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Additionally LC-MS was also used in qualitative analysis of the reactionsystem for the synthesis of dipropyl toluene-2,4-dicarbamate TDC(Pr. The main side-reactions were condensation reactions between 3-amino-4-methyl N-propylphenylcarbamate with TU or toluene 2,4-bisurea.

同样,运用液质联用技术对甲苯-2,4-二氨基甲酸丙酯TDC合成反应进行了定性分析,确定了副产物并推测其主要副反应是中间产物3-氨基-4甲基苯氨基甲酸丙酯与TU和甲苯-2,4-二脲之间的缩合反应。

In the third part of this dissertation, based on the leading compound ACPD, we design and asymmetric syhthesized two analogues: 56 and 57 by using Seebach's self- regeneration strategy to synthesize α,α-disubstituted amino acid as the key step.

论文的第二部分,我们利用我们所开发的合成α,α双取代氨基酸的方法,以对甲基苯甲醛为原料,经过分子内付克烷基化、氧化银氧化和氢化等16步反应,完成了代谢型谷氨酸受体拮抗剂-AIDA的不对称合成。

A-Methylnaphthalene contains a methyl group, which is a strong donor group, so the reaction of a-methylnaphthalene with C14 AOS acid had a higher conversion of aromatic than did the reaction of benzene with C14 AOS acid. After alkylaryl sulfonic acid is formed, it will continue to react with another AOS acid to rapidly produce dialkylaryl disulfonic acids owing to the electron- donating effect of the long alkyl chain in the alkylaryl sulfonic acid molecule.

a-Methylnaphthalene包含一个甲基集团,这是一个强大的捐赠团体,所以 a-methylnaphthalene反应出了与C14酸更高的转换的反应比苯与C14活性氧酸。alkylaryl磺酸为后形成,它将继续与另一出酸 dialkylaryl disulfonic迅速产生的电子-酸捐赠的长期效果在alkylaryl烃链磺酸分子。

Results showed that the monomer conversion increased slightly in the presence of the crosslinking agents The size of particles decreased slowh as the amount of cmsslinking agent increased.and the size distribution of the particles broadened at a higher amount of cmsslinking agent Divinyl benzene was more effective than ethyl glycol dimethyl methacrylate to make polymer crosslinked.During alkali treatment process,void latex particles can be obtained when no DVB or less than 0.5 wt% of EGDMA was used,while muhihollow structure was generated when DVB or more than 1.0 wt% of EGDMA was introduced.The volume expansion of the particles decreased with increasing the amount of emsslinkirlg agents.

结果表明,体系中加入交联剂后,单体转化率都有不同程度的提高;随交联剂用量的增加,乳胶粒粒径略有减小,交联剂用量较高时,乳胶粒粒径分布加宽;二乙烯基苯的交联效率稍高于双甲基丙烯酸乙二醇酯;不加入交联剂及EGDMA用量低于0.5%时,处理后乳胶粒呈空腔结构,加入DVB及EGDMA用量高于1.0%时,处理后乳胶粒呈多孔结构,并且乳胶粒体积增量随交联剂用量的增加而减小。

The main volatile chemical components were n-hexadecanoic acid (24.03%), dodecanoic acid (6.20%) tetradecanoic acid (6.44%), 6, 10, 14-trimethyl-2-pentadecanone (4.03%), nonanal (4.54%), anthracene (4.26%), benzeneacetaldehyde (4.25%).

主要成分有:正十六酸(24.03)%、十四酸(6.44%)、6,10,14-三甲基-2-十五烷酮(4.30%)、壬醛(4.54%)、蒽(4.26%)、苯乙醛(4.25%)。

According to the 1951 edition of Pharmacology and Therapeutics, it was to be prescribed for narcolepsy , post- encephalitic parkinsonism , alcoholism ,...

二十世纪五十年代,美国政府颁布法令将甲基苯丙胺规定为处方药,根据1951年出版的Arthur Grollman所著的《病理与药理学》一书,它可用于治疗嗜睡,后脑炎,帕金森综合症,酒精中毒,以及肥胖症。

Three new ferrocenylmethyl-substituted indenes and cyclopentadienes were synthesized by the addition of hydrogen anion and carbon anion to fulvene and benzo fulvene respectively, moreover, their structures were characterized by NMR and MS.

本文以二茂铁基富烯和二茂铁基苯并富烯为前体,通过负氢和负碳对双键的加成,合成了3个新型的二茂铁基甲基取代的茚及环戊二烯,并对其结构进行了核磁及质谱表征。

The first and second generation of dendritic polyesters have been prepared by divergent synthetic ways using trimethylopropame as core and o-phthalic anhydride, glycidol as branched units.

以三羟甲基丙烷为核,邻苯二甲酸酐,环氧丙醇为支化结构单元,合成了第一及第二代树枝状聚酯。

The result showed due to yeast fermentation process there were many new aroma components in jujube wine which were different from the juice: Isoamyl alcohol, Phenylethyl alcohol, Benzyl alcohol and so on; jujube juice hexadecanoic acid and other senior fatty acid composition obviously degradated; Alcohols and esters composition were sharply upward.

反映出发酵过程由于酵母的繁殖代谢产生了很多新成分,如异戊醇,丁酸乙酯,辛酸乙酯等;枣汁中十六酸等高级脂肪酸成分明显降解,苯乙醇,2,3-丁二醇,己二酸(2-甲基)丁酯,己二酸二异丙酯等醇类和酯类成分呈急剧上升的趋势。

A suspension of carbon nanotubes as a nanofluids was prepared by dispersing carbon nanotubes into deionized water. The effects of several typical kinds of surfactants such as sodium dodecyl benzene sulfonate, hexadecyl trimethyl ammonium bromide and emulsifying agent OP on the stability of the nanofluid were studied by stationary and centrifugal tests with sample morphologies characterized by SEM and TEM.

在水中加入碳纳米管制备了含碳纳米管悬浮液,研究了几种典型类型的表面活性剂:十二烷基苯磺酸钠、十六烷基三甲基溴化铵及乳化剂OP对纳米流体稳定性的影响,通过静置和离心分离等手段研究了其稳定性,并采用扫描电子显微镜和透射电子显微镜对样品的形貌进行了表征。

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Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在,所有的孩子都要在综合学校继续学习,所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地,使人们普遍认识到发展不能以牺牲农业为代价。

Detailed Intrinsic Reaction Coordination calculations were carried out to guarantee the optimized transition-state structures being connected to the related tautomers.

同时,做了详尽的内禀反应坐标计算,以保证所得到的过渡态连接相应的始末异构体。