苯甲醛

Firstly, the reactivity of benzaldehyde is studied utilizing the autoclave designed by us in near-critical water.

通过对苯甲醛在近临界水中反应后产物的分析检测认为，苯甲醛在有限的温度范围内微量的发生了Cannizzaro反应，并同时伴随有苯甲醛自身的羟醛缩合反应等其他副反应的发生。

My company can provide pesticide, medicine, veterinary medicine intermediates, have 48 kinds of products (p-Bromo-p-Bromotoluene bromoform 1 - bromo-heptane Triethyl Citrate 1,2,3 - three Bromopropane 3 - Chlorine -4 - fluoro bromobenzene Bromotoluene ethylbenzene 4 - bromo -2 - bromo-ethyl-Chloroaniline 2 - bromo--5 - chloro-toluene 3 - bromo-C methyl 1,6 - dibromo-hexane 1 - bromo --4 - p-methoxy benzaldehyde o-bromo-acetic acid propyl bromide p-fluorotoluene dodecane four bromoethane of iodine bromide toluene tert-butane Tributyl Citrate 2 - bromo-p inter - Hydroxybenzaldehyde bromine butane 2 - bromo-propionic acid bromide veratryl aldehyde inter-bromo-trifluoro-n-hexane of toluene on Bromoxynil Bromotoluene toluene ethylbenzene o-bromophenol bromide Cyclohexane Cyclopentane bran bromate bromide Malay Dibutyl Ethyl Lactate Propylene between bromine bromine bromine between aniline o-anisidine o-fluorophenol difluorobenzonitrile to aminobenzaldehyde Bromotoluene aniline on Bromobenzaldehyde Bromotoluene acid) expressed the hope that customers contact us!

我公司可提供农药，医药，兽药中间体，有四十八种产品(对溴苯酚对溴甲苯溴仿 1-溴庚烷柠檬酸三乙酯 1，2，3-三溴丙烷 3-氯-4-氟溴苯对溴乙苯 4-溴-2-氯苯胺溴乙酸乙酯 2-溴-5-氯甲苯 3-溴丙酸甲酯 1，6-二溴己烷 1-溴-4-硝基苯邻甲氧基苯甲醛溴乙酸丙酯对氟甲苯溴代十二烷对碘甲苯四溴乙烷溴代叔丁烷柠檬酸三丁酯 2-溴氯苯间羟基苯甲醛溴丁烷 2-溴丙酸黎芦醛溴已烷间溴三氟甲苯对溴苯腈对溴乙苯邻溴甲苯溴代环已烷溴代环戊烷糠溴酸马来酸二丁酯溴丙烯乳酸乙酯间溴苯胺间溴苯甲醚邻氟苯酚邻氟苯腈对氨基苯甲醛对溴苯胺对溴苯甲醛对溴苯甲酸)希望广大客户与我司联系！

The main products are: HH-01 fungicides HH-02 organic dispersant HH-03 cationic starch Wood HH-04 cationic starch Department HH-05 modified starch warp sizing agents also sell German Baker Chemical Co., Ltd. Main Products Defoamer series product: E640, T50 Surface Sizing Agent: A281, A288, K532, pesticides / medicine / veterinary medicine a variety of intermediate products (p-Bromo-p-Bromotoluene bromoform 1 - bromo-heptane triethyl citrate 1,2, 3 - Three Bromopropane 3 - chloro -4 - fluoro bromobenzene Bromotoluene ethylbenzene 4 - bromo -2 - bromo-ethyl-Chloroaniline 2 - bromo--5 - chloro-toluene 3 - bromo-methyl 1,6 C - Dibromo Hexane 1 - bromo -4 - nitrobenzene o-methoxy benzaldehyde acid propyl bromide p-fluorotoluene bromo dodecane toluene four of iodine bromide bromoethane three citric acid tert-butane n-butyl 2 - bromo-p-bromo-butane Hydroxybenzaldehyde between 2 - bromo-propionic acid bromide veratryl aldehyde inter-bromo-trifluoro-n-hexane of toluene on Bromoxynil Bromotoluene toluene ethylbenzene o-bromophenol bromide bromide Cyclohexane Cyclopentane bran acid dibutyl maleate Ethyl Lactate Propylene between bromine bromine bromine between aniline o-anisidine o-fluorophenol difluorobenzonitrile to aminobenzaldehyde Bromotoluene aniline on Bromobenzaldehyde Bromotoluene acid) and other relevant units have been in substantial promotion, and client set up a good relationship of cooperation has been the user's praise.

