苯甲酸基

Aminobenzoic acid was used to synthesize 4'-methyl-2-cyanobiphenyl, which was one of medicine intermediates, by diazotization, acylation, substitution, and dehydration.

以邻氨基苯甲酸为起始原料，经重氮化、芳基化、取代和脱水等步骤合成药物中间体4'-甲基－2-腈基联苯。

The article includes three parts. The first, a steroselective and regioselective synthesis of digitoxin with glycosyl ortho-alkynylbenzoates as doners. The second, synthesis of different length chain of L-fucose with a SO3Na group in the position of C-2 hydroxy.

本文工作主要包括三部分内容，分别为采用全新发展的一种邻炔基苯甲酸酯的糖基供体进行地高辛的全合成并与常规的Schimidt供体及三氟亚胺酯供体进行结果比较；合成不同长度的2位硫酸化的岩藻糖糖链；对现有的合成伏格列波糖的一条合成路线进行工艺优化。

Dimethylnitrobenzene was oxidized to 3-methyl-4-nitrobenzoic acid with oxygen in the presence of catalyst under high pressure. The yield of 3-methyl-4-nitrobenzoic acid is 50% under proper condition and is higher than the literature yield of 27%.

论文还研究了在常压和高压下催化氧化2，4-二甲基硝基苯合成3-甲基-4-硝基苯甲酸的工艺，在一定的条件下产率可以达到51.2％。

Under basic conditions p-nitrotoluene was oxidized to p-nitrobenzoic acid with oxygen or air. The reaction parameters, such as reaction temperature, reaction time, substrate concentration were optimized and 75% of p-nitrobenzoic acid was obtained under proper conditions.

论文探讨了在碱性条件下，用空气／氧气氧化对硝基甲苯的反应，得出了温度、时间、底物浓度、催化剂用量等工艺参数对反应的影响，在较佳的工艺条件下，对硝基苯甲酸的收率可达到75％左右。

The optimal reaction conditions were as follows: the molar ratio of propanol to acid was 1:1, the mass ratio of the catalyst used to p-nitrobenzoate was 6%.

合成硝基卡因的最佳工艺条件为：醇酸比为1：1，催化剂的用量为对硝基苯甲酸的6%，在回流温度下反应14h，产率达到79.5%。

Our use Co2 as a catalyst in this work, exploring new way to produce nitrobenzoic acid from nitrotoluene under the prue oxygen in basic medium.

本文探讨了以乙酰丙酮钴为催化剂，分子氧为氧源，在NaOH-CH_3OH的反应环境下，氧化硝基甲苯制备硝基苯甲酸的新方法。

Tetra(4-methoxycarbonylphenyl)porphyrin was synthesized from 4-formacylmethyl benzoate and pyrrol under microwave irradiation.

以4 -甲酰基苯甲酸甲酯和吡咯为原料，微波辐射合成了5， 10， 15， 20 -四(4-甲氧羰基苯基)卟啉。

By using the a device being similar to water segregator and by controlling the temperature, cyclization of the intermediate product in chloroform reduced carbonization and gave 2-dodecaneanthraquinane in 68.1% yielding.

以十二烷基苯和苯酐为起始原料，经酰基化、关环和磺化三步反应合成了3-十二烷基蒽醌磺酸；并进一步改进和优化了合成工艺条件：即在催化剂三氯化铝过量50%并有三乙胺存在的条件下，中间体2-（4-十二烷基苯甲酰基）苯甲酸收率为72.45%；关环反应采用氯仿作溶剂，利用类似分水器的装置有效控制反应温度以减少碳化，2-十二烷基蒽醌的收率为68.1%。

Nitro-4-methylsulfonylbenzoic acid was prepared from 4-toluene sulfonyl chloride by the reaction of Alkylation (in the condition of sodium sulfite and baking soda), Nitrification (in the condition of nitric acid and vitriol) and Oxidation reaction (in the condition of nitric acid and catalyzer).

研究了以对甲苯磺酰氯为起始原料，首先通过亚硫酸钠和碳酸氢钠的水溶液进行烷基化、其次在浓硝酸和浓硫酸加热回流的条件下峭化、最后在浓硝酸和催化剂的条件下进行氧化，3步反应合成了玉米田高效除草剂甲基磺草酮的重要中间体2-硝基－4-甲磺酰基苯甲酸。

In order to improve their water solubility, 4"-fatty amido-3"-sodium carboxylate azobenzene-4-sodium sulfonates were synthesized. They are azo compounds with two hydrophilic groups of carboxyl and sulfonyl. They decrease the surface tension in dilute solution slowly, and show some surfactivity, but are not surfactants. The probable reason is their relative strong hydrophile. Furthermore, their colors are not fresh and far from our destination.

为了改善其水溶性，改用对氨基苯甲酸为原料合成了4′-脂肪酰氨基-3′-羧酸钠偶氮苯-4-磺酸钠盐，以偶氮结构为主的亲水基团上连有羧酸基和磺酸基两个亲水性较强的基团，但可能由于其亲水性太强，在稀溶液中只能缓慢地降低溶液的表面张力，具有一定的表面活性，但不是表面活性剂，而且颜色不鲜艳，距离我们的目标较远。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。