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The decomposition of hydroxylamine hydrochloride under the reaction conditions was studied to understand its function during the amination process.

在此条件下,得到的苯胺收率为64 mol%,苯胺选择性为95.6%,转化数为48摩尔苯胺/摩尔V,此结果好于已有文献报道值。

According to the contrasts between the structure of PANI and that of POT, the conclusion could be made that steric hinderance effect of methyl groups in the poly-O-methylaniline is more prominent than induction effect and hyperconjugation.

比较聚苯胺和聚邻甲苯胺的结构可知,甲基取代苯环中的一个氢原子后,甲基对聚邻甲苯胺的空间位阻效应明显大于诱导效应和超共轭效应。

Based on the mechanism of coupling reaction,the reaction of melt metallocene-based Poly(Ethylene-α-Octene) initiated by dicumyl peroxide was studied at elevated temperature in oscillatory shear flow field.

苯胺、环氧丙烷为原料制备了N,N 二(2 羟丙基)苯胺,然后NHPPA与对硝基苯胺通过重氮偶合反应制备了一种具有推拉电子结构的偶氮化合物4 硝基 4′ N,N 二(2 羟丙基)氨基偶氮苯。

The results indicate that the change of oxidation and doping condition affects the ratio of benzenoid to quinoid ring and the orientation order of the polyaniline chain, which are important factors to decide the conductivity of polyaniline.

这些结果表明:氧化与掺杂条件的变化影响到聚苯胺中苯环与醌环的相对比例、聚苯胺链的排列有序度,而这些也是影响聚苯胺电导率的重要因素。

C. I. Reactive blue KN-R, Alizarin brilliant green G and Hostlam blue R could not be degraded by Zoogloea HP3. Furthermore, ABAS degradation was regressed under the exisitence of the above dyes. 1-Aminoanthraquinone-2sulfonic sodium, 1, 4-dihydroxylanthraquinone-2-sulfonic sodium, 1, 4, 5, 8tetrahydroxylanthraquinone, anthraquinone, aniline, phenol, catechol and ophthalic acid could be degraded by Zoogloea HP3. Aniline was the most degradable substrate among ABAS, aniline, phenol, catechol and o-phthalic acid. However, benzenesulfonic sodium and p-amino benzenesulfonic sodium were not degraded by it.

动胶菌HP3不能降解活性艳蓝KN-R、弱酸性绿GS及毛用活性蓝HW-R等蒽醌型染料,且染料的存在对菌体降解溴胺酸有不同程度的抑制作用;动胶菌HP3可以降解1-氨基蒽醌-2-磺酸钠、1,4-二羟基蒽醌-2-磺酸钠、1,4,5,8-四羟基蒽醌、蒽醌及苯酚、邻苯二酚、苯胺、邻苯二甲酸等苯系化合物,而不降解苯磺酸钠、对氨基苯磺酸钠;在溴胺酸、苯酚、邻苯二酚、苯胺、邻苯二甲酸中,苯胺是动胶菌HP3的天然底物。

Rhodamine B, Malachite green, Auramine O, Bismark Brown,Methyl Violet 5BN, Basic Magenta, Acid Orange II, Chrysophenine GX, Direct Fast Black G, Indigo, Sulphur Black, Solvent Red 24, Solvent Red 49, Solvent Brown 41, Solvent Orange 3,Pigment Yellow 154,155, Pigment Red 188,208, Meta-Diethyiaminophenol, M-Amino acetanilide , P-Amino acetanilide, etc.

主要产品:碱性玫瑰精,碱性品绿,碱性嫩黄O,碱性品红,碱性紫5BN,碱性红6DDN,酸性橙II,靛蓝,硫化黑,直接冻黄,直接黑G,溶剂红24,溶剂红49,溶剂棕41,溶剂橙3,溶剂橙62,颜料黄154,155,颜料红188,208,间羟基-N,N-二乙基苯胺,间氨基乙酰苯胺,对氨基乙酰苯胺

Seven Schiff bases of N-(4-hydroxyphenylmethylene)-1-naphthylamine, N-(4-hydroxyphenylmethylene)-p-methoxyaniline, N-(4-hydroxyphenylmethylene)-benzylamine, N-(4-hydroxy-3-methoxyphenylmethylene) furfurylamine, N-(4-hydroxy-3-methoxyphenyl methylene)-p-methylaniline, N-(4-hydroxy-3-methoxyphenylmethylene)-p-methoxyaniline and N-salicylidene-4-aminoantipyrine were first synthesized by the one step solid phase reactions between aromatic aldehydes with phenolic hydroxyl and amines at room temperature without solvent.

分别以带酚羟基的芳醛与胺类反应,首次通过室温固相反应一步合成了N-(4-羟基苯基亚甲基)-1-萘胺、N-(4-羟基苯基亚甲基)-对甲氧基苯胺、N-(4-羟基苯基亚甲基)-苄胺、N-(4-羟基-3-甲氧基苯基亚甲基)糠胺、N-(4-羟基-3-甲氧基苯基亚甲基)-对甲苯胺、N-(4-羟基-3-甲氧基苯基亚甲基)-对甲氧基苯胺和N-亚水杨基-4-氨基安替比林7种Schiff碱,反应15min完成,产率均超过90%。

First, aniline reacts with methyl chloroformate in the presence of tri-n-butylamine; then the unseperated mixture then reacts with aniline to get final product. The first step was quick, and finished within 30 min of refluxing.

该反应分两步进行,即在三正丁胺存在下,苯胺与氯甲酸甲酯加热回流生成苯胺基甲酸甲酯,后者不经分离再与过量苯胺继续反应,生成目标产物。

A facile method is presented for synthesis of malonaldehyde dianil from propargyl alcohol by oxidizing using chromium trioxide and addition reaction with aniline.

以丙炔醇为原料,经三氧化铬氧化生成丙炔醛后,直接与苯胺反应简便地合成了β-苯胺基丙烯醛缩苯胺

In order to research the influence of polyaniline on acrylic anticorrosive coating, the polyaniline/acrylic anticorrosive coating that the mass rate of emeraldine base form of polyaniline in coating was 0%, 1.5%, 3%, 5%, 10% were prepared, and theirs anticorrosive performance in 3.5% NaCl solution was studied by Tafel and EIS.

为了研究本征态聚苯胺对丙烯酸涂层防腐性能的影响,制备了本征态聚苯胺质量分数分别为0%,1%,3%,5%及10%的聚苯胺/丙烯酸防腐涂层,应用Tafel极化曲线和电化学阻抗谱方法对比了其在3.5% NaCl溶液中的防腐性能。

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