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苯胺

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It is demonstrated that living polymerization can be achieved when the concentration of electron pair donors such as DMAB or Et3N is higher than that of trace water in the polymerization system,and that polymers with narrow molecular weight distribution can be obtained.

发现当N,N-二甲基苯胺或三乙胺的浓度稍高于质子性杂质的浓度时,即能实现异丁烯的活性聚合,得到分子量分布较窄的聚合物。

One pot synthesis of tetrahydroquinolines from aldehyde, aniline and enol ethers catalyzed by iodine was also applicable and provided tetrahydroquinolines in comparable yields.

在碘的催化下,从醛、苯胺和烯醇醚出发"一锅"合成了四氢喹啉衍生物,反应的产率与使用预制的亚胺进行的反应基本相同。

In addition, ioding was found to be an efficient catalyst for the imino Diels-Alder reaction of N-arylimine and enol ethers and the reaction provided tertrahydroqinolines in good yields. One pot synthesis of tetrahydroqinolines from aldehyde, aniline and enol ethers was also achieved using iodine as the catalyst. The chemical yield of the"one pot"reaction was comparable with that obtained using preformed N-arylimine.

此外我们也发现碘能够有效地催化N-芳基亚胺与烯醇醚的Diels-Alder反应,以很高的化学收率得到了四氢喹啉衍生物,并且发现碘也能够直接催化芳香醛、苯胺、烯醇醚的三组分"一锅"反应,获得的化学产率与使用预制的N-芳基亚胺相当。

The poly with p-aminophenyl-ethynyl as a side-group was synthesized through Pd-catalyzed Sonogashira coupling reaction between 4-[(2,5-dibromophenyl)ethynyl] aniline and 1,4-diethynyl-2,5-bis benzene.

通过单体4-[(2,5-二溴苯)乙炔基]苯胺和1,4-二乙炔基-2,5-二戊氧基苯之间的Sonogashira偶合反应合成了带有p-氨基苯乙炔基共轭侧基的聚对苯撑乙炔。

Dibromoaniline is an important organic intermediate for synthesis of pharmaceuticals , alkaloid and ferromagnetics.

2 ,6 二溴苯胺是重要的有机合成中间体,可用于合成医药、生物碱和铁磁体等。

At 12w after operation, the cells in control group still behaved as fibroblasts and fibrocartilage like cells were predominant in grafts of cell and gene groups , the grafts in these two groups were similar to normal ligament morphologically.

手术后12周,对照组显现移植物内有大量的成纤维细胞,甲苯胺兰染色轻度异染;而细胞组和基因组细胞量减少,显现类软骨性状,细胞排列与正常前交叉韧带接近。

The measuring system is comprised of three layers of components: an electrochemical control layer, a fluidic control layer, and a control interface layer.

所观察到的有效振动模式主要是苯环平面上对称的运动,和苯胺上所观察的结果相互一致。

Teflubenzuron was synthesized from 2,4-difluoronitrobenzene and 2,6-dichlobenil as starting reagent through six-step reaction with the yield of 75.3%.3,5-Dichloro-2,4-difluoroaniline was synthesized by chlorination,reduction reaction from 2,4-difluoronitrobenzene,the yield was 84.5%;2,6-difluorobenzamide with the yield of 87.7% was synthesized by fluoridation and hydrolysis from 2,6-dichlobenil.

以2,4-二氟硝基苯和2,6-二氯苯腈为起始原料,经过6步反应合成伏虫隆,总收率为75.3%。以2,4-二氟硝基苯为原料,经过氯化、还原反应合成3,5-二氯-2,4-二氟苯胺,产率为84.5%;以2,6-二氯苯腈为原料,经过氟化和水解,制得2,6-二氟苯甲酰胺,产率为87.7%;将Ⅱ与二碳酸酯酰化,合成2,6-二氟苯甲酰异氰酸酯,产率为91.3%;Ⅲ与Ⅰ加成,得到杀虫剂伏虫隆,产率为95%。

Here we found the optimum situation to determine LAP: the concentration of Tris-HCl is 125 mmol L^(-1) and the optimum pH is 7.2, temperature is 37℃, under this condition, Michaelis constant is 0.15 mmolL^(-1), ground substance concentration is 6.0 mmol L^(-1), with 157 health people serum samples (81 from male, 76 from female),x± s=35.7 UL^(-1)±8.2 UL^(-1), we established the method and reference value for clinical application and automatic analysis.

测定亮氨酰氨基肽酶的最适条件:选用浓度为125mmolL^(-1)的Tris-Hcl缓冲液,最适pH为7.2,温度取37℃,得出在此实验条件下的米氏常数Km为0.15mmolL^(1),亮氨酰对硝基苯胺浓度取6.0mmolL^(-1),取健康体检者血清157例(男81例,女76例),测得x±s为35.7UL^(-1)+8.2UL^(-1),建立了适合于临床应用及有动生化分析仪的方法和参考值。

In previous work of helicid's structure modification show that 4 substituted groups of helicid are some ordinary acyclic and substituted aniline group, and it had no heptad heterocyclic substituted group.

在前期的豆腐果苷结构修饰工作中,豆腐果苷4位取代基多为一些简单的脂肪族、取代苯胺基等,尚无七元杂环作为取代基的此类化合物。

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