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The formed long and linear chain alkyl benzene changes into benzene methyl and alkene through β-scission and monomolecular homolysis, and then benzene methyl shifts to the position of α-Carbon in the long chain alkyl benzene through H-transfers.

已形成的长直链烷基苯通过β分裂、单分子均裂形成苯甲基、烯烃,苯甲基通过氢转移到长链烷基苯的α碳上,烯烃再与α碳结合形成带支链的烷基苯。

Isolation, purification and characteristics of D-hydantoinase were carried out. The experiment results showed that the optimal pH and temperature of pure D-hydantoinase were pH 8. 5 and 35℃, respectively. D-hydantoinase activity could be increased significantly by Mn〓 and Fe〓. Substrate specificity of D-hydantoinase on various hydantoin derivatives showed the optimal substrate of D-hydantoinase was 5-phenylhydantoin, but hydantoin, 5-methylthioehylhydantoin, 5-hydroxyphenylhydantoin, 5-methylhydantoin, 5-benzylhydantoin could also be hydrolyzed by D-hydantoinase.

本文还进行了海因酶的分离纯化及性质研究,发现酶的最适反应温度为35℃,最适pH为8.5,金属离子Mn〓和Fe〓能显著提高D-海因酶活力。D-海因酶的特异性实验表明,D-海因酶的最适底物为D,L-苯海因,其次为海因,D,L-对羟基苯海因和D,L-甲硫乙基海因,对D,L-甲基海因和D,L-苯甲基海因也有一定的作用。

Methods Benzhydrylpiperazine was synthesized by condensation of chlorodiphenylmethane and anhydrous piperazine in absolute ethanol.

以二苯甲基氯和无水哌嗪为原料,无水乙醇做溶剂,两者经缩合制得二苯甲基哌嗪。

This paper details an efficient method for a one-step transformation of the trityl ether to the acetonide. Treatment of trityl ether with a mixture of trifluoroacetic acid, 2,2-dimethoxy propane and camphorsulfonic acid as catalyst in dichloromethane through detritylation followed by acetonization gave the acetonide in high yield.

介绍了一种新的高效的由三苯甲基醚直接生成丙酮化合物的方法,也就是使三氟乙酸条件下脱三苯甲基的反应和生成丙酮化合物的反应在一个反应瓶中同时进行,使脱三苯甲基作用后生成的醇继续反应得到高产率的丙酮化合物。

In this thesis, we did modifications of alkyl groups upon benzyl fluorophosphonate. In order to study the influence of alkyl length and steric effect on activity and selectivity of probes, we synthesized benzyl fluorophosphonate recognition heads with modifications including ethyl, butyl, octyl and cyclohexyl. By way of connecting different kinds of tag like azido group, biotin and rhodamine with recognition heads separately through a higher hydrophilic ethylene glycol derived linker, a series of benzyl fluorophosphonate probes were made up. And they will apply to various biological testing strategies.

在本论文中,我们以苯甲基氟化磷酸酯为基础,於其上进行一系列烷基之修饰,为了探讨烷基长度与空间立体性质对於探针活性及选择性的影响,我们合成了包含乙烷基、丁烷基、辛烷基以及环己烷基修饰的苯甲基氟化磷酸酯辨识端,并藉由具较高亲水性的聚乙二醇衍生连接桥结合三种不同的发报端,分别有叠氮基团、生物素及萤光基团来构成不同的化学探针组合,这一系列苯甲基氟化磷酸酯类化学探针将可被应用於不同的生物测试策略。

Phenylethyl than malonic acid methyl malonic acid benzene over a methylene, metal complexes of stability and performance is a lack of research.

苯乙基丙二酸比苯甲基丙二酸多一个亚甲基,其金属配合物的稳定性及性能尚缺乏研究。

Can induce the reaction of cleavage H atom from methyl on the ring of deactivated toluenes,such as nitrotoluene. The carbanions caused by base are the very important reaction intermediums, which determined the reaction rate and reaction effect.

该反应体系中,NaOH的加入对此催化反应起着相当关键的作用,研究表明强碱也能像温度一样促进苯环卜甲基的摘氢速度,使底物形成相应的硝基苯甲基阴离子,稳定的硝基苯甲基阴离子是氧化反应进行的重要中间体。

This thiosemicarbazide was treated under the catalysis of glacier acetic acid,mercuric acetate giving 2 benzyl 5 phenylamino 1,3,4 thiodiazole and 2 benzyl 5 phenylamino 1,3,4 oxadiazole respectively.

然后分别将其在冰醋酸、醋酸汞存在下关环,制得 2 苯甲基 5 苯胺基 1,3 ,4 噻二唑与 2 苯甲基 5 苯胺基 1,3 ,4 口恶二唑

In this study, we investigate the effect of benzyl isothiocyanate and phenethyl isothiocyanate on human prostate cancer DU-145 cells, the results demonstrate that benzyl isothiocyanate and phenethyl isothiocyanate induced cause G2 / M phase arrest and apoptosis. These effects are in a dose- and time-dependent manners.

但是苯甲基异硫氰酸酯和苯乙基异硫氰酸酯造成人类前列腺癌细胞株DU-145的凋亡机转则尚未有较详细的报导,所以本研究即是探讨苯甲基异硫氰酸酯和苯乙基异硫氰酸酯造成人类前列腺癌细胞株DU-145的相关凋亡机转。

At 60 ℃ the reaction of 1-O-alkyl-2-O-acetyl-3-O-trityl glycerol with iodine/methanol system removed trityl and acetyl and gave 1-alkyl glycerol. But at r.t. the reaction only removed trityl and gave two isomers 1-O-alkyl-2-O-acetyl glycerol and 1-O-alkyl-3-O-acetyl glycerol.

1-烷氧基-2乙酰氧基-3-三苯甲氧基甘油醚与碘/甲醇体系反应,在60 ℃时,同时发生了脱三苯甲基及乙酰基,在室温下,仅脱三苯甲基,但乙酰基在反应过程中发生了部分转移,产生了两个异构体。

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Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在,所有的孩子都要在综合学校继续学习,所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地,使人们普遍认识到发展不能以牺牲农业为代价。

Detailed Intrinsic Reaction Coordination calculations were carried out to guarantee the optimized transition-state structures being connected to the related tautomers.

同时,做了详尽的内禀反应坐标计算,以保证所得到的过渡态连接相应的始末异构体。