苯甲基

Gel-type cross-linked polystyrene-isocyanuric acid resin has been obtained by reaction of chloromethylated polystyrene with isocyanuric acid under the existence of triethylamine.

由氯甲基化低交联聚苯乙烯和异氰尿酸在三乙胺作用下反应，制得了凝胶型交联聚苯乙烯-异氰尿酸树脂，测定了该树脂对苯酚和间苯二酚在不同温度下的吸附等温线，依据Clapeyron-Clausius方程从吸附等温线计算出了吸附热，从热力学的角度论证了树脂是基于氢键键合和疏水作用而吸附苯酚和间苯二酚的。

Neomycin on ammonia acid can lead to vitamin B12 deficiency; phenytoin, methotrexate, B ammonia pyrimidine, methyl benzyl ammonium pyrimidine and Triamterene, etc. can cause folic acid deficiency; mercaptopurine, 5 - fluoro-piperidine urine density, Ara-C, etc. can interfere with nucleic acid synthesis, these drugs can lead to megaloblastic anemia.

新霉素、对氨水杨酸可导致维生素B12缺乏；苯妥英钠、甲氨蝶呤、乙氨嘧啶、甲基苄氨嘧啶及氨苯蝶啶等可引起叶酸缺乏；巯嘌呤、5--氟尿密啶、阿糖胞苷等能够干扰核酸的合成，这些药物都可导致巨幼红细胞性贫血。

Based on relative literatures,this part has included five resesearch aspects as below.1 Fifteen compounds were isolated and purified by extraction,column chromatography,and their structures were determined on the basis of spectral analysis: acteoside(Ⅰ-1),isoacteoside(Ⅰ-2),crenatoside(Ⅰ-3),cistanoside F(Ⅰ-4),sinapoyl-4-O-β-D-glucoside(Ⅰ-5),adenosine(Ⅰ-6),β-siterol(Ⅰ-7),oleanic acid(Ⅰ-8), succinic acid(Ⅰ-9),caffeic acid(Ⅰ-10),protocatechuic aldehyde(Ⅰ-11),p-hydro xybenzyl alcohol(Ⅰ-12),β-daucosterol(Ⅰ-13),D-galacitol(Ⅰ-14),D-mannitol(Ⅰ-15).Ⅰ-4～15 were obtained from this plant for the first time,andⅠ-6,7,9,and 13 were isolated from Orobanche genus for the first time.2 The scavenging test of DPPH showed that most compounds have comparative antioxidant activity as L-ascorbic acid and part of them show better activity such as the O.coerulescens extract and phenylethanoid glycosides.Acteoside showed potent free radical scavenging effects with a median inhibition concentration of 25.6μg/ml.3 The anti-HBV activities of acteoside,isoacteoside and crenatoside were measured,and all of them showed suppressive activity on the expression of HBsAg and HBeAg in the HepG2.2.15 cell line.

本论文在文献调研基础上对紫花列当化学成分及生物活性进行了研究，并从免疫抗病毒角度探讨紫花列当中特征性成分类叶升麻苷的肝保护作用及其机制。1采用大孔树脂、硅胶和Sephadex LH-20等色谱技术对紫花列当进行系统的植物化学研究，从中分离得到19个化合物，利用UV和NMR等波谱手段及理化性质鉴定了其中的15个化合物，分别为类叶升麻苷(Ⅰ-1)、异类叶升麻苷(Ⅰ-2)、crenatoside(Ⅰ-3)、cistanoside F(Ⅰ-4)、sinapoyl-4-O-β-D-glucoside(Ⅰ-5)、腺苷(Ⅰ-6)、β-谷甾醇(Ⅰ-7)、齐墩果酸(Ⅰ-8)、琥珀酸(Ⅰ-9)、咖啡酸(Ⅰ-10)、原儿茶醛(Ⅰ-11)、对羟甲基苯甲酸(Ⅰ-12)、β-胡萝卜苷(Ⅰ-13)、D-半乳糖醇(Ⅰ-14)和甘露醇(Ⅰ-15除化合物Ⅰ-1、Ⅰ-2和Ⅰ-3外，其余化合物均为首次从该植物中分离得到。2)通过大孔树脂富集该药材有效部位苯乙醇总苷，并采用HPLC测得其所含特征性成分类叶升麻苷的含量可达80%以上。3DPPH自由基清除试验显示紫花列当提取物及其所含的苯乙醇苷类化合物均具有较好的抗氧化能力，其清除DPPH自由基能力接近于抗坏血酸。4采用卡介苗整体致敏、脂多糖离体攻击构建大鼠原代肝细胞免疫性损伤模型，在体外观察类叶升麻苷的保肝作用。

Cu2-Co2-KBr with high catalytic activity and selectivity shows synergistic effect between metal ions.Under the reaction conditions of mCu(Ac2:mCo(Ac2:m= 0.1:0.5:0.1, n:n=0.14, glacial acetic acid as solvent, overdosage sodium percarbonate, 65℃, the conversion can reach 45.9% and the selectivity for p-methoxy benzaldhyde is about 68.3%.

