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苯胺

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3-Nitrodiphenylamine is generally synthesized by the Ullmann condensation of N-(3-nitrophenyl) acetamide with bromobenzene.

摘 要:间-乙酰氨基硝基苯与溴苯发生Ullmann缩合反应是制备3-硝基二苯胺最常用的方法。

When acetanilide content was 20%, the elongation at break point rose to about 10 times of pure PVC.

当乙酰苯胺质量分数为20%时,材料的断裂伸长率增大至纯PVC的10倍左右。

Acetanilide preparation of micro-experiments, the use of smaller amounts of reagents and shorter time to obtain a satisfactory experimental results.

乙酰苯胺制备的微型实验,利用较少量的试剂和较短的时间获得了满意的实验效果。

How long would it reach the balance? It was dependent on the annealing temperature and the content of acetanilide.

达到平衡的时间与热处理温度和乙酰苯胺的质量分数有关,温度越低,达到平衡的时间越长,反之越短。

While acetanilide could induce PVC to form a soft network,as made the elongation at break be 11 times of pure PVC.

而乙酰苯胺诱导PVC形成了柔性的网络结构,使PVC的断裂伸长率增至纯PVC的11倍。

Acetanilide could promoted the growth of micelle crystal .

乙酰苯胺能明显促进胶束状晶体生长。

On the contrary, the existence of electron-donating groups on the benzene ring would prolong reaction times and decrease the yields.

使用苯胺为反应底物考察了各因素的影响,在优化的反应条件下,苯胺的转化率可达到99.7%,N-甲基-N-苯基氨基甲酸甲酯的收率为83.2%。

It was found that with the Ni-Zr-Ce/Al2O3 catalyst prepared in present work the production of aniline from benzene, hydrogen peroxide and aqueous ammonia could be realized under mild conditions, that is, at about 50 °C and under atmospheric pressure, and the selectivity of aniline is much higher than that of phenol.

发现在常压、50 ℃的温和条件下,该催化剂对苯、氨水与 H_2O_2直接氧化胺化生成苯胺有较好活性,并且其对苯胺的选择性远远大于对苯酚的选择性。

A series of Ni-V/γ-Al2O3 catalysts were prepared and used in the one-step synthesis of aniline from benzene, hydrogen peroxide, and aqueous ammonia and/or urea.

设计并制备了Ni-V/γ-Al2O3催化剂,研究了其上苯用过氧化氢氧化氨化一步直接合成苯胺的性能和不同氨基源对合成苯胺的影响。

The empirical Freundlich equation was successfully employed to describe the adsorption process. Due to hydrogen-bonding interaction between the tertiary amino groups on the resin and the amino groups of p-methylaniline, the adsorption capacity towards p-methylaniline of NDA-8 is higher than that of NKA when the equilibrium concentration is 5 mmol/L.

结果表明:2种树脂吸附对甲苯胺均符合Freundlich等温吸附方程,NDA-8树脂表面叔氨基与对甲苯胺之间的氢键作用可有效强化吸附能力,在平衡浓度均为5mmol/L的情况下,其吸附容量达到NKA的1.5~1.6倍。

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