苯甲醚

In this dissertation, two derivatives of aniline containing polyoxyethylene substituent m-phenylene diamino formyl alkylenediamine poly acetate and poly-3-aminobenzoate were designed and synthesized. And then, comb-shaped polyaniline grafted by PEO were prepared by chemical oxidation copolymerization. The structure of copolymers were characterized by FTIR, ultraviolet-visible spectrum, elemental analysis and TEM etc..

本文在设计并合成两种含聚氧乙烯取代基的苯胺衍生物——间苯二氨基甲酰己二氨基甲酸聚氧乙烯乙酸酯和3-聚氧化乙烯单甲醚基苯胺的基础上，采用化学氧化法将它们与苯胺进行共聚，制备出了聚氧乙烯接枝聚苯胺的梳型共聚物。

Light oil, ferrocene, EPA light hydrocarbon, dimethyl ether, xylene, acetone, hydroquinone, potassium permanganate, petroleum ether, naphtha, thiol, butane, sodium hydroxide , synthesis gas reactor

轻质油，二茂铁，轻烃碳五，二甲醚，二甲苯，丙酮，对苯二酚，高锰酸钾，石油醚，石脑油，硫醇，丁烷，氢氧化钠，合成液化气反应罐

Sixteen compounds were separated from 80% ethanol extract of Plant A, they were:-lariciresinol,-isolariciresinol,-isolariciresinol 9-O-β-D-glucopyranoside, tanegoside B, apiginin, apigenin 7-O-β-D-glucoside, apigenin 7-O-β-neospheroside, quercetin 3-O-β-D-glucopyranoside, 1, 7-dihydroxy-3, 4-dimethoxyxanthone, 3-O- [α-L-rhamnopyranosyl (1-4 ] -β-D-glucopyranoside-(25S)-5β-spirostan-3β-ol , 3β-O-D-glucopyranoside quinovic acid, mangiferin , 3'-p-hydroxybenzoyl-mangiferin, physcion, benzenyl methanol β-D-glucopyranoside and Vanillic acid.

结果： 1。从植物A的80％乙醇提取物中共分离得到16个化合物，分别为：-落叶松脂醇、-异落叶松脂醇、异落叶松脂醇9-O-β-D-吡喃葡萄糖苷、tanegoside B、芹菜素、芹菜素7-O-β-葡萄糖苷、芹菜素7-O-β-新橙皮糖苷、槲皮素3-O-β-D-吡喃葡萄糖苷、1，7-二羟基-3，4-二甲氧基-口山酮、菝葜皂苷元-3-O-[α-L-吡喃鼠李糖基（1-4）]-β-D-吡喃葡萄糖苷、喹诺酸3β-O-D-葡萄糖苷、知母宁、3′-对羟基苯甲酸-知母宁、大黄素甲醚、苯甲醇-β-D-吡喃葡萄糖苷、香草酸。

The main products are: phosphorous trichloride 300,000 tons / year, phosphorus oxychloride 100,000 tons / year, phosphorus pentachloride 50,000 tons / year, 10,000 tons trichloroisocyanuric parathion / year chloromethyl ether 5000 tons / year, triethyl phosphite 10,000 tons / year, triphenyl phosphite 5000 tons / year, three phosphoric acid ethyl butoxy 2000 tons / year.

主要产品有：三氯化磷30万吨/年、三氯氧磷10万吨/年、五氯化磷5万吨/年、三氯硫磷1万吨/年、氯甲基甲醚5000吨/年、磷酸三乙酯10000吨/年、磷酸三苯酯5000吨/年、磷酸三丁氧基乙酯2000吨/年。

Then,the core molecule was used as a coupling agent to condensate with polyethylene glycolsof different molecular weight or polyethylene glycol monomethyl etherin the presence of stannous octoate as catalyst and diphenyl ether as azeotropic agent to remove water.

在辛酸亚锡催化下，以二苯醚为共沸脱水剂，将三官能度小分子TMP-SK3作为偶联剂，进一步与不同分子量的端羟基聚乙二醇和聚乙二醇单甲醚缩合，减压下共沸脱水，制备了以TMP-SK3为核，PEG或PEGm为臂的三臂星形大分子。

These compounds were identified as follows:chrysophanol (FP-1),physcion(FP-2),eriosematin(FP-3),scoparone(FP-4),lupeol(FP-5),betulinic acid(FP-6),3\',4\'-Dihydroxy-trans-cinamic acid octacosyl ester(FP-7),β-sitosterol (FP-8),flemiphilippinone A(FP-9),monopalmitin(FP-10),emodin(FP-11),islandicin (FP-12),salicylic acid(FP-13),p-methoxyphenylpropionic acid(FP-14),trideca-1, 3-diene(FP-15),lupinifolin(FP-16),flemichin D(FP-17),flemiphilippinin A(FP-18), auriculasin(FP-19),erythrinin B(FP-20),6-C-prenylluteolin(FP-21), 8-(1,1-dimethylallyl) genistein(FP-22),flemiphilippinin E(FP-23),flemiphilippinin F (FP-24),5,7,3\',4\'-tetrahydroxy-6,8-diprenylisoflavone(FP-25),flemiphilippinin D (FP-26),dorsmaninsⅠ(FP-27),osajin(FP-28),6,8-diprenyleriodictyol(FP-29), lupinalbin A(FP-30),genistein(FP-31),3\'-O-methylorobol(FP-32),orobol(FP-33), 5,7,2\',3\',4\'-pentahrdroxyflavone(FP-34),the mixture of biochanin A and prunetin (FP-35 and 36),genistin(FP-37),sophororicoside(FP-38),3\'-O-methylorobol-7-glucoside(FP-39),the mixture of sissotrin and prunetin 4\'-O-β-D-glucoside(FP-40 and 41),adenosine(FP-42) and luteoloside(FP-43,mixture).