结果表明，Cu2-Co2-KBr具有较高的催化活性和选择性，体现出金属离子之间的协同作用，对甲基苯甲醚在mCu(Ac2：mCo(Ac2：m=0.1：0.5：0.1，n：n=0.14，冰醋酸作溶剂，稍过量的过碳酸钠，65℃的条件下，转化率可达45.9%，生成对甲氧基苯甲醛的选择性为68.3%。

Four series and sixteen solid complexes of rare earth chloride with 1-naphthoic acid (L_1),benzoic acid (L_2),phenylacetic acid (L_3) and Mandelic acid (L_4) have been synthesized by method of solid state reaction at low temperature,and then these complexes were characterized by chemical analysis methods.

本文采用低温固相合成法，以稀土氯化物、1—萘甲酸(HL_1)、苯甲酸(HL_2)、苯乙酸(HL_3)、苯羟乙酸(HL_4)为原料，以六次甲基四胺为质子受体，合成并表征了四个系列十六种固态配合物。

Mainly engaged in sodium azide, barium azide, three phosphorus nitride Friday, phenyl isothiocyanate, 1 - phenyl -5 - mercapto-tetrazole, 4 - dimethylamino-pyridine, 2 - mercapto--5 -- methyl-1,3,4 thiadiazole, N-hydroxy phthalimide, anhydrous betaine and betaine hydrochloride, such as fine chemical raw materials and medicine, pesticide intermediates of the development, production and sales.

主要从事叠氮化钠，叠氮化钡，五氮化三磷，异硫氰酸苯酯，1-苯基-5-巯基四氮唑，4-二甲氨基吡啶，2-巯基-5-甲基-1，3，4噻二唑，N-羟基邻苯二甲酰亚胺，无水甜菜碱及甜菜碱盐酸盐等精细化工原料及医药、农药中间体的开发、生产和销售。

The resin is prepared by swelling chlorine balls in a solvent such as nitrobenzene; adding catalyst to obtain polystyrene-divinylbenzene adsorptive resin; removing reaction mother solution; washing to remove residual solvent and catalyst; swelling; adding pyrane reagent to further react with chloromethyl residual on inner and outer surfaces of the resin to obtain the pyranyl modified adsorptive resin with the composite function.

该树脂的制备方法：将氯球溶胀于硝基苯等溶剂中，加入催化剂，得到聚苯乙烯-二乙烯苯吸附树脂；抽尽反应母液，洗去残留的溶剂和催化剂；溶胀，加入吡喃试剂与树脂内外表面残留氯甲基进一步反应，可制得吡喃基修饰复合功能吸附树脂。

In this paper, the synthesis of polyamide acid resin, with 4, 4′-diam-inodiphenyl ether and pyromellitic dianhyride as monomers and dimethylacetamide as solvent, is reported; the preparation of polyimide fiber from PAA resin by dry- spinning method is described; and the effects of various factors of operating conditions upon the mechanical properties of the fiber is discussed.

本文报导了用4，4′—二氨基二苯醚与苯均四酸酐作单体，在N，N′—二甲基乙酰胺溶剂中合成聚酰胺酸树脂，以及用该树脂经干纺法制备纤维和制备过程中各项参数对纤维力学性能的影响。

Comparison of inhibitors for anti-polymerization of isoprene, such as NaNO2, p-tert-butylcatechol, N-methyl pyrrolidone and paradioxybenzene, was carried out using polymer segregation process and the results showed that TBC was the best one.

采用聚合物离析法比较了亚硝酸钠（NaNO2）、对叔丁基邻苯二酚、N-甲基吡咯烷酮、对苯二酚对异戊二烯的阻聚效果，发现TBC阻聚效果最好。

In our work, as a preliminary experiment, the N-phenacylisoquinolinium bromide was reacted with methlhydrazine in refluxed acetic acid. Unexpectedly, 2-methyl-1,2,3-triazole was obtained. The further study of this reaction led to a more simple starting material,α-bromoacetophenone to react with methylhydrazine, obtaining the same product.

我们在研究N-苯乙酰异喹啉溴化物与甲肼在冰醋酸中的反应时，意外地得到了2-甲基-4-苯基-1，2，3-三氮唑，经过进一步的研究发现α-溴代苯乙酮与甲肼也能得到同样的产物。

My first article for Screen Power Magazine, which is to this day is the official magazine of Jackie Chan, was a DVD review of the Hong Kong actioner Gen-X Cops, starring Nicholas Tse and Daniel Wu.

我的第一篇文章为屏幕力量杂志，在对这天是Jackie Chan 正式杂志，是香港actioner Gen X 警察的DVD 回顾，担任主角Nicholas Tse 和丹尼尔吴。

His lips grazed hirs, Now what are you going to do?

他的唇使吃草了 hirs，现在你将要做什麼？