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Diphenylmethane diisocyanate production process produces a lot of brine containing aniline and polyamine.

二苯基甲烷二异氰酸酯生产过程中会产生大量含苯胺和多胺的盐水,对其有效的处理是MDI生产技术中的一大难点。

The disubstituted ureas and the catalyst could be separated by addition of water and the catalyst could be reused without deactivation.

新型高效的菲咯啉钯-离子液体含氮化合物羰化催化剂体系,以苯胺为反应物时该体系的转化频率可以达到6000mol/mol/h;氢氧化铯-离子液体催化剂体系,可以在不加入化学计量脱水剂的条件下活化二氧化碳与脂肪族胺反应得到二取代脲,反应结束后可以通过加入水实现产品和催化剂体系的分离,催化剂体系可以重复使用。

It is insoluble in carbon disulphide, soluble in hot aniline and phenol.

它不溶于二硫化碳,溶于热苯胺和苯酚。

Not only has it a better ability of electrocatalysis to the redox reaction of Br〓 and Tl〓/Tl, but also it has a good response to H〓.

并对制备聚苯胺修饰电极的几种方法进行了比较,从而指出了最佳的聚合方法和条件。

Corrosion protection of cold-rolled steel was investigated with dispersed emeraldine base form of polyaniline.

研究了分散的颗粒状本征态聚苯胺(EB0对冷轧钢的腐蚀防护作用。

The emeraldine salts (ES1) of polyaniline were synthesized by emulsion polymerization with different dopants at 0℃.

另外,以DBSA、HCl及H3PO4为共掺杂酸,於室温下,藉二次掺杂制备含不同掺杂酸结构之聚苯胺(ES2)。

The specific heat of the emeraldine base form of polyaniline and the emeradine salt of polyaniline has been measured at temperatures between 1.8 and 45K. The experimental results have been interpreted in terms of the contributions from both the crystalline and the amorphous phases characterizing the polymer.

我们测量了聚苯胺及其掺杂盐酸后在1.8K至45K的热容,利用声子-分形子模型来处理非晶态对比热的贡献,对获得的数据进行处理,发现EB和ES的比热数据均不符合德拜理论,超出德拜模型的比热来源于非晶态的贡献。

1The chemical oxidization method was used to prepare emeraldine salt type conductive polyaniline doped with hydrochloric acid by interfacial polymerization which employ immiscible interface formed via the water and organic solvent, and we discuss the influences of synthetic conditions on the conductivity of PANI-HCl.

1采用化学氧化合成法,以界面聚合方式,利用水与有机溶剂所形成的不相容界面,直接制备以盐酸掺杂Emeraldine Salt型导电性聚苯胺,探讨合成条件对PANI-HCl之导电度的影响。

FT-IR spectra shows that the polyaniline is present primarily in the emeraldine salt form, and the polymeric chains interact with inorganic framework, most likely via V=O…HN hydrogen bonding. XRD,TG and DSC indicate that the lamellar structure of the V_2O_5 is preserved, PAn chains eliminate water form the interlamellar region and are partially inserted between the layers, and exist with extended-chain conformation owing to the confined environment.Electrochemical investigation in the range of 1.8~3.8V vs.

红外光谱表明复合物中PAn主要以导电聚苯胺盐的形式存在,PAn链与V_2O_5晶格之间可能形成了V=O…HN氢键。X射线衍射、热重和差示扫描量热证实了PAn/V_2O_5复合物保持了较规整的层间排列结构,PAn取代了V_2O_5干凝胶中的层间水而部分嵌入其片层间,由于受空间的限制,PAn分子链以比较伸展的链构象存在。

Their activities towards A431 epidermoid carcinoma cells and MDA-MB-468 human breast carcinoma cells were determined.

我们通过十步的反应路线,合成了21个6,7-取代-4-取代苯胺基-3-硝基喹啉类化合物。

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