现主要产品：HH—01杀菌剂 HH—02有机分散剂HH—03阳离子淀粉 HH—04木署阳离子淀粉 HH—05 经纱上浆变性淀粉同时还代理销售德国贝克化学公司系列产品主要产品消泡剂：E640 、T50 表面施胶剂：A281、A288 、K532，农药/医药/兽药中间体多种产品(对溴苯酚对溴甲苯溴仿 1-溴庚烷柠檬酸三乙酯 1，2，3-三溴丙烷 3-氯-4-氟溴苯对溴乙苯 4-溴-2-氯苯胺溴乙酸乙酯 2-溴-5-氯甲苯 3-溴丙酸甲酯 1，6-二溴己烷 1-溴-4-硝基苯邻甲氧基苯甲醛溴乙酸丙酯对氟甲苯溴代十二烷对碘甲苯四溴乙烷溴代叔丁烷柠檬酸三丁酯 2-溴氯苯间羟基苯甲醛溴丁烷 2-溴丙酸黎芦醛溴已烷间溴三氟甲苯对溴苯腈对溴乙苯邻溴甲苯溴代环已烷溴代环戊烷糠溴酸马来酸二丁酯溴丙烯乳酸乙酯间溴苯胺间溴苯甲醚邻氟苯酚邻氟苯腈对氨基苯甲醛对溴苯胺对溴苯甲醛对溴苯甲酸)等在相关单位得到了大量推广，与客户建立了良好的合作关系，得到了用户的赞誉。

Kinds of Schiff base derivatives of 2-N-benzylidene Furanmethanamine have been designed. The Net Charges of main atoms, bond lengths, bond angles, dihedral angles, IR have been calculated by means of HyperChem6. 0 program. 36 kinds of Schiff base derivatives of benzylidene adenine have been designed. Also the net charges of main atoms, bond lengths, bond angles, dihedral angles, IR, the energy gap △E between HOMO and LUMO and the nonlinear second-order polarizability β have been calculated by means of HyperChem6. 0 program. The calculated results indicated that the nonlinear second-order polarizability β were up in accordance with the △E down.

设计了腺嘌呤缩苯甲醛36种衍生物，计算了这些分子的气相几何，腺嘌呤缩苯甲醛中各原子的电荷分布，最高占有轨道HOMO和最低未占有轨道LUMO的能量以及它们之间的能量差△E，同时还计算了这些分子的二阶非线性极化率β，我们发现腺嘌呤缩苯甲醛的二阶非线性光学系数与△E有近似一致的变化关系，随着△E的减小，二阶非线性光学系数有增大的趋势。

A HPLC method has been developed for the simultaneous determination of 4-methylbenzy- lalcohol,p-tolualdehyde,4-caboxybenzaldehyde,benzoic acid,p-toluie acid,terephthalic acid,o- phthalic acid and isophthalic acid in the residue from purification of terephthalic acid.

其残渣中含有再利用价值很高的中间产物：4一甲基苯甲醇(4一MBA)，对甲基苯甲醛(P一tolual-dehyde)，4一竣基苯甲醛(4一CBA)，苯甲酸，对甲基苯甲酸，对苯二甲酸，邻苯二甲酸，间苯二甲酸等。

Tetra-O-benzyl-D-glucose reacted with bromine to give glucosylbromide. It reacted with hydroxyl phenyl acetonitrile or hydroxyl benzaldehyde to give substituted ph- enylacetonitrile or substituted benzaldehyde.11 New stilbenes were synthesized possessing 2,3,4,6-tetra-O-benzyl-D-glucoside by condensation reaction with pheny lacetonitrile or benzaldehyde, which had potential biological activity and would be sieved in the future.

由2，3，4，6-四芐氧基葡萄糖作为中间体，首先制备出的溴代糖和含有羟基的苯甲醛和苯乙反应制备出含有糖的取代苯甲醛和取代苯乙，再和简单的苯乙或苯甲醛缩合反应生成11种具有潜在的生物活性且含有2，3，4，6-四芐氧基葡萄糖的类化合物，这些新化合物有待于进一步进行药理活性筛选。

By using isopropyl benzene as the internal standard material, using Agilent 1100 HPLC, using methanol-acetonitrile-water as mobile phase ,using three-component grade elution program, the components that contain benzene such as TALD,PT,4-CBA,TA,BA,PX and internal standard material isopropyl benzene in liquid phase product was analysed. Shimazu6A GC was used to analyse the solvent acetic acid and internal standard material isopropyl benzne in liquid phase.

