苯甲酰胺

The optimum reaction conditions are as follows: diphenylmethanethiol : methyl chloroacetate is 1:1.5, and the reaction carried out at 100℃ for 4 h, 2- acetamide can be carried out in the room temperature for 20 h, the yield of 2- acetamide was 76%, hydrogen dioxide: 2- acetamide is 1:1, and the reaction carried out at 60℃ for 3 h, the yield of modafinil was 79%, the total yield of reaction can be reached 48%.

研究表明，采用氯乙酸甲酯作为醚化试剂，反应时间4h，反应温度100℃，二苯甲硫醇：氯乙酸甲酯=1：1.5，室温下氨解反应20h，二苯甲硫乙酰胺收率76%；采用过氧化氢作为氧化试剂，反应时间3h，反应温度60℃，过氧化氢：二苯甲硫乙酰胺=1：l，莫达非尼收率79%，反应总收率可达48%。

Development period of the parasitoid pupa from the 5th instar larva fed on MSB was significantly longer. Length of cocoon of MSB treatment was significantly shorter than the control. However, no obvious differences were detected in the development periods of egg to larva, cocoon mass size, wasp emergence rate, sex ratio, longevity and forewing length of wasp between KMD1 and the control. 3. Amino acid content in the haemolymph of SSB after fed with transgenic rice Although there were no changes on the components of amino acids in the haemolymph of SSB after fed with two transgenic rice lines, there were some changes on relative contents of amino acids.

取食KMD1 36h后0天，20种氨基酸中除天门冬酰胺、丝氨酸、苏氨酸和甲硫氨酸外，其它16种氨基酸的含量都高于对照，其中组氨酸、甘氨酸、苯丙氨酸、异亮氨酸、赖氨酸差异达显著水平，谷氨酰胺、脯氨酸差异达极显著水平，与氨基酸总量表现一致的变化趋势；取食KMD1后1天，除天门冬酰胺、谷氨酰胺和赖氨酸高于对照外，其它17种氨基酸均较对照低，但仅丝氨酸、苏氨酸和色氨酸与对照差异显著；取食KMD1后3天，绝大多数氨基酸含量的变化与取食KMD1后0天的趋势一致，除丙氨酸和色氨酸比对照稍低，其它18种氨基酸均高于对照，其中精氨酸、缬氨酸差异显著，丝氨酸差异达极显著。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

The unit can be used to sample most containerized liquid wastes, except those containing ketones, nitrobenzene, dimethylformamide, mesityl oxide, and tetrahydrofuran.

该装置可用于大部分的废品样本采集除含有酮，硝基苯，二甲基甲酰胺，异丙叉丙酮和四氢呋喃的液体废品。

The intermediate which obtained from oximation of 7a-e reacted withmethyl N-(2-bromomethylphenyl)-N-methoxycarbamate to synthesize oxime ether methyl carbamate 3a-e.

以邻位卤代苯甲醛和3-丁烯-2-醇为原料通过钯催化&一锅法&反应合成了2-乙酰基茚7a-e，7a-e 肟化之后和N-(2-溴甲基苯基)-N-甲氧基氨基甲酸甲酯反应合成了肟醚类氨基甲酸甲酯3a-e，进一步胺解之后得到了肟醚类氨基甲酰甲胺3f-j。

Amino-monomethoxypoly(ethy1ene glycol)(mPEG-NH2) was synthesized based on the principle of Gabriel synthesis.Monomethoxypoly(ethy1ene glycol) tosylate was prepared at first,and then reaction with potassium salt of phthalimide as nucleophile to produce the monomethoxypoly(ethy1ene glycol)phthalimide derivative.

摘 要：首先合成了单甲氧基聚乙二醇对甲苯磺酸酯，然后根据盖布瑞尔合成法原理，以邻苯二甲酰亚胺钾盐为亲核试剂与mPEG-OTs反应，生成单甲氧基聚乙二醇的邻苯二甲酰亚胺衍生物，mPEG-PI与水合肼反应肼解生成伯胺，合成了一端为氨基的单甲氧基聚乙二醇(mPEG-NH2)。

Huapai products:pchlorophenol,ochlorophenol,2,4dichlorophenol,2,6dichlorophenol,2,4,5trichlorophenol,2,4,6trichlorophenol,4chloro2benzyl phenol,pbromophenol,2,4,6tribromophenol,1chloro4(1,1dimethyl ethyl) benzene ether,3bromoanisole,mbromofluorobenzene,2tetra hydrofuran,αbromo4chloro acetophenone,αbromo4methoxy acetophenone,4chloro benzophenone,4chloro2methylaniline,n(2hydroxyethyl)ethane diamine; n(2aminoethyl)ethanolamine,2,3dibromopropionyl chloride,4bromo benzene sulphonyl chloride,terephthaloyl chloride,isophthaloyl chloride,nchlorosuccinimide,nbromosuccinimide,pchloranil;tetrachloro1,4benzoquinone,5chloroisatin.

华派公司产品：对氯苯酚，邻氯苯酚，2，4二氯苯酚，2，6二氯苯酚，2，4，5三氯苯酚，2，4，6三氯苯酚，4氯2苄基苯酚，对溴苯酚，2，4，6三溴苯酚，对氯苯基叔丁基醚，间溴苯甲醚，间溴氟苯，α溴甲基四氢呋喃，α溴代4氯苯乙酮，α溴4甲氧基苯乙酮，4氯二苯甲酮，4氯2甲基苯胺，N(2羟乙基)乙二胺， 2，3二溴丙酰氯，对溴苯磺酰氯，对苯二甲酰氯，间苯二甲酰氯，N氯代丁二酰亚胺，N溴代丁二酰亚胺，四氯苯醌，5氯靛红。

The biogenic amines in test samples were extracted by 10% trichloroacetic acid and then derived with benzoyl chloride. The HPLC analysis for the samples were conducted as the following condition: mobile phase was a gradient elution program of methanol and water, the flow rate was 0.8 mL/min.

用10%的三氯乙酸提取样品中的生物胺，采用苯甲酰氯衍生处理后，以甲醇/水为流动相，进行梯度洗脱，流速0.8 mL/min，紫外检测器波长为254 nm。

The effect of reaction temperature,reaction time,materials ratio on the synthesis of piperidine alcohol benzoate ,hindered amine light stabilizer,from piperidine alcohol and benzoyl chloride by direct condensation were studied,and the proper technological conditions were given as follows:the reaction temperature is 95℃;reaction time is 4 h; the mole ratio of reactants,n∶n is 1∶1.4,the amounts of solvent is 40 mL(based 0.1mol piperidine alcohol),the arerage yield ...

王树清，高崇，苯甲酸哌啶醇酯HALS的合成工艺研究研究了以苯甲酰氯和哌啶醇为原料直接缩合合成苯甲酸哌啶醇酯受阻胺光稳定剂时反应温度、反应时间、原料配比等条件对合成反应的影响，确定了最佳工艺条件。最适宜的工艺条件是：反应温度95℃、反应时间6h、原料摩尔比n∶n为1∶1.4，溶剂用量为70mL(相对于0.1mol哌啶醇)，苯甲酸哌啶醇酯的收率为91.05%，产品纯度98.5%。

Using phenol and benzyl chloride as raw materials and N,N-dimethyl formamide as solvent, benzyl phenyl ether was synthesized under microwave radiation.

采用微波辐射技术，以苯酚、氢氧化钾和氯化苄为原料，N，N-二甲基甲酰胺为溶剂合成了苄苯醚。

The concept of equivalent rotationally rigidity is offered and the formula of rotationally rigidity is obtained.

主要做了如下几个方面的工作：对伸臂位于顶部的单层框架—筒体模型进行分析，提出了等效转动约束的概念和转动约束刚度的表达式。

Male cats normally do not need aftercare with the exception of the night after the anesthetic.

男猫通常不需要善后除了晚上的麻醉。