苯甲酸苄酯

Sodium Benzoate, Amyl Cinnamal, Benzyl Alcohol, Eugenol, Hydroxy Citronellol, Benzyl Salicylate, Geraniol, Linalool, Citronellol, Benzyl Benzoate.

苯甲酸钠，戊Cinnamal ，苯甲醇，丁香酚，羟基香茅醇，水杨酸苄酯，香叶醇，芳樟醇，香茅醇，苯甲酸苄酯。

The synthesis of benzyl benzoate from sodium benzoate and benzyl chloride by phase transfer catalysis process is studied in the article.

由苯甲酸钠和氯化苄通过相转移催化法合成了苯甲酸苄酯，考察了几种季铵盐类相转移催化剂的亲核取代反应性能。

Benzyl benzoate was synthesized using benzoic acid paste residua and benzyl chloride as raw material at the presence of TEA.

以反应代替分离，将膏状的苯甲酸釜残液碱化后和氯化苄反应，采用相转移催化技术合成苯甲酸苄酯来加以应用。

After enriched by flash, benzoic acid-containing fraction was obtained below 210 ℃ and benzyl benzoate -fluorenone-containing fraction was between 220 and 260 ℃,then these fractions were separated by vacuum distillation respectively.

废料通过闪蒸，在210℃以下得到了富集苯甲酸馏分，在220—260℃之间得到了富集苯甲酸苄酯和芴酮馏分；之后对各馏分进行高真空减压精馏，得到了苯甲酸、苯甲酸苄酯和芴酮等产品，纯度分别可达95%，91%和92%。

Results Benzyl cinnamate, benzyl benzoate and borneol were found in vitro of rabbits, 2-hydroxy-methyl benzoate and borneol were found in vivo of rabbits.

结果 体外药物成分含有肉桂酸苄醋、苯甲酸苄酯、冰片等；体内药物成分含有2-羟基苯甲酸甲酯、冰片等。

Glycine Soja Oil, Vitis Vinifera Seed Oil, Pistacia Vera Seed Oil, C 12-15 Alkyl Benzoate, Caprylic/Capric Triglyceride, Prunus Amygdalus Dulcis Oil, Fragrance, Tocopheryl Acetate, Lecithin, Amyl Cinnamal, Benzyl Benzoate, Citronellol, Geraniol, Limonene, Linalool.

野生大豆油，葡萄籽油，阿月浑子种子油和c 12月15日烷基苯甲酸，辛酸/癸甘油三酯，李野枣油，香水， Tocopheryl醋酸酯，卵磷脂，戊Cinnamal ，苯甲酸苄酯，香茅醇，香叶醇，柠檬烯，芳樟醇。

Unflower Oil*, Jojoba Oil*, Macadamia Nut Oil*, Parfum**(Benzyl Salcylate, Geraniol, Benzyl Benzoate, Citronellol, Limonene, Linalool), Glyceryl Caprylate, Polyglyceryl-3 Palmitate, Vitamin E Tocopherol

有机葵花籽油，有机荷荷芭油，有机澳洲坚果油，有机精油香水（水杨酸苄酯，香叶醇，苯甲酸苄酯，香茅醇，柠檬烯，芳樟醇），辛酸甘油酯，聚3硬脂酸钠，维生素E。

Borneol play a role in blood with an original form, benzyl cinnamate and benzyl bcnzoate were metabolized into 2-hydroxy-methyl benzoate to produce marked effect.