以异丙苯为内标物，应用Agilent1100高效液相色谱仪，用甲醇－乙腈－水为流动相，采用三元梯度洗脱程序分析液相产物中的含苯环组分对甲基苯甲醛、对甲基苯甲酸、对羧基苯甲醛、对苯二甲酸、苯甲酸、对二甲苯和内标物异丙苯，应用Shimazu6A气相色谱仪分析液相中的溶剂醋酸和内标物异丙苯。

The effects of solution\'s pH value, mol ratio between phenyl aldehyde and L-Arginine, concentrations of sodium chloride, ammonia chloride andL-Lystine, initial concentration of L-Arginine on precipitation rate of a -tolylene arginine were investigated, the results indicated that phenyl aldehyde precipitation method\'s appropriate pH value was higher than 11, suitable mol ratio between phenyl aldehyde and L-Arginine was 1.25, initial concentration of L-Arginine was must higher than 15g/L, sodium chloride had little effect on precipitation rate, on the contrary, ammonia chloride and L-Lystine had great effect on it, both of them must be eliminated; At the same time, adsorption isotherm at 25 C of L-Lystine on anion exchange resin A was measured, the result showed that the maximal equilibrium adsorbance was 30mg/g, the influences of solution\'s pH value, temperature, concentration of chloride ion on adsorption of L-Lystine by anion exchange resin A were also studied, the results indicated that appropriate operational pH value was 0.5 0.2, the effect of temperature on adsorption ratio was little, process could be operated at room temperature, the concentration of chloride ion must be eliminated.

考察了溶液pH值、苯甲醛与L-精氨酸摩尔比、氯化钠与氯化铵浓度、L-赖氨酸浓度、L-精氨酸初始浓度对苯甲醛沉淀L-精氨酸的影响，结果表明，沉淀反应的适宜pH值大于11，苯甲醛与L-精氨酸的适宜摩尔比为1.25，(来源：Aa6BC论文网www.abclunwen.com)L-精氨酸适宜的初始浓度在15g/L以上，氯化钠的存在对沉淀率基本上没有影响，而氯化铵和L-赖氨酸的存在使沉淀率下降；同时测定了25℃时阴离子交换树脂A吸附L-赖氨酸的吸附等温线，表明其最大平衡吸附量为30mg/g，考察了溶液pH值、温度、氯离子浓度对阴离子交换树脂A吸附脱除L-赖氨酸的影响，结果显示从L-精氨酸和L-赖氨酸混合液中吸附分离出L-赖氨酸的适宜pH值为10.5±0.2，温度对L-赖氨酸吸附率影响不大，吸附过程可在室温下进行，氯离子的存在使L-赖氨酸的吸附率降低。

First, by using p-methoxybenzaldehyde , p-hydroxybenzaldehyde and pyrrole as raw materials, 5-(p-hydroxyphenyl)-10,15,20-tri(p-methoxyphyenyl)porpyrin was prepares under acidity condition and the let reacted with benzoyl chloride, o-nitrobenzoyl chloride, m- nitrobenzoyl chloride and p- nitrobenzoyl chloride respectively under alkalinity condition with DMF as solvent.

以对-甲氧基苯甲醛、对-羟基苯甲醛和吡咯为原料，在酸性条件下合成了5-对羟苯基10，15，20-三对甲氧苯基卟啉，再以该化合物为原料分别与苯甲酰氯、邻-硝基苯甲酰氯、间-硝基苯甲酰氯和对-硝基苯甲酰氯反应，在碱性条件下以DMF为溶剂合成了四种目前尚未见文献报道的对-甲氧基卟啉硝基苯甲酸酯类化合物。

The degree of hydrogenation of methyl benzoate might be controled by adding the promoters and changing the nano-size of ZnO. For hydrogenation of methyl benzoate to benzaldehyde, the active-structure of a catalyst should be modified to decrease the absorption of benzaldehyde on the surface of it, because benzaldehyde absorbed is hydrogenated easily. Using 30-40％ZnO/γ-Al〓O〓 or Li-30％ZnO/γ-Al〓O〓, a higher selectivity to benzaldehyde is obtained. Hydrogenolysis of methyl benzoate to toluene or benzene is carried out effectively using a catalyst modified. For instance, 45.3％ selectivity to benzene and 100％ conversion of methyl benzoate at 420℃ was obtained over 10％ZnO/MCM-41 with the nano-size particles of ZnO (2.4nm).

也可以通过助催化剂的添加和活性组分的纳米化，并根据苯甲酸甲酯多步加氢反应的特点实行加氢深度的调控：苯甲酸甲酯选择性加氢制苯甲醛中，由于苯甲醛容易进一步加氢，需要对活性结构进行调变，以减弱苯甲醛的吸附，使用30-40％ZnO/γ-Al〓O〓催化剂或Li调变的Li-30％ZnO/γ-Al〓O〓催化剂，可获得较高的苯甲酸甲酯加氢制苯甲醛的活性；采用同样的方式，苯甲酸甲酯选择性氢解为甲苯或苯也获得了较好的结果，如使用ZnO纳米化的10％ZnO/MCM-41催化剂，在420℃，可获得45.3％的苯选择性，苯甲酸甲酯完全转化。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。