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苯甲醇

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The results showed that (1) The grain size of nanometer YiO_2 was40~80nm.The wavelength corresponding to the maximum absorbency values were observedin the 200~320nm range.The crystal structure of carbon doped TiO_2 photocatalyst is primarilyanatase(22.43% rutile), and the content of carbon is about 4.6%.(2) The relative humidityvaring from 8% to 80%, the photocatalytic degradation degree of benzene increased withincreasing relative humidity; and to toluene, degradation rate was hanced by relative humidityup to 60%, and more or less inhibited above 60%.(3) Scheme and results of orthogonal testswere used by evaluating the photocatalytic performance of the gas phase methanol, acetoneand 1-heptane.The results revealed that their degradation degree reached 84.5%, 93.39% and93.45%, respectively.(4) The 254nm UV lamp showed higher photocatalytic degradation rate.For methanol, acetone and 1-heptane, it was found that photocatalytic degradation reactionoccurs with the light strength of daylight lamp.(5) Under the the same conditions, 15%degradation degree has been obtained for benzene, whilst about 10% degradation degree wasattained by Degussa P25; During the initial phases, the toluene revealed higher photocatalyticactivity, comparing with Degussa P25, the degradation degree of methanol, acetone and1-heptane were slightly lower.

结果表明:(1)CVD法制备的纳米TiO_2光催化剂,颗粒球形度好、粒径在40~80nm之间;最大吸光度值所对应的波长为200~320nm;含碳量约为4.6%;晶型组成主要为锐钛矿型,金红石的含量约为22.43%;(2)在相对湿度为8%~80%范围内,苯的光催化降解率随着相对湿度的增大而增大;甲苯在相对湿度为60%时达到最好降解效果,当相对湿度增大到80%时光催化效果降低;(3)将正交实验设计及实验方案应用于气相甲醇、丙酮和正庚烷光催化降解研究,实验结果表明:三者最高降解率分别为84.5%、93.39%和93.45%;(4)有254nm紫外灯参与的光催化实验可以大大提高有机气体的光催化降解率;在日光灯的照射下,掺碳纳米TiO_2对气相甲醇、丙酮和正庚烷具有一定的光催化氧化能力;(5)较P25粉,在相同的光催化操作条件下:气相苯的平均降解率达15%,高于P25粉10%的降解率;气相甲苯在初始阶段具有较高的反应速率;气相甲醇、丙酮和正庚烷的降解率略低于P25粉。

The catalytic transformation pathway can change to decrease the yield of hydrogen and yield methyl-contained sulfides such as methyl mercaptan, dimethyl sulfide and dimethyl disulfide, but overlarge concentration of methanol would holdback the transformation of isobutyl mercaptan. The transformation of isobutyl mercaptan was favorable if the volume ratio of methanol and benzene was 0.2.The addition of methanol assume certain effect on the catalytic cracking of di-n-butyl sulfide in solvent benzene but without changing the cracking reaction mechanism of di-n-butyl sulfide.

甲醇也可以使异丁硫醇的催化转化路径发生改变降低硫化氢的产率,生成甲硫醇、甲硫醚及二甲基二硫化物等含甲基硫化物,但甲醇的浓度过高会抑制异丁硫醇的转化,在反应体系中当甲醇的体积占到溶剂苯体积的20%时对异丁硫醇的转化较为有利;甲醇的添加对丁硫醚在溶剂苯中的催化裂化有一定影响,但没有改变丁硫醚的裂解反应历程。

By using isopropyl benzene as the internal standard material, using Agilent 1100 HPLC, using methanol-acetonitrile-water as mobile phase ,using three-component grade elution program, the components that contain benzene such as TALD,PT,4-CBA,TA,BA,PX and internal standard material isopropyl benzene in liquid phase product was analysed. Shimazu6A GC was used to analyse the solvent acetic acid and internal standard material isopropyl benzne in liquid phase.

以异丙苯为内标物,应用Agilent1100高效液相色谱仪,用甲醇-乙腈-水为流动相,采用三元梯度洗脱程序分析液相产物中的含苯环组分对甲基苯甲醛、对甲基苯甲酸、对羧基苯甲醛、对苯二甲酸、苯甲酸、对二甲苯和内标物异丙苯,应用Shimazu6A气相色谱仪分析液相中的溶剂醋酸和内标物异丙苯。

On the sick child to minimize or avoid intramuscular buttocks toxic irritant strong drugs, in particular the use of benzyl alcohol should not be diluted drugs.

对病儿尽量减少或避免对臀部肌肉注射毒性大、刺激性强的药物,尤其是不应使用苯甲醇稀释的药物。

Under the optimal conditions, the conversion of benzyl chloride is nearly 100% during esterification, and the total yield of benzyl alcohol is higher than 98%, the percent of benzyl ether is lower than 2%.

氯化苄在酯化反应中基本反应完全,苯甲醇的两步总选择性可以达到98%以上,二苄醚的含量低于2%。

A novel type of photoalignment material based on the esterification reaction of 3,5-dihydroxyl benzyl alcohol and cinnamoyl chloride was firstly reported in this paper. The distinct property of this material is the nonlinear branch conformation and its polarity end with hydroxyl group.

通过在3,5-二羟基苯甲醇分子中的双酚基基团上引入双肉桂酰酯光敏基团的酯化反应,合成了一类新型的分子顶部为羟基极性基团,整个分子构型类似于树枝状的光敏小分子化合物。

During esterification of benzyl chloride and sodium formate, benzyl formate is esterilysis which is a reversible reaction, and the mole ratio of benzyl formate to benzyl alcohol is 3:7 because of the chemical equilibrium.

在氯化苄与甲酸钠的酯化反应同时存在甲酸苄酯的水解反应,并且甲酸苄酯的水解反应是可逆反应,受化学平衡的限制,在实验条件下的甲酸苄酯与苯甲醇平衡的摩尔比大致为3:7。

Lincomycin Sterile Solution contains benzyl alcohol as a preservative.

林可霉素无菌液含有苯甲醇作为防腐剂。

The invention is characterized in that the carrier is produced through the reaction between halogen acetylized crosslinked polystyrene resin and hydroxybenzyl alcohol.

本发明的特征是:该载体由卤乙酰化聚苯乙烯树脂与对羟基苯甲醇反应制得。

The invention adopts halogen acetylized crosslinked polystyrene resin and hydroxybenzyl alcohol as the raw material, and the solid phase synthesis carrier with hydroxymethyl as the active group is synthesized through the joint catalysis of N, N-dimethyl formamide used as the reaction solvent, inorganic base and phase-transfer catalyst.

本发明采用卤乙酰化交联聚苯乙烯树脂和对羟基苯甲醇为原料,在以N,N-二甲基甲酰胺为反应溶剂、无机碱及相转移催化剂的共同催化下合成了一种以羟甲基为活性基团的固相合成载体。

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Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在,所有的孩子都要在综合学校继续学习,所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地,使人们普遍认识到发展不能以牺牲农业为代价。

Detailed Intrinsic Reaction Coordination calculations were carried out to guarantee the optimized transition-state structures being connected to the related tautomers.

同时,做了详尽的内禀反应坐标计算,以保证所得到的过渡态连接相应的始末异构体。