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苯甲醛

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The wastewater from gum benzion production contains benzaldehyde, cyanide, gum benzoin and ethyl benzoate. When the cyanide is determined by isonicotinic acidpyrazalon method, the ethyl benzoate is distilled and goes into NaOH absorption liquid with cyanide in the process of predistillation, because its boiling point is low. Thus the absorption liquid produces a great deal of foam and feculence.

摘要]有机化工产品安息香生产废水中含有苯甲醛、氰化物、安息香和苯甲酸乙酯,在用异烟酸吡唑啉酮法对其进行氰化物测定时,由于油酯类的沸点较低,在预蒸馏过程中被蒸出和氰化物一起进入NaOH吸收液,使得吸收液产生大量泡沫和沉淀,严重干扰后续比色测定。

Methods Using cell suspension cultures of Datura stramonium to convert the exogenous p-hydroxybenzaldehyde into gastrodin was conducted and the converted compounds were separated with a combination of multi-chromatography.

方法利用白花曼陀罗细胞悬浮培养转化外源对羟基苯甲醛合成天麻素,并应用多种色谱技术进行分离纯化,根据转化产物的理化性质和光谱数据分析鉴定结构。

To better understand the principles of enzymatic unhairing, changes of contents of protein, hydro-proline and glucose in depilatory liquors were determined in Lowery method, DMBA method and Sulfuric Acid-Anthrone method, respectively, during bath dehairing procedure of 2709 proteinase and A.

为更好地理解酶脱毛的机理,本文用Lowery法、对二甲胺基苯甲醛法和硫酸-蒽酮法分别测定了2709酶和A.S1398酶有温有浴酶脱毛过程溶液中的总蛋白、羟脯氨酸及糖含量的变化。

The "no-fly pollution, clean health", including the human body needs calcium, phosphorus, iron, carotene, ammonium acid, niacin, ascorbic acid and various vitamins, has a high nutritional value, which in the human body VB17 can degrade to form benzaldehyde, and then into a acid and ammonium hydride, can inhibit cancer cells die and break, with a clear role in anti-cancer Cancer

该产品"无蚊蝇污染,干净卫生",含人体需要的钙、磷、铁、胡萝卜素、硫铵酸、尼克酸、抗坏血酸及多种维生素,有很高的营养价值,其中VB17在人体内可降解成苯甲醛,进而转化成铵得酸和氢化物,能抑制和休死癌细胞,有明显的防癌治癌作用

Discusses the technology with double caldrons in series in the chloration process of the technology of producing O chlorobenzaldehyde.

介绍了在邻氯苯甲醛合成中,采用的双釜串联氯化技术,改善了反应条件、提高了氯气利用率、降低了消耗、解决了环境污染问题。

A novel method to prepare polyrotaxane in solution by α-cyclodextrins and dumbbell-like poly derivative with reversible acylhydrazone bond and big end stopper (2',4-dinitrophenyl) is described.

合成了具有可逆酰腙键的2,4-二硝基苯甲醛封端的哑铃型聚乙二醇衍生物。

A better understanding of the role of PPAR in insulin action system will be critical in developing more efficacious and safe agent s that act on PPAR and benefit patients with type 2 diabetes. The main content is followed: Synthesis and analysis of 1,3-dicarbonyl compounds. Make use of easily available cheap reagent such as 2-naphthol, 6-hydroxyquinoline, 1,2-dibromoethane, 4- hydroxybenzaldehyde, dimethyl malonate, 2-{4- [(2-napthoxy)ethoxyl] benzyl} malonates and 2-{4 [(1,2,3,4-tetrahydro-6 -quinolinoxy)ethoxyl] benzyl } malonates were synthesized through 6-8 steps in virtue of Williamson, Knoevenagel reaction, Pd/C catalyzed hydrogenation with mild conditions and high yield. The total yield of 40-50%.

本论文的主要内容和研究结果如下: 1,3-二羰基类化合物的合成及分析,采用2-萘酚、6-羟基喹啉、1 ,2二溴乙烷、对羟基苯甲醛、丙二酸二甲酯等常见易得试剂,利用Williamson反应、Knoevenagel反应、钯碳加氢等条件温和且收率高的方法,分别合成了2-{4- [(2-萘氧)乙氧基]苄基}丙二酸衍生物和2-{4 [(1,2,3,4-四氢-6-喹啉氧基)乙氧基]苄基}丙二酸衍生物两个系列8个化合物,经6-8步反应,总收率为40-50%,具有一定绿色化学特性。

The invention uses benzene carbonic acid as raw material, uses hydrogen gas as reducing agent, and uses ZnO and CeO2 as main accelerating agent. In solid-bed reactor the invention carries out hydrogenation reduction reaction. The reaction temperature is 340-440Deg.C, gas hourly space velocity is 600-4800h-1, hydracid mole rate is 20:1-160:1, the selectivity ratio of benzaldehyde is 99%, and the productivity is above 95%.

该方法以苯甲酸为反应原料,以氢气为还原剂,以ZnO和CeO 2 的复合氧化物为主催化剂,在固定床反应器中,进行气相加氢还原反应,反应温度为340℃~440℃,气时空速为600h -1 ~4800h -1 ,氢酸摩尔比为20∶1~160∶1,采用本发明制备苯甲醛的选择性可达99%,收率可达95%以上。

The invention uses benzene carbonic acid as raw material, uses hydrogen gas as reducing agent, and uses ZrO2, TiO2 and Y2O3 as main accelerating agent. In solid-bed reactor the invention carries out hydrogenation reduction reaction. The reaction temperature is 340-450Deg.C, gas hourly space velocity is 600-4800h-1, hydracid mole rate is 20:1-160:1, the selectivity ratio of benzaldehyde is 96%, and the productivity is above 90%.

该方法以苯甲酸为反应原料,以氢气为还原剂,以复合氧化物ZrO 2 、TiO 2 和Y 2 O 3 为主催化剂,在固定床反应器中,进行气相加氢还原反应,反应温度为340℃~450℃,气时空速为600h -1 ~4800h -1 ,氢酸摩尔比为20∶1~160∶1,采用本发明制备苯甲醛的选择性可达96%以上,收率可达90%。

Benzaldehyde nitrogen mustard isonicotinoyl hydrazone was synthesized according to literature method. The copper , cobalt , nickel , chromium , iron , zinc and cadmium complexes of it were prepared and characterized by elemental analysis, IR, UV-vis, NMR and EPR spectra. The cytotoxicity effect of the complexes was examined on SMMC-7721 cell line. Results show that the complexes have definite antitumor activity and the synergic effect between chromium and the ligand.

依照文献合成了异烟肼苯甲醛氮芥腙及其铜、钴、铬、镍、铁、锌和镉配合物并用元素分析、红外、电子光谱、核磁共振及电子顺磁共振光谱,对这些配合物进行表征,确认了它们可能的立体结构,并研究它们对SMMC-7721人肝癌细胞的作用,结果表明它们均有一定的抗肿瘤作用,发现铬与配体存在有协同作用。

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