苯甲醛

Its zinc complex was applied in asymmetric direct aldol reaction of acetone and p-nitrobenzal...

设计合成了一种NOBIN衍生的手性配体，初步研究了该手性配体的双核锌配合物在对硝基苯甲醛和丙酮的不对称直接醇醛缩合反应中的催化应用，20℃和20mol％催化剂量下，获得了32.5％ee和72％收率的产物。

We first examined the ability of the catalyst to promote the direct aldol reaction between acetone and 4-nitrobenzaldehyde under various conditions.

通过偶联反应将催化剂1固载到硅胶上，并将其用于催化环己酮和硝基苯甲醛的aldol反应，dr值最高达到90：10，ee最高76%。

We found that when acetone was used as solvent, in the presence of TFA, cis-4-pyrrodin-1-yl-L-proline could catalyze the direct asymmetric aldol reaction between acetone and 4-nitrobenzaldehyde with 84% ee.

研究发现，该催化剂以丙酮为溶剂时，加入催化剂等当量的三氟乙酸可以较好的催化丙酮与对硝基苯甲醛之间的直接不对称Aldol反应，得到84%的ee值。

Two: Synthesized a novel rhodamine derivative with a single amidogen, then analyzed and characterized the dye by 1H NMR and EI-MS.

二、以对硝基苯甲醛和八羟基久洛尼定为原料，合成了一种新型的罗丹明荧光染料，并通过核磁共振、质谱等手段对染料结构进行了表征。

At present, production and processing of amygdalin in China domestic market is limited to a single product, and discarded other products. In particular, amygdalin is discarded as toxic substances. This is not only wasted the resources but also caused environmental pollution.

目前，我国市场对苦杏仁产品的生产加工仅限于单一产品的开发，而丢弃了其他副产品，尤其是将苯甲醛的前体物质苦杏仁甙作为有毒物质丢弃，不仅造成了资源的大量浪费也使环境受到污染。

Bitter almond contains amygdalin and almond oil, amygdalin can be decomposed to benzaldehyde under acidic condition, benzaldehyde is one of the most widely used flavor in fragrance industry. Almond oil contains high contents of unsaturated fatty acids and VE, it is an advanced edible oil, also can be used in cosmetics materials.

苦杏仁含有2-4%的苦杏仁甙，苦杏仁甙在酶或酸的作用下水解后产生具有强烈的杏仁香气的苯甲醛—即苦杏仁精油的主要成分；另外，苦杏仁含有约50%左右的脂肪油，苦杏仁脂肪油含有大量不饱和脂肪酸以及VE，可直接作为高级食用油或高级化妆品的原料。

With Ti(30)/W(400)-HMS as catalyst, at n:n=1:2,ω=4%, and the reaction time 5 h, the conversion of benzyl alcohol and the selectivity of benzyl aldehyde reached to 72.6% and 96.9%, respectively.

利用Ti(30)/W(400)-HMS为催化剂，当n：n(H2O2)=1：2、ω=4%、反应时间为5 h时，苯甲醇的转化率和苯甲醛的选择性分别为72.6%、96.9%。

They are 2,7-dihydroxy-1,5,6-trimethoxy-9,10-phenanthrene,p-hydroxy phenyl aldehyde, 4-Hydroxybenzyl alcohol, Protocatechuic aldehyde, Gastrodin, 4,4'-Dihydroxydiphenylmethane,4-(4-(hydroxym-ethyl)phenoxymethylphenol,Isorhamnetin-3-O-glucoside,Isorhamnetin-3,7-di-O–glucoside, Imbricatin,2,3-dihydroxy-7-methoxy-9,10-dihydrophenanthropyrone, Cyclopholidone,Cyclopholidonol and β-daucosterol.

分别为：2，7-二羟基-1，5，6-三甲氧基-9，10-二氢菲，对羟基苯甲醛、天麻苷元、原儿茶醛、天麻素、4-（4-羟基-苄基）苯酚、4(4-苯氧基甲基苯酚、异鼠李素-3-O-葡萄糖苷、异鼠李素-3-O-7-O-二葡萄糖苷、Imbricatin、2，7-二羟基-3-甲氧基-9，10-二氢菲吡喃酮、Cyclopholidone、Cyclopholidonol和β-胡萝卜苷。

A series of 3,5-disubstituted chiral hydantoins were prepared from D-amino acid and phenyl isocyanate in mixed solvent, and the catalyst was then supported on macroporous adsorption resins.

摘 要：以混合溶剂法由D 氨基酸和异氰酸酯制备一系列3，5 二取代手性海因，用大孔吸附树脂作载体，制成固载型手性催化剂，并考察了不同结构手性海因化合物在3 苯氧基苯甲醛氰醇化反应中的催化活性。

5 G Benzaldehyde was added dropwise at 0 °C to a Grignard reagent from 4 g Mg and 20.6 g 2 Bromopropane, and the mixture stirred 0.5 h at room temperature, yield, 20.5 g isopropylphenylcarbinol.

在 0°C时，将 1 6.5g苯甲醛滴加到由 4g Mg和 2 0 。6g2 -溴丙烷制得的 Grignard试剂中，在室温下搅拌 0 。5h，得到 2 0 。5g异丙基苯甲醇。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。