苯胺

Goal compound synthesis namely: Take the vanillic acid as outset raw material, obtains 4- hydroxyl - 3- anisole methyl formate with the methyl alcohol reflux conditions, then after the etherification, the nitration, the return to original state, the ring closure response obtains 6- methoxy - 7- animal pen oxygen radical kui zuo lin - 4- alkone, then passes through the chlorination, the substitution aniline, to escape responses again and so on animal pen oxygen radical, etherification to obtain the goal compound; The goal compound and the diethylamine had the amine substitution reaction to obtain TM1, namely 4- benzene amino - 6- methoxy - 7- [2- hydroxyl - 3-(N, N- two ethyl aminos) third oxygen radical] kui zuo lin; Through zuo has the etherification with the Austria niter to respond obtains TM2, namely 4- benzene amino - 6- methoxy - 7- [2- hydroxyl - 3-(2- methyl - 5- nitryl imidazole) third oxygen radical] kui zuo lin.

目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

Effects of preparation method and reactive process on the nitrobenzene hydrogenation performance of CeO〓 catalyst had also been investigated.

考察了制备工艺和反应工艺对CeO〓催化剂上硝基苯加氢制苯胺反应的影响。

Modifications of alkylation, chlorination and Vilsmeier reaction were employed for the synthesis of aromatic aldehydes bearing nitrogen mustard derivatives and halogenoalkylpiperazinyl.

通过对Vilsmeier反应、烷基化反应和氯化反应的改进提出了以简单易得的苯胺和苯基哌嗪为原料制备氮芥和哌嗪芳香醛的方法。

The 1,5-Bis(4-aminophenylazo) anthraquinone, 1,5-bis(4-hydroxyphenyl azo) anthraquinone and 1,5-bis(3-methyl-4-hydroxyphe nylazo) anthraquinone were synthesized by diazotizing 1,5-biaminoanthraquinone with nitrosyl sulfuric acid and coupling with aniline, phenol and o-cresol.

合成以1，5-二氨基蒽醌为原料，经亚硝酰硫酸重氮化，分别和苯胺、苯酚及邻甲酚偶合，得到双（4-氨基苯）－1，5-二偶氮蒽醌，双（4-羟基苯）－1，5-二偶氮蒽醌和双（3-甲基－4-羟基苯）－1，5-二偶氮蒽醌，反应产率达47%~62%。

METHODS: Heparin with an aldehyde group as reducing end was prepared by nitrous acid degradation method.

将肝素钠用亚硝酸降解法降解，得到还原末端为醛基的肝素，分别溶解于二甲亚砜、含0.05 mL，0.5 mL冰醋酸的二甲亚砜溶液，再与对巯基苯胺发生还原胺化反应，用氰基硼氢化钠作还原剂，得到带巯基的肝素衍生物。

Counterdiffusion of solvent and nonsolvent during the formation of the as-spun fibers was studied in detail.

研究了纤维成形过程中的双扩散问题，初生纤维的结构形态以及聚苯胺在纤维中的分布形态、结晶等，探讨了影响纤维导电性能的诸多因素等。

A novel PAn/CeO2 nano-composite has been successfully synthesised by three different ways, ie, in-situ dispersion polymerization with nano CeO2 particles, in-situ polymerization in CeO2 nanaparticles hydrosol and in-situ polymerizatoin in CeO2 nanoparticles organosol.

本论文采用三种不同的方法：在CeO2纳米粒子存在下的在位分散聚合法、CeO2纳米水溶胶中的原位聚合法、CeO2纳米有机溶胶中的原位聚合法制得了聚苯胺/纳米CeO2复合材料。

The effect of HCl doping process on the conductivity of polyaniline was investigated through orthogonal tests.

采用正交实验法研究盐酸掺杂工艺对导电聚苯胺电导率的影响。

For intramolecular electron transfer reactions in solution,the fluctuations of the intramolecular vibrational modes are much faster than that of solvent mode.Thus,the reaction-diffusion equation is commonly used to describe the motion of solvent,with a sink function to treat the vibrational high-frequency mode.Based on this theory-so -called the Sumi-Marcus theory,we proposed an imaginary-time split operator approach to solve the reaction-diffusion equation.The approach is applied to evaluate the intermolecular ET rate between oxazine 1 and N,N-dimethlaniline.By measuring the two average survival times of the donor state probability and the rate constant in long time limit,the full kinetics of the ET is revealed with a variety of sink functions.

对于扩散控制的溶液中的电子转移反应，分子内振动模的运动比溶剂运动快很多，Sumi-Marcus理论提出用反应扩散方程(reaction-diffusion equation)处理溶剂的扩散运动，而分子内的振动用sink函数来表示，我们基于此理论发展了用虚时间分裂算符的方法(imaginary-time Split operator approach)解反应扩散方程，并将其应用于嗪1(oxazine 1，OX1)和N，N-二甲基苯胺分子之间的电子转移反应，Sink函数采用几种不同的微扰表达式，通过计算得到给体几率衰减的两种平均速率和长时间极限下的速率常数，揭示了该体系电子转移过程中的一些动力学性质。

CNTs ; nano tube PANIs ; coating treatment ; conducting fabric ; anti-electromagnetic wave

碳纳米管；纳米管聚苯胺；涂层整理；导电织物；抗电磁波

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。