苯胺

Application of conductive polyaniline on the electronic related industry has become more and more interesting and popular. In this research, the chemical oxidization method was used to form emeraldine salt type PANi doped with HNO3 and dodecyl benzene sulfonic acid.

导电性聚苯胺(Polyaniline；PANi)应用在电子相关产业是目前相当热门的研究领域，本研究采用化学氧化合成法制备硝酸与十二烷基苯磺酸共掺杂之Emeraldine Salt型聚苯胺。

The SDS micellar-templated polymerization of aniline is strongly pH-dependent in this case. A wider range at low pH (1.0～4.0) was required to produce the conducting PANI, optimal pH was 3.0 and the transition from emeraldine salt to emeraldine base form of PANI occurred at about pH 10.4 in this anionic micellar system.

结果表明该反应具有明显的pH值依赖性， pH (1.0～4.0)是合成导电聚苯胺所必需的，其最适pH值为3.0，聚苯胺由导电的翠绿亚胺盐转变为本征态发生在pH 10.4。

2The chemical oxidization method was used to prepare emeraldine salt type conductive polyaniline co-doped with hydrochloric acid and dodecylbenzene sulfonic acid (PANI－HCl－DBSA) by interfacial polymerization which employ immiscible interface formed via the water and organic solvent.

2采用化学氧化合成法，以界面聚合方式，利用水与有机溶剂所形成的不相容界面，直接制备以盐酸和十二烷基苯磺酸共掺杂ES型导电性聚苯胺(PANI－HCl－DBSA)，藉由加入适量之DBSA，达到聚苯胺可完全溶解分散於有机溶剂中的目的。

Part three: Thermodynamics, Kinetics and Mechanism of aniline adsorption on carbon nanotubes The results show that the adsorption isotherm confirms to the Freundlich equation, and the adsorption is a spontaneous ,exothermal and decreasing entropy process.

碳纳米管吸附苯胺的吸附热力学、动力学及其吸附机理通过吸附等温式的拟合发现，碳纳米管原料对苯胺的吸附对Freundlich公式有最佳的拟合结果。

Part three: Thermodynamics, Kinetics and Mechanism of aniline adsorption on carbon nanotubesThe results show that the adsorption isotherm confirms to the Freundlich equation, and the adsorption is a spontaneous ,exothermal and decreasing entropy process.

碳纳米管吸附苯胺的吸附热力学、动力学及其吸附机理通过吸附等温式的拟合发现，碳纳米管原料对苯胺的吸附对Freundlich公式有最佳的拟合结果。

Amino-6-nitrobenzodifuroxan was prepared through a three-step reaction from starting material 3, 5-dinitrobenzoic acid:(1)3, 5-dinitroaniline (1) was synthesized from the reaction of DNBA and hydrazoic acid in inert solvent 1, 2-dichioroethane through Schmidt rearrangement with yield of 89.6%;(2) 1 was subjected to nitration to prepare pentanitroaniline (2) with yield of 51.1%;(3) The title compound was prepared from 2 and sodium azide in acetic acid through denitrogenation and then Schmidt rearrangement with yield of 86.8%, m.p.204℃～206℃.

以3，5-二硝基苯甲酸为原料经过3步反应合成了7-氨基6-硝基苯并二氧化吠咱：第1步反应，在二氯乙烷惰性溶剂中，DNBA与叠氮酸反应并发生Schmidt重排反应生成3，5-二硝基苯胺(1)，产率89.6%；第2步反应，1在含100%硫酸的硝硫混酸中硝化生成五硝基苯胺(2)，产率51.1%；第3步反应，2与叠氮酸反应，不经分离直接进行热解脱氮、Schmidt重排反应，得到目标化合物， m.p.204℃~ 206℃，产率86.8%。

The method is characterized in that the acid solution of one of hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid and hydriodic acid is divided into two portions; aniline monomer and ammonium persulfate are respectively added; then aniline monomer solution and ammonium persulfate solution can be prepared.

一种乙酸松油酯的制备方法，其特征是，将盐酸、硫酸、硝酸、磷酸、氢碘酸中任一种酸溶液分成两等份，并分别加入苯胺单体和过硫酸铵，形成苯胺溶液和过硫酸铵溶液。

Under the experimental conditions of polymerization temperature at 25℃, n/n of 1:1, c of 0.03mol/L, the nanocomposite of polyaniline/monmorillonite was prepared by intercalative polymerization.

在聚合温度为25℃，蒙脱土质量含量为苯胺的0.5%，过硫酸铵和苯胺的摩尔比为l：1，掺杂剂磺基水杨酸摩尔浓度为0.03mol/L的实验条件下，运用插层聚合的方法制备出PAn-MMT复合纳米材料。

Conductive composite materials of polyaniline/Ca-bentonite and PAn/organicbentonite were pre-pared by means of intercalative polymerization.

采用插层聚合法制备了导电聚苯胺／钙基膨润土、聚苯胺／有机化膨润土复合材料。

Racemic backbones 2-amino-2'-hydroxy-6,6'-dimethyl-l,l'-biphenyl la and 2-amino-2'-hydroxy-4,4',6,6'-tetramethyl-l,1'-biphenyl 1b were synthesized from o-methylaniline and 2,4-dimethylaniline via nitration, diazotation/iodination, Ullmann coupling, selective reduction, diazotation/hydrolysis and hydrogenation.

从邻甲苯胺及2，4-二甲基苯胺出发，经过硝化，重氮化-碘代，偶联，单还原，重氮化-水解及还原反应合成了消旋体骨架2-氨基-2'-羟基-6，6'-二甲基-1，1'-联苯1a和2-氨基-2'-羟基-4，4'，6，6'-四甲基-1，1'-联苯1b。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。