冰片以原型药物形式入血产生疗效，肉桂酸苄醋、苯甲酸苄酯被转为2-羟基苯甲酸甲酯的代谢产物发挥作用。

Chemiluminescent immunoassay is one of the advanced immunoassay ofnon-radioisotopic immunoassay because of its high sensitivity, wide dynamic range,high accuracy, stable labeled protein, full automation and extensive application field.CLIA using acridinium ester derivatives as chemiluminescent label has advantages oflow background, high signal-to-noise ratio, no need of catalyst and simpleluminescence system. Different aspects associating the DMAE·NHS-based CLIA were studied in thisthesis, including synthesis of acridinium ester, chemiluminescentcharacteristics of DMAE·NHS, labelling antibody or streptavidin with DMAE·NHS,two-site sandwich chemiluminescent immunoassay for TSH, two-sitesandwich chemiluminescent immunoassay involved biotin-streptavidinsystem for TSH, and competitive chemiluminescent immunoassay usingbiotin-streptavidin system for TT〓. The desired acridinium ester, DMAE·NHS, was synthesized according to thereference method with some modifications. The products were identified by IR, NMR,MS and elemental analysis. In our method, KOH was used in place of NaOH tosynthesize benzyl ester of 3,5-dimethyl-4-hydroxybenzoic acid,2',6'-dimethyl-4'-(n-succinimidyloxycarbonyl) phenyl-acridinium-9-carboxylate waspurified on a silica gel column with chloroform/ethylacetate(4:1, v/v) as eluent andfurther purified by triturating with hexane/acetone(2:1, v/v).

DMAE·NHS的合成是本论文的关键和难点，我们对文献方法进行改进：文献方法用氢氧化钠与3，5-二甲基-4-羟基苯甲酸反应制得3，5-二甲基-4-羟基苯甲酸钠，再用3，5-二甲基-4-羟基苯甲酸钠与苄氯作用制备3，5-二甲基-4-羟基苯甲酸苄酯，我们用氢氧化钾代替氢氧化钠，使合成取得成功；在合成2'，6'-二甲基-4'-苯基-吖啶-9-甲酸酯时，文献方法对粗产品进行两次硅胶柱层析纯化，第一次柱层析用氯仿／乙酸乙酯(4∶1，V∶V)作溶剂和淋洗剂，第二次柱层析用己烷／丙酮(2∶1，V∶V)作溶剂和淋洗剂，按照文献方法得到的不是所需要的化合物，我们只进行第一次柱层析纯化，然后用己烷／丙酮(2∶1，V∶V)进行研磨，过滤，洗涤，除去溶于己烷／丙酮(2∶1，V∶V)的部分，得到所需要的产品。

The products were identified by IR,NMR,MS and elemental analysis. In our method,K.OH was used in place of NaOH to synthesize benzyl ester of 3,5-dimethyl-4-hydroxybenzoic acid,2',6'-dimethyl-4'-(n-succinimidyloxycarbonyl) phenyl-acridinium-9-carboxylate was purified on a silica gel column with chloroform/ethylacetate(4:l,v/v) as eluent and further purified by triturating with hexane/acetone(2:l,v/v).The luminescence produced by DMAE-NHS is a flash light with maximumemission at 0.4s and decay half-time of 0.9s. The luminescence intensity is 6.11x10 cps/mol,which is affected by the composition of trigger and surfactant.

DMAE·NHS的合成是本论文的关键和难点，我们对文献方法进行改进：文献方法用氢氧化钠与3，5-二甲基-4-羟基苯甲酸反应制得3，5-甲基-4-羟基苯甲酸钠，再用3，5-二甲基-4-羟基苯甲酸钠与苄氯作用制备3，5-二甲基-4-羟基苯甲酸苄酯，我们用氢氧化钾代替氢氧化钠，使合成取得成功；在合成2'，6'-二甲基-4'-苯基-吖啶-9-甲酸酯时，文献方法对粗产品进行两次硅胶柱层析纯化，第一次柱层析用氯仿/乙酸乙酯(4：1，Ⅴ：Ⅴ)作溶剂和淋洗剂，第二次柱层析用己烷/丙酮(2：1，Ⅴ：Ⅴ)作溶剂和淋洗剂，按照文献方法得到的不是所需要的化合物，我们只进行第一次柱层析纯化，然后用己烷/丙酮(2：1，Ⅴ：Ⅴ)进行研磨，过滤，洗涤，除去溶于己烷/丙酮(2：1，Ⅴ：Ⅴ)的部分，得到所需要的产品。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。