苯胺

The investigation also showed that, the antioxidants with same action mechanism, for example, as both radical scavengers, phenol and amine antioxidants are synergistic; but the synergistic effects between two antioxidants with different action mechanism, such as radical scavenging phenol and amine antioxidants, and hydroperoxide decomposing ashless dithiocarbamate, are much stronger, and the heterosynergism between dithiocarbamate and alkylated diphenylamine is outstanding, which can serve as high temperature ashless high performance antioxidant combination; the heterosynergism among three antioxidants with three different action mechanisms, for example, the tri-component combination of alkylated diphenylamine, zinc dithiocarbamate and organic molybdate ester, can achieve excellent antioxidation performance.

研究还表明，具有相同抗氧机理的不同抗氧剂，如酚类和胺类抗氧剂，具有协同作用；不同作用机理的两抗氧剂之间，如自由基清除剂和氢过氧化物分解剂，具有更好的抗氧化协同效果，其中，无灰氨基甲酸酯与烷基化二苯胺抗氧剂具有最佳的抗氧协同效能，可成为高温无灰抗氧剂应用的一个很好选择；不同抗氧机理的三种抗氧剂复合，如烷基化二苯胺，氨基甲酸锌和有机钼酸酯组成的三元复合抗氧剂，具有更为优秀的抗氧化性能。

Computationalresults indicate that the no-planar trans-benzanilide is the most stable structure. The spectra indicate that the Franck Condon region photodissociation dynamics have multidimensional character withnine activemodes. The intensity of υ24 mode in methanol is much stronger than that in acetonitrile. Compared with fatty amides and benzamide, phenyl substitution for H atom on-NH2 group makes C=O solvent effects disappear.

结果表明，苯甲酰苯胺的非平面反式结构为最稳定结构；在Frank-Condon区域内，苯甲酰苯胺主要由9个活性振动模组成；其中ν24（苯环上C＝C不对称伸缩振动和CCH的面内弯曲振动，NH面内弯曲振动）振动模在甲醇溶剂中的强度远远大于其在乙腈的强度；与脂肪酰胺类化合物和苯甲酰胺的研究结果比较发现，苯基取代－NH2上的H原子使得C＝O不再具有明显的溶剂效应。

2,7-di-diphenylamine-spiro[fiuorene -7,9'-benzofluorene] was successfully synthesized .Its structure was determined by 1HNMR、MS、IR and Elemental Analysis.Yield of each reaction was more than 70%.

设计并合成了一种新型的含二苯胺基团的螺芴化合物2，7-双二苯胺-螺环-[芴-7，9'-苯并芴]，并通过了1HNMR、MS、IR、元素分析图谱检验，每步反应的产率均在70%以上。

After reaction for 30 minutes, the removal rate of TOC is 40% lower than that of aniline, which shows a series of intermediate by-products, mainly benzoquinone, as detected by HPLC and IC, are resulted from the decomposition of aniline.

反应30min后，TOC 去除率比苯胺去除率低40%左右，表明伴随着苯胺的分解，生成一系列中间产物，通过HPLC和IC检测主要为苯醌等。

After reaction for 30 minutes, the removal rate of TOC is 40% lower than that of aniline, wh ic h shows a series of intermediate by-products, mainly benzoquinone, as detected by HPLC and IC, are resulted from the decomposition of aniline.

反应30min后，TOC去除率比苯胺去除率低40%左右，表明伴随着苯胺的分解，生成一系列中间产物，通过HPLC和IC检测主要为苯醌等。

The cesium fluoride-mediated N,N-diarylation of 4-(biphenyl-4-oxy)aniline with 4-fluoronitrobenzene and subsequent reduction of the dinitro intermediate led to a new triphenylamine-based diamine monomer, 4,4'-diamino-4-(biphenylyl-4-oxy)triphenylamine.

以氟化铯为媒介将此苯胺与 4-fluoronitrobenzene 进行芳香族亲核取代反应，随后再进行dinitro中间体的还原反应，制得ㄧ种新型具有三苯胺结构的芳香族二胺单体4，4'-diamino-4-(biphenylyl-4-oxy)triphenylamine。

The recent advances in the main clean processes to synthesize diphenylmethane diisocyanates are reviewed, such as BTC method, condensation of aniline, reductive carbonylation of nitrobenzene, oxidative carbonylation of aniline, methoxycarbonylation of aniline, alcoholysis of N,N'-diphenyl urea and the coupling process.

回顾了清洁合成二苯甲烷二异氰酸酯的几种主要方法，如BTC法、苯胺缩和法、硝基苯还原羰基化法、苯胺氧化羰基化法、碳酸酯法、二苯基脲法和反应耦合法等合成路线。

The white mixture of starting materials turns green after milling, indicating the formation of polyaniline in its doped emeraldine oxidation state.

白色的初始材料混合物在球磨后变成了绿色，这表明，混合物在掺杂苯胺绿氧化状态下形成了聚苯胺。

The peaks at 389 and 430 nm and the broader absorption at 869 nm correspond to electronic transitions from valence band to polaron band characteristic of the doped emeraldine oxidation state of polyaniline.19 This is consistent with the green color observed in the product.

在389和430 nm波长处的峰值以及在869 nm波长处的较宽吸收，对应于聚苯胺的掺杂苯胺绿氧化状态从价带到极化子能带的电子跃迁特性。19 这与产物观察到的绿色相一致。

By way of sulfonation on emeraldine base polyaniline, sulfonated polyaniline was prepared. Effect of reaction conditions on conductivity and sulfonation degree of SPAN was discussed in detail. The relationship of sulfonation degree and solublility was also discussed.

通过磺化的方法，对本征态聚苯胺进行了磺化改性研究，讨论了磺化条件对磺化聚苯胺电导率、磺化度的影响以及磺化度与溶解度的关系。

What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢？

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我，一个心中布满虚荣的女孩子真实的想法。