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PANSA nanoparticles were synthesized by oxidative copolymerization of aniline and 2-methoxyaniline-5-sulfonic acid in 1.0 mol/L HCl aqueous solution with ammonium peroxydisulfate as oxid...

PANSA纳米颗粒通过化学氧化聚合法,在无乳化剂或稳定剂存在下,以过硫酸铵为氧化剂,在1.0m ol/L盐酸水溶液中由苯胺与2-甲氧基苯胺-5-磺酸合成得到。

In a chemical oxidative seeded polymerization system of aniline using the polystyrene seed particles pretreated by emulsifier or modified by copolymerizing with acrylic acid, colloidally stable core-shell polystyrene/polyaniline composite particles were prepared.

苯胺的化学氧化种子聚合体系中,以乳化剂预处理和与丙烯酸共聚改性的聚苯乙烯粒子为种子,制备具有一定分散稳定性的聚苯乙烯/聚苯胺核-壳型复合高分子粒子乳液。

Methods: 2ethyl aniline was used as starting material of the synthesis and was processed by acetic anhydride acylation, strong nitric acid nitraction at low temperature, and desacyl synthesis to produce 2ethyl5nitro aniline. The product was then synthesized to 3methyl6nitro1Hindazole by using ringclosing reaction in the presence of NaNO2, and then ethylated to obtain 2,3diethyl6 nitro2Hindazole. The latter compound was then reduced by SnCl2/Hcl to get target compound 2,3diethyl6nitro2Hindazole.

以2乙基苯胺为原料经醋酐酰化、浓硝酸低温硝化及去酰基保护合成2乙基5硝基苯胺,后用亚硝酸钠关环得3甲基6硝基1H吲唑,经硫酸二甲酯甲基化得2,3二甲基6硝基2H吲唑,最后用氯化亚锡将其还原得到目标产物,通过1H NMR确定结构与目标产物一致。

Methods: 2-ethyl aniline was used as starting material of the synthesis and was processed by acetic anhydride acylation, strong nitric acid nitraction at low temperature, and desacyl synthesis to produce 2-ethyl-5-nitro aniline. The product was then synthesized to 3-methyl-6-nitro-lH-indazole by using ring-closing reaction in the presence of NaNO2, and then ethylated to obtain 2, 3-diethyl-6- nitro-2H-indazole. The latter compound was then reduced by SnC12/Hcl to get target compound 2, 3-diethyl-6-nitro-2H-indazole.

以2-乙基苯胺为原料经醋酐酰化、浓硝酸低温硝化及去酰基保护合成2-乙基-5-硝基苯胺,后用亚硝酸钠关环得3-甲基-6-硝基-1H-吲唑,经硫酸二甲酯甲基化得2,3-二甲基-6-硝基-2H-吲唑,最后用氯化亚锡将其还原得到目标产物,通过1HNMR确定结构与目标产物一致。

As for PAn-based composites, the influences of the kinds of oxidant, the amount of hydrochloric acid and barbon black on conductivity were investigated, Li/PAn button-type secondary batteries were assembled with PAn-based composites which were synthesized by chemical oxidative polymerization and used as cathode, the influences of the kinds of oxidant, synthesized technics, conducting carbon black added mode and PAn/metal oxide composites used as cathode on the properties of these batteries were studied.

对于聚苯胺基复合材料体系,研究了氧化剂种类、盐酸用量、炭黑用量对复合材料电导率的影响;以化学法制备的聚苯胺基复合材料作正极组装了Li/PAn二次扣式电池,探讨了氧化剂种类、聚合工艺、导电剂的加入方式以及PAn与金属氧化物复合后作电池正极的性能。

Diamino-dipenylamine-2-sulfonicacid was used as an alternative of benzidine,and reacted withl-hy droxy-8-aminonaphthalene-3,6-dusuifonicacid,m-benzioc-diamine and aniline to synthesize eco-friendly black direct dye s.

报道了以4,4'-酸(4,4'-二氨基-二苯胺-2-磺酸)代替联苯胺,与H酸(1-羟基-8-氨基-3,6-二萘磺酸)、间苯二胺、苯胺等合成无致癌作用的环保型黑色直接染料。

Aniline blue staining can stain the host tissue, forming a light blue background, which results in unsatisfactory observation of fungal structures.

苯胺蓝组织透明染色方法也可观察到病菌的不同发育阶段,但苯胺蓝易使寄主组织产生浅蓝色背景,而菌体呈现深蓝色,观察效果不理想。

For example, aniline hydrochloride and aniline sulfate sill stain lignin yellow.

例如苯胺盐酸盐和苯胺硫酸盐可以把木质部染成黄色。

Through these we find the characterization of ammonium sulfate and aniline ratio, hydrochloride and perchlorate (HCLO4) concentration, polyvinylpyrrolidone and polyvinyl alcohol of Concentration on the morphology and conductivity polyaniline films have great impact.

通过这些表征我们发现过硫酸铵与苯胺摩尔比、盐酸和高氯酸(HCLO4)的浓度、聚乙烯吡咯烷酮和聚乙烯醇的浓度对聚苯胺薄膜形貌和电导率有很大的影响。

Here, we describe a solvent-free mechanochemical route to polyaniline in which the reaction is induced by ball-milling an aniline salt and an oxidant under ambient conditions.

我们在此描述一个无溶剂的机械化学路径聚合苯胺,在环境条件下通过球磨苯胺盐和氧化剂反应。

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