about 0.01mmol/L, when the culture contained 0.1mmol/L 2,5-dimethoxyaniline.

结果发现该菌种适宜在pH值3.5~5.7环境下生长并合成漆酶，培养基中添加缓冲液可以获得更高的酶活，但不加则有较高的酶产率；铜和锰可以显著提高漆酶活力，当以0.1mmol/L 2，5-二甲基苯胺为诱导剂时，培养基中宜含0.008~0.08mmol/L Cu(上标 2+)，0.01mmol/L左右的Mn(上标 2+)。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新