苯甲基

Their chemical structures were characterizd on the basis of spectral and chemical evidences to be: Sarracenin (1), 2-methyl-5-hydroxy-7-O-ethyl caffeate chromome (2), Naringenin(3), 2-methyl-5, 7-dihydroxychromome (4), 2-methyl-6-hydroxyl-cinnamic acid methyl ester (5), eriodictyol (6), quercetin (7), Naringenin-7-O-β-D-glucoside( 8 ), eriodictyol-7-O-α-D-glucoside (9), quercetin-3-O-β-D-glucoside(10). In addition, one compound was abtained from the n-butanol frationk, which was finally identified as Morrosiside(11) by spectral and chemical evidences.

以波谱数据及其理化性质鉴定为：Sarracenin(1)，2-甲基-5-羟基-7-O-咖啡酸乙酯色原酮(2)，柚皮素(3)，2-甲基-5，7-二羟基色原酮(4)，2-甲基-6-羟基苯丙烯酸甲酯(5)，圣草酚(6)，槲皮素(7)，柚皮素-7-O-β-D-葡萄糖苷(Naringenin-7-O-β-D-glucoside)(8)，圣草酚-7-O-α-D-葡萄糖苷(eriodictyol-7-O-α-D-glucoside)(9)，槲皮素-3-O-β-D-葡萄糖苷(quercetin--3-O-β-D-glucoside)(10)；另外从正丁醇萃取部位分离得到1个化合物，以波谱数据和文献对照鉴定为：Morroniside(11)。

Synthesis process of 2,6-dichloro-3-methylaniline was investigated 3-methylaniline was first N-acetylated with acetic anhydride,then treated with chlorosulphonic acid and ammonia yielding the 2-methyl-4--benzenesulfonic amide,which wasin turn deacetylated,chlorinated and hydrolyzed to the title compound.Hydrochloric acid was used instead of sodium hydroxide in deacetylation and sodium chlorate instead of hydrogen peroxide as oxidant in chlorination.

合成工艺2，6-二氯-3-甲基苯胺调查3-甲基首次N-乙酰与醋酸酐，然后与氯磺酸和氨产量 2-甲基-4--苯磺酰胺基，而擅转乙酰，氯化和水解的标题compound.hydrochloric酸代替氢氧化钠乙酰氯酸钠代替双氧水为氧化剂，加氯。

In a similar way, using N,N\'-dibenzyl tartamide as auxiliary,-(2-methyl)allyl-2-chloro-phenyl-methyl azide, a vital intermediate of Repaglinide, can be prepared via asymmetric allylation of o-chlorobenzaldehyde in

产物经氧化和碘加成内酯化反应得到阿伐他汀中间体(3R，5S)-3-羟基-5-碘甲基戊内酯(10)；将N-苄基酒石酸二酰胺用于邻氯苯甲醛的不对称烯丙基化反应以较高光学收率得-甲基烯丙基-2-氯苯基-甲基醇

Ib was synthesized by condensation of phthalic anhydride with 2-methylresorcinol in fused AlCl〓/NaCl (5∶1), followed by selective acetylation, methylation, NBS bromination and condensation with sodium ethoxide.

邻苯二甲酸酐在熔融的三氯化铝-氯化钠(5：1)中和-2，6-二羟基甲苯环合得1，3-二羟基-2-甲基蒽醌〓后经选择性乙酰化、甲基化、NBS溴化、乙醇钠缩合得1-甲氧基-2-乙氧甲基-3-羟基蒽醌。

Methods 4-Methylacetophenone was used as starting material to give 2-(4-methylphenyl) propionitrile via reduction, chlorination and cyanation. 2-(4-Bromomethylpheny1) propionic acid obtained by hydrolysis and bromination of compound Ⅲ could further provided loxoprofen sodium through four steps.

以4-甲基苯乙酮为原料，经还原、氯化、氰化得到2-（4-甲基）苯基丙腈，然后经水解、溴化得到关键中间体2-（4-溴甲基）苯基丙酸，该中间体再经过4步反应可制得洛索洛芬钠。

A new photochromic organic compound of thiosemicarbazone, 4-( p -bromo-α-methylaminothiocarbonyl hydrazonobenzal)-2,5-dihydro-3-methyl-5-oxo-1-phenyl pyrazole, was synthesized and characterized by elemental analyses, IR, 1H NMR spectra, and X-ray single-crystal diffraction analysis.

文章合成了一个新的有机化合物1-苯基-3-甲基-4-对溴苯亚甲基-吡唑啉酮-5 缩甲基氨基硫脲(1)，并分别用元素分析、红外光谱、氢核磁共振及X-射线单晶衍射对化合物的结构进行了确证和表征。

Disposal on methyl orange solution by two kinds of nanometer sized iron oxyhydroxides:α-FeOOH and β-FeOOH in visible light showed that methyl orange solution decolored by 90% by FeOOH/H2O2 system.And phenyl in methyl orange molec...

用2种纳米氧氢氧化铁针铁矿，正方纤铁矿处理偶氮染料分子甲基橙溶液，在自然光下，FeOOH/H2O2体系能使甲基橙溶液脱色率达90%，并且能将甲基橙分子中的苯环部分打开。

They are insoluble in water, ethanol, methanol, acetone, chloroform and benzene, but soluble in DMA, DMF and DMSO.

它们溶于N，N-二甲基甲酰胺、N，N-二甲基乙酰胺和二甲基亚矾等溶剂，但不溶于水、乙醇、甲醇、丙酮、氯仿和苯。

A process for synthesis of-2-{[4-(3-methoxypropoxy)-3-methyl-pyridin-2-yl]methyl- sulfinyl}-1H-benzimidazole from 2,3-lutidine was studied.

以2，3-二甲基吡啶为起始原料，经过11步反应，不对称合成了质子泵抑制剂的关键中间体：-2-{[4-(3-甲氧基丙氧基)-3-甲基吡啶-2-基]甲基亚硫酰基}-1H-苯并咪唑。

Finally, N ethey[3,3 dimethyl spiralindoline naphthoxazine]was synthesized by the addition of 1 nitroso 2 naphthol also,the photochromic mechanism of the substance and its photochromic phenomenon in ethanol were studied.

报道了以苯肼和 3 甲基 2 丁酮为原料首先合成 2 ，3 ，3 三甲基吲哚，吲哚再与碘乙烷亲核取代，碱化得费舍尔碱，最后与 1 亚硝基 2 萘酚作用合成N 乙基 [3 ，3 二甲基螺吲哚啉萘并恶嗪 ]的全过程，并研究了该物质的变色机理以及在乙醇溶剂中的光致变色现

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。