这些化合物分别为大黄酚(FP-1)、大黄素甲醚(FP-2)、eriosematin(FP-3)、滨蒿内酯(FP-4)、羽扇豆醇(FP-5)、白桦酸(FP-6)、咖啡酸二十八烷酯(FP-7)、β-谷甾醇(FP-8)、蔓性千斤拔酮A(FP-9)、单棕榈酸甘油酯(FP-10)、大黄素(FP-11)、islandicin(FP-12)、水杨酸(FP-13)、对甲氧基苯丙酸(FP-14)、十三烷-1，4-二烯烃(FP-15)、lupinifolin(FP-16)、千斤拔素D(FP-17)、蔓性千斤拔素A(FP-18)、auriculasin(FP-19)、erythrinin B(FP-20)、6-C-异戊烯基木犀草素(FP-21)、8-(1，1-二甲烯丙基)-染料木黄酮(FP-22)、蔓性千斤拔素E(FP-23)、蔓性千斤拔素F(FP-24)、5，7，3′，4′-四羟基-6，8-双异戊烯基异黄酮(FP-25)、蔓性千斤拔素D(FP-26)、dorsmaninsⅠ(FP-27)、osajin(FP-28)、6，8-双异戊烯基圣草素(FP-29)、lupinalbin A(FP-30)、染料木黄酮(FP-31)、3\'-O-甲基香豌豆苷元(FP-32)、奥洛醇(FP-33)、5，7，2′，3′，4′-五羟基黄酮(FP-34)、鹰嘴豆素甲和樱黄素的混合物(FP-35和FP-36)、染料木苷(FP-37)、槐属苷(FP-38)、7-葡萄糖基-3\'-O-甲基香豌豆苷(FP-39)、印度黄檀苷和樱黄素4′-O-β-D-葡萄糖苷的混合物(FP-40和FP-41)、腺嘌呤核苷(FP-42)和木犀草苷(FP-43，混合物)。

The novel reaction to create 6,7-dimethoxy-1-(3,4-dimethoxyphenyl)-4-hydroxy-naphthalene 83 in one-pot procedure was found during the synthesis of diphyllin, which started from catechol dimethylether and succinic anhydride and involved heating the molten mixture of the two reactants in the presence of polyphosphoric acid at 140℃.

这个反应是用邻苯二酚二甲醚和丁二酸酐为原料，把两个原料的混合物熔融后，加入PPA，在140℃下搅拌后就会有产物生成。

Chloroacetic acid,chloromethyl ether,acetone,mphenylenediamine,butyl acetate,ethyl acetate,methylene chloride,ethylene dichloride,dioxane.

氯乙酸，氯甲醚，丙酮，间苯二胺，醋酸丁酯，醋酸乙酯，二氯甲烷，二氯乙烷，二氧六环。

The synthesization technics of MPEG- MAA was studied in this paper,which is an important intermediate used for preparation of polycarboxylate superplasticizer.

本文对制备聚羧酸系减水剂的重要中间体——甲基丙烯酸聚乙二醇单甲醚酯的合成工艺进行了研究，考察了反应时间、催化剂对甲苯磺酸的用量、阻聚剂对苯二酚的用量、反应温度及甲基丙烯酸与聚乙二醇单甲醚的用量比对酯化率的影响。

Light oil 2,000 yuan / ton; ferrocene 20000 yuan / ton; DME 2,500 yuan / ton; Light EPA [density 0.60-0.63] 2,000 yuan / ton; sodium bicarbonate 2600 yuan / ton; Mercaptans 3,000 / ton; xylene 3,500 yuan / ton; potassium permanganate 5,000 yuan / ton; petroleum ether 3,000 yuan / ton; naphtha 2900 yuan / ton; butane 2,000 yuan / ton; acetone 4400 yuan / t; hydroquinone 15,000 yuan / ton.

轻质油2000元/吨；二茂铁20000元/吨；二甲醚2500元/吨；轻烃碳五[密度0.60-0.63]2000元/吨；碳酸氢钠2600元/吨；硫醇3000元/吨；二甲苯3500元/吨；高锰酸钾5000元/吨；石油醚3000元/吨；石脑油2900元/吨；丁烷2000元/吨；丙酮4400元/吨；对苯二酚15000元/吨。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。