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Is a high-tech private enterprise, located in Laohekou City, Hubei Province, the main products are: 3,4 - dichloro-nitrobenzene; 3,4 - dichloroaniline; 2,4 - dimethyl-nitramine p; 2,4 - dimethylaniline; 2,6 - dimethyl-nitrobenzene; 2,6 - dimethylaniline; 3,5 - dimethyl-nitrobenzene; 3,5 - dimethyl Aniline; acrolein; Glutaraldehyde and other fine chemical products.

老河口联谊化工有限公司为一家高科技民营企业,位于湖北省老河口市,主要产品有:3,4-二氯硝基苯;3,4-二氯苯胺;2,4-二甲基硝基苯;2,4-二甲基苯胺;2,6-二甲基硝基苯;2,6-二甲基苯胺;3,5-二甲基硝基苯;3,5-二甲基苯胺;丙烯醛;戊二醛等精细化工产品。

Results indicated that the content of polyaniline had significant influence on the anticorrosive performance of the coatings.

结果表明:聚苯胺含量对涂层的防腐蚀性能有较大影响,当涂层中聚苯胺含量较低时,随着聚苯胺在涂层中质量分数的增加,涂层的防腐蚀性能相应提高;随涂层中聚苯胺质量分数的进一步增大,涂层的防腐蚀效果开始下降;涂层中聚苯胺含量为5.0%时具有最佳的防腐蚀性能。

Many aromatic amine, such as aniline and N-methylaniline and diphenylamine, whose antidetonating quality are excellent, are not only often employed as concocting ingredient of antiknock but also suitable to research with electrochemical methods.

许多苯胺类化合物,如苯胺、N-甲基苯胺、二苯胺是性能良好的非金属抗爆制,也是抗爆剂常用的调合组分,且具有电子转移性质,适于电化学研究。

After sodium bisulfite reacted with methanal at 60-65℃ for 0.5h, aniline was dripped into the system to synthesize phenylaminomethyl-sodium sulfonate subsequently, the diazol solution of p-nitroaniline was dripped into phenylaminomethyl-sodium sulfonate synthesized to form 4'-nitro-4-aminoazobenzene. The compound was then added into diazol solution of p-chloroaniline to obtain the object product, which was identified by IR spectrum and element analysis.

在60~65℃温度下,亚硫酸氢钠与甲醛反应半小时之后滴入苯胺生成苯胺基甲基磺酸钠,另将硝基苯胺重氮化得到重氮盐溶液滴入苯胺基甲基磺酸钠中得到4'-硝基-4-氮基偶氮苯,然后将其滴入氯苯胺重氮化后的重氮盐溶液中,得经红外光谱检验和元素分析证实的目标产物。

Using 9 fluorenylmethylchloroformate as a pre column derivatising agent, nine aromatic amines ( o toluidine, 4 chloro o toluidine, aniline, 2,4,5 trimethylaniline, p cresidine, p chloroaniline, 4 aminodiphenyl, o anisidine, 2 naphthylamine,) are separated and a quantitative analysis method is studied by means of RP HPLC.

以氯甲酸 9 芴基甲酯为柱前衍生试剂,对 9种单环芳香胺(邻甲苯胺、4 氯邻甲苯胺苯胺、2 ,4 ,5 三甲基苯胺、3 氨基对甲苯甲醚、对氯苯胺、4 氨基联苯、邻氨基苯甲醚、2 萘胺)进行了高效液相色谱分离和定量分析方法研究。

This study concludes the following four parts:(1) acute toxicity of several chloroanilines to zebra fish;(2) effects of chloroanilines on antioxidant defense of crucian carp;(3) effects of chloroanilines on serum sex steroids in crucian carp;(4) effects of chloroanilines on lymphocyte proliferation in crucian carp, and the detailed results and main conclusions are concluded as follows

本论文以2-氯-4-硝基苯胺、4-氯-3-硝基苯胺、2-氯-5-硝基苯胺、2,4-二氯苯胺、3,4-二氯苯胺、2,5-二氯苯胺、2,3-二氯苯胺为研究对象,研究分为四部分:(1)氯代苯胺对鱼类的急性毒性;(2)氯代苯胺对鲫鱼抗氧化系统的影响;(3)氯代苯胺对鲫鱼血清性类固醇激素水平的影响;(4)氯代苯胺对鲫鱼淋巴细胞增殖的影响。

The acute toxicities of 2-chloro-4-nitroaniline, 4-chloro-3-nitroaniline, 2-chloro-5-nitroaniline, 2, 4-dichloroaniline, 3, 4-dichloroaniline, 2, 5-dichloroaniline, 2, 3-dichloroaniline to zebra fish were conducted in lab. 48h LC〓 values were 11. 18, 4. 62, 9. 23, 9. 55, 7. 07, 6. 68, 0.62mg/L respectively, and 96h LC〓 values were 6. 99, 2. 58, 8. 63, 7. 79, 6. 08, 5. 23, 0.49mg/L respectively.

1研究了2-氯-4-硝基苯胺、4-氯-3-硝基苯胺、2-氯-5-硝基苯胺、2,4-二氯苯胺、3,4-二氯苯胺、2,5-二氯苯胺、2,3-二氯苯胺对斑马鱼的急性毒性,经计算48h LC〓分别为11.18、4.62、9.23、9.55、7.07、6.68、0.62mg/L,96h LC〓分别为6.99、2.58、8.63、7.79、6.08、5.23、0.49mg/L,这7种化合物均属于高毒物质。

We have not found any reports that o-toluidine and N,N-dimethylaniline can be used as antiknock. The electrochemical properties of aromatic amine are in line with its' antidetonating quality and actual application.

而实际上采用胺类化合物作抗爆剂时,一般使用N-甲基苯胺苯胺、邻甲苯胺及间甲苯胺,尚未见到使用对甲苯胺和N,N-二甲基苯胺的报道。

At first, Polyaniline was synthesized by the improved chemical oxidation technique, then, PANI/HCl, PANI/TSA and PANI/DBSA were obtained by doping emeraldine with HCl, 4-methyl benzene sulfonic acid and dodecylbenzene sulfonate acid, separately. Leucoemeraldine was obtained in the N-dimethylformamide by using phenylhydrazine deoxidizing emeraldine in N_2 atmosphere.

本文首先通过改进合成条件的化学氧化法合成了聚苯胺,经氨水脱掺杂获得本征态聚苯胺,再经盐酸、对甲苯磺酸、和十二烷基苯磺酸掺杂,分别获得到质子酸掺杂的聚苯胺样品,然后在N,N-二甲基甲酰胺中,利用苯肼,在N_2氛围下还原本征态聚苯胺得到还原态的聚苯胺

For example, when there is only an alcohol as dopant, fiber-shaped nanostructure polyaniline is easily formed; when there is only a metallic ion as dopant, sphere-shaped nanostructure polyaniline is easily formed; when alcohol and metallic ion coexist, fibrous and sphere-shaped nanostructure polyaniline are formed at the same time.

如仅有醇类掺杂剂存在下,苯胺易于聚合成纤维状纳米结构的聚苯胺;仅有金属离子掺杂剂存在下,苯胺易于聚合成球形纳米结构的聚苯胺;在醇和金属离子掺杂剂共存时,苯胺能同时聚合成纤维状和球形纳米结构的聚苯胺

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