苯甲腈

After mixing benzonitrile with anhydrous ethanol, we have also measured their vibrational dephasing time.

并对苯甲腈与无水乙醇混合后的这三个振动模式的振动退相时间进行了测量，并得到了变化后的振动退相时间。

Under optimal reaction conditions: catalyst dosage(mass fraction based on benzonitrile)6%,etha...

在上述条件下，苯甲腈催化加氢反应的表观活化能为20.4kJ/mol。

Synthesis of 2, 6-Bis (4-aminophenoxy) Benzonitrile and Polyimide Film Therefrom

篇名 2， 6-双（4-氨基苯氧基）苯甲腈的合成及其聚酰亚胺薄膜

Furthermore, the polymerization of benzonitrile catalyzed bydifferent Lewis acid and zinc was also investigated.

测定了以Lewis酸和几种金属催化苯甲腈聚合的反应速度，结果表明金属的活性次序为：镁＞锌＞钠＞钙。

Keywords amorphous nickel aluminium alloy catalyst;benzonitrile;benzylamine;catalytic hydrogenation

非晶态镍铝合金催化剂；苯甲腈；苄胺；催化加氢

The coexistence curves and light scattering data for a critical solution of benzonitrile + octane have been reported. The critical exponents relating to the difference in the density variables between two coexisting phasesβ, the osmotic compressibilityγ, and the correlation length v have been deduced and the values were consistent with the 3D-Ising value in the range close to the critical point. The experimental results of the coexistence curves have also been analyzed to examine the Wegner correction terms and the behavior of the diameter of the coexistence curves.

用折射率法和不同角度的光散射法测量了苯甲腈+正辛烷二元体系在临界温度附近的液-液共存曲线和一相区不同温度下的渗透压缩系数及关联长度，得到与共存曲线相关的临界指数β，与渗透压缩系数相关的的临界指数γ和与关联长度相关的的临界指数γ，发现在近临界点体系符合3D-Ising模型，讨论了共存曲线直径和Wagner校正项。

The epoxidation of of various olefins was carried out using LDH-F with Mg/Al=5 as the catalyst and H2O2 and benzonitrile as the oxidants. This catalytic system has excellent catalytic activity. The conversion and selectivity are both above 95% when using styrene, indene, allyl alcohol, and allyl chloride as the substrates.

以Mg/Al=5的LDH-F为催化剂，H2O2和苯甲腈为氧化剂对不同官能团化烯烃进行环氧化反应，结果表明，此催化体系具有良好的催化性能，在苯乙烯、茚、丙烯醇和烯丙基氯环氧化反应中转化率和选择性均在95%以上。

The optimal separating condition of chromatography analysis was: Shimadzu VP-ODS 150mm4.6mm as chromatographic column; acetonitrile/water (12/88,V/V, Contained 1.25mmol/l phosphoric acid) as mobile phase with flow rate of 1.0ml/min. Macroporous ion exchange resins and activated carbon were applied to enrich the trace level impurities and the main impurities was determined by LC-MS and GC-MS.They were : Benzonitrile , 2-Methyl-8-hydroxyquinoline, 2,6-Pyridinediamine , O-ethyloxime Cyclo-hexanone and compound with 220 molecular weight .

采用离子树脂和活性炭吸附富集这些微量的杂质，并通过液质联用和气质联用对杂质进行了定性分析，鉴定了影响290nm吸收的主要杂质为苯甲腈，2甲基-8羟基喹啉，2，6二氨基吡啶，O-乙基环己酮肟和分子量220的物质。

In order to find highly active pesticide, three series of 5--12-substituent-benzo phenanthridine derivatives were synthesized through the reaction of 2-methylbenzonitrile with dif-ferent aldehyde, and further dehydration with DDQ or N-methylation with NaH and CH3I, respectively.

为了寻找新的高活性农药，利用2-甲基苯甲腈与不同的醛反应，再通过2，3-二氯－5，6-二氰基－1，4-苯醌脱氢或NaH和CH3I氮甲基化，合成了3个系列共18个5-取代氨基－12-取代苯并菲啶衍生物，其中15个是未见文献报道的化合物。

Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用&一勺烩&方法，以4-羟基苯甲腈为起始原料，首先与硫氢化钠和无水氯化镁在N，N-二甲基甲酰胺中反应，所得中间体不经分离，直接加入2-氯乙酰乙酸乙酯进行环合反应，得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（2）；然后通过六亚甲基四胺/三氟乙酸进行Duff反应，得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（3）；再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。