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A series of so-called hairy-rod fluorene-alt-benzene based polymers with different substituted groups on phenylene were synthesized through Suzuki route.

通过光谱、电化学和模拟计算等手段研究了苯环上不同性质的侧基取代芴苯聚合物的发光性质、电化学性质和溶剂化效应等,同时研究了侧基性质的变化对这些物理性质的影响规律。

However, the spectral stability was increased, and the 0-1 transition and the full width at the half-maximum of photoluminescence spectra was decreased with the increase of the alkoxy length on phenylene. The nature (e.g. electron-donating and electron-withdrawing) of the substituted side groups on phenylene has obvious effect on the optical properties, QY and electrochemical properties of the polymers.

苯环上取代侧基的给吸电子性质变化对聚合物的光电性能具有全面的影响,改变取代侧基的给吸电子性质可调节芴苯共聚物的发光颜色和HOMO、LUMO能级以及HOMO-LUMO能隙等,因此,通过引入不同性质的侧基可以实现对此类聚合物光物理性能的调控。

Compared with the pure AlPO 4-5 molecular sieve, the unit cell volume of Cr-AlPO 4-5 expanded and its skeleton vibration peaks in FT-IR spectra shifted to low wavenumbers.

但是 ,由于苯环上共轭大π键所产生的化学稳定性,使得苯在温和条件下难于发生反应;因此,必须选择高活性的催化剂。

The OnTrak TesTcard 9 provides a qualitative screen for the presence of amphetamines, barbiturates, benzodiazepines, cocaine, methamphetamines, morphine, phencyclidine, tetrahydrocannabinol, and tricyclic antidepressants in urine.

OnTrak TesTcard 9能够定性筛查下述尿液中的药物:安非他明、巴比妥酸盐、苯二氮、可卡因、脱氧麻黄碱、吗啡、苯环己哌啶、四氢大麻酚、三环抗抑郁药。

Mechanism of the synthesization of aminobenzene sulfonate high performancing water-reducing was proved by virtue of mass experiment and infrared spectral analysis.

在合理酸碱催化作用下,形成初级生成物,然后和对氨基苯磺酸钠苯环的邻位缩合反应,同时氨基上只有一个氢和甲醛反应生成仲胺,最后形成高聚物。

In the three systems, system realizes the crosslinking of PVC bases on the peroxide crosslinking mechanism, the tensile strength of crosslinked PVC has been improved somewhat, the IR spectrum of gel demonstrates that there are characteristic absorption peaks of n-alcohol that belongs to ethanol amine and benzenoid group. From the analysis of gel structure , deduces that the mechanism of crosslinking reaction: under the initiations of peroxide and high temperature, PVC yields macromolecules free radicals, at the same time , styrene"s polymerization and grafting onto PVC takes place, at last the system forms crosslinking structure through coupling between radicals; confirms that triethanol amine can absorb HC1 produced by degradation of PVC, so improves the crosslinking efficiency of peroxide, decreases the HCl"s promotion for PVC"s degradation; deduces that triethanol amine can activate the PVC macromolecules and prolong the free radicals" life-time of PVC macromolecules; the effect to the PVC macromolecule makes styrenes graft reaction easy, and thus improves the crosslinking efficiency.

三种体系中三乙醇胺/过氧化二异丙苯/苯乙烯体系基于过氧化物交联机理实现了聚氯乙烯的交联,聚氯乙烯交联后拉伸强度有一定提高,凝胶红外光谱分析证实了凝胶结构中含有乙醇胺的伯醇基团特征吸收和苯环的特征吸收,由凝胶结构分析,推断出交联反应的机理:聚氯乙烯在过氧化物和热作用下产生大分子自由基,苯乙烯在过氧化物和大分子自由基的作用下发生聚合和接枝反应,最终通过自由基之间的偶合产生交联;证实三乙醇胺可以吸收聚氯乙烯分解产生的HCl,提高了过氧化物的交联效率,消弱了HCl对聚氯乙烯降解的促进作用;推断三乙醇胺可以活化聚氯乙烯大分子并有可能使聚氯乙烯大分子自由基存在的时间得以延长,对聚氯乙烯大分子的作用使苯乙烯的接枝反应易于发生,从而提高了交联效率。

According to the 13CNMR chemical shifts of substituted benzene, conjugative effect parameter and inductive effect parameter are established.

以取代苯苯环碳原子化学位移为依据,用曾经设定并初步证实的甲基诱导效应和共轭效应参数,讨论了甲基取代基的诱导效应、共轭效应及定位效应。

The bond lengths,bond angles and molecular conformation indicate that:in these polyphenoxy benzene systems the conjugative polari...

的分子构象、键长和键角数据表明氧桥两边的苯环的共轭极化效应不能贯通,而苯氧基只是分子中的一个独立片断。

This paperindicated that it was good for condensation reaction when benzene-ring bearingelectron-attaching groups. It also showed that and the 6-hydroxyl group could bereacted with acyl halide, haloid ether and halo alkene, but not with halo alkane. It wasnot only the first time to find that the reaction product of D-mannitol and aromaticaldehyde is tri-condensation derivatives, but also the first time to obtain thep-phthaldehyde-sorbitol derivatives containing eight hydroxyl groups.

研究发现:苯环上有吸电子基团时对缩合反应有利;多元醇缩醛衍生物6-羟基除与酰氯反应外,也能和卤代酸酯、溴代烯反应,但不与卤代烷反应;首次发现D-甘露醇与醛反应主要得到三缩合物;首次合成了含有8个羟基的对苯二甲醛和山梨醇的缩合物。

The formation mechanism for the C-PPV aggregation we proposed is: complex between K+ and the crown ether derivatives in the C-PPV brings two polymer chains closer together, and the K+ ions create interpolymer bridges, forming aggregations in the solution.

本文合成了可溶的带冠醚取代基的聚苯撑乙烯,其中冠醚基团的氧原子直接连在PPV主链上苯环的2、3位,并研究了聚合物在K~+存在下的自组装形成聚集体的行为。

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推荐网络例句

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。