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苯甲醛

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Methods This title compound was prepared using the O-phenylene diamine and the anisaldehyde as the raw material,methanol as the solvent,and the phosphoric acid makes the oxidant.

方法本课题以邻苯二胺和对甲氧基苯甲醛为原料,在甲醇为溶剂,磷酸为催化剂的酸性条件下,一步反应制得2-(4-甲氧基苯基)苯并咪唑。

The results showed that the main product was benzaldehyde and a little by-products were styrene oxide and phenylacetaldehyde.

发现该工艺中主要生成苯甲醛,少量副产物是环氧苯乙烷和苯乙醛等。

When the molar ratio of H2O2 to benzyl alcohol was 0.9, the conversion of benzyl alcohol was 86.2%, the selectiv-ity of benzaldehyde was not less than 99%.

当H2O2与苯甲醇的物质的量比为0.9时,苯甲醇的转化率为86.2%,苯甲醛的选择性≥99%。

Six novel dihydrobenzofuran and benzofuran neolignans compounds(1~6) were synthesized by knoevenagel reactiton,esterfication, biomimetic oxidative coupling ,DDQ dehydrogenation,reduction and hydrolysis with 4-hydroxybenzaldehyde and malonic acid as starting material.

以对羟基苯甲醛和丙二酸为原料,经Knoevenagel缩合反应,酯化、仿生氧化偶联、DDQ脱氢、还原和水解等反应步骤,合成了6种未见文献报道的苯并二氢呋喃新木脂素和苯并呋喃新木脂素类化合物(1~6)。

Their structures were characterized as dihydroconiferyl dihydro-p-coumarate, vanillin, apocynin, p-hydroxybenzaldehyde, syringaldehyde, syringic acid, syringylethanone,α-hydroxypropiosyringone, coniferyl aldehyde, dihydroconiferyl alcohol, 2-hydroxyphenylpropanol, and 3-hydroxy-4-methoxy-phenylethanol, respectively.

结果 从该植物中分离得到12个酚性化合物,其结构分别为二氢松柏醇二氢对羟基桂皮酸酯,香草醛,罗布麻宁,对羟基苯甲醛,丁香醛,丁香酸,丁香乙酮,α-羟基丁香丙酮,松柏醛,二氢松柏醇,2-羟基苯丙醇和3-羟基-4-甲氧基苯乙醇。

The acetalization and ketalization of various aldehydes and ketones with catechol by using HY zeolite as catalyst were studied.

研究了 HY分子筛催化邻苯二酚与环己酮、丁酮、丙酮、丙醛、丁醛、异丁醛、戊醛、异戊醛、正己醛、正辛醛、苯甲醛、二苯甲酮等十余种醛的缩合反应。

Two novel soluble poly, poly [(3-butyrylpyrrole-2, 5-diyl) p-nitrobenzylidene] and poly [(3-butyrylpyrrole-2, 5-diyl)(3-hydroxy-4-methoxy) benzylidene], were synthesized firstly by condensation of 3-butyrylpyrrole with p-nitrobenzaldehyde and vanillin, respectively.

通过3-丁酰基吡咯单体分别与对硝基苯甲醛和香草醛的缩聚反应,成功合成了两种新型可溶性聚吡咯甲烯衍生物-策[(3-丁酰基吡咯-2,5-二)对硝基苯甲烯]和聚[(3-丁酰基吡咯-2,5-二)(3-羟基-4-甲氧基)苯甲烯]。

1 Mol % dibenzoyl peroxide as catalyst and CCl_4 as solvent to give α-chloro-4-fluoro-3-phenoxybenzaldehyde and α,α-dichloro-4-fluoro-3-phenoxybenzaldehyde.

研究和优化了以4-氟-3-苯氧基甲苯为起始原料,经氯化反应,氧化反应合成对氟间苯氧基苯甲醛的方法。

The selectivity of phenylacetaldehyde is increased when Br〓nsted acidity is getting stronger. The selectivity of benzaldehyde can be increased by increasing the amount of extraframework titanium species.

分子筛的B酸中心强度对产物分布有着显著的影响,B酸越强,苯乙醛的选择性越高,B酸位是催化环氧苯乙烷定向重排生成苯乙醛的催化活性中心;非骨架钛物种的增加有利于苯甲醛的生成。

The volatile components were separated and identified using GC-MS technique. RESULTS Seven ingredients were. isolated: 2-ethyl-hexyl-adipate (66.5%), 1-methoxy-4-(1-propenyl)benzene (12.5%), isopropyl isothiocyanate (6%), isobutylisothiocyanate (6%), 6-methyl-5-heptene-2-one (3.5%), benzaldehyde (1.4%), phenylacetaldehyde (0.8%).

结果 分离出7个成分,采用峰面积归一化法确定了各成分的相对含量,分别为66.5%双-2-乙基己基-己二酸、12.5%1-甲氧基-4-(1-丙烯基)苯、6%异硫氰酸异丙酯6%、6%异硫氰酸异丁酯、3.5%6-甲基-5-庚烯-2-酮、1.4%苯甲醛、0.8%苯乙醛